Materials Literature
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Abstract The series of nylon 612 copolymers was synthesized from caprolactam (C) and laurolactam (L) at 145°C. The 50/50 C/L molar ratio copolymer was found to have the minimum melting temperature ( T m ) for the series. The glass transition temperatures ( T g 's) of the copolymers were affected by the crystallinity o…
Abstract The stress relaxation behavior of model silicone room temperature vulcanizing (RTV) elastomers has been used to examine the chemistry of the cured silicone network. It has been shown that the tin crosslinking catalyst, together with water, produces siloxane bond rearrangement which results in chemical stress…
Abstract A thermogravimetric/mass spectrometric (TG/MS) system was used to characterize the thermolysis reactions of (4‐O‐methyl‐ D ‐glucurono)‐ D ‐xylan. The mass spectrometric peaks, measured as function of time, were attributed to water, methanol, carbon monoxide, carbon dioxide, formaldehyde, formic acid, acetic a…
Abstract The moisture‐induced plasticization of some amorphous polyamides in pure and blended form has been determined by calorimetric methods. The compositional dependence of the glass transition temperature of these polymer‐diluent systems has been adequately accounted for using an existing predictive expression der…
Abstract The Sanchez‐Lacombe equation of state was used to model the sorption of high‐pressure gases into solid, amorphous polymers and molten polymers. Only one adjustable parameter per binary pair, δ 12 , was used in the mixing rules to correct the deviation of the characteristic pressure of the mixture, P 12 * , fr…
The mobility of foams in porous media is dominated by foam texture (i.e., foam bubble size). The effect of bubble size can be incorporated into a reservoir simulator by adding balances on the number density of bubbles in flowing and stationary foam to the equations of mass, momentum, and energy conservation. These bal…
Abstract Average advancing and receding contact angles made against cotton and glass fibers by a set of probe liquids are determined using the Wilhelmy technique. The dispersive and polar components of the surface energy are calculated from the measured contact angles using both the geometric and the harmonic mean met…
The stoichiometric complex formed between human leukocyte elastase and a synthetic MeO-Suc-Ala-Ala-Pro-Val chloromethyl ketone inhibitor was co-crystallized and its X-ray structure determined, using Patterson search methods. Its structure has been crystallographically refined to a final R value of 0.145 (8.0 and 2.3 A…
Diamond-like carbon films have been deposited onto clean, unseeded substrates using a hybrid ion beam technique. In this method the ion fluences available for acceleration were particularly enhanced by the use of laser ablation plumes ejected from highly purified graphite targets. The combination of levels of purity c…
We report frequency-dependent measurements of the specific heat ${c}_{p}$ thermal conductivity $\ensuremath{\kappa}$ of ${(o\ensuremath{-}\mathrm{t}\mathrm{e}\mathrm{r}\mathrm{p}\mathrm{h}\mathrm{e}\mathrm{n}\mathrm{y}\mathrm{l})}_{1\ensuremath{-}x}{(o\ensuremath{-}\mathrm{p}\mathrm{h}\mathrm{e}\mathrm{n}\mathrm{y}\ma…
A field-effect transistor structure is used to study the transport properties of the soluble conductive polymer, poly(3-hexylthiophene). We have measured conductance, mobility, and carrier concentration in undoped polymer thin films. The field-effect mobility was found to be 10−5–10−4 cm2/V s at room temperature. The…
The magnetic properties of five different microstructures of AISI 4140 steel are measured as a function of compressive plastic deformation. Coercivity, hysteresis loss, remanence, permeability, differential permeability, and anhysteretic magnetisation are determined for strains of up to 10%. Coercivity, hysteresis los…
The intrinsic magnetic material parameters of the 2: 17 type matrix phase and the 1: 5 type precipitation phase in sintered multiphase Sm(Co0.68Cu0.08Fe0.22Zr0.02)7.6 permanent magnets are determined in the whole ferromagnetic temperature regime between 10 K and Tc = 1070 K. Magnetization curves measured parallel and…
The interaction of surface plasmons with surface-optical-phonon modes in the presence of an external dc magnetic field, neglecting the retardation effect, has been studied to investigate the factors which may influence the coupling between the two waves in III-V polar semiconductors. It has been found that the couplin…
The time and temperature dependence of the specific heat of glasses is considered in light of an analytic form for the density-of-states function of two-level systems, N(E), which has recently been calculated. It is shown that experimentally observed time and temperature dependences are explainable with this function…
A structural investigation by x-ray diffraction is presented on ionic conducting glasses of composition (AgI)x (AgPO3)1−x, with x=0.0, x=0.45, and x=0.55. The radial distribution functions of the AgI-doped glasses, calculated from the experimental diffracted intensities, are dominated by a peak centered at about 2.80–…
Refinement and thin film synthesis methods were used by members of six different institutions to design antireflection coatings for germanium substrates. The solutions are based on the use of zinc sulfide and germanium layers only. Several systems were found with an average reflectance that is less than 1% in the 7.7…
The origin and characteristics of the field-off state optical properties of the general twisted nematic liquid-crystal displays (LCD) are discussed. The optical field propagating normally in a uniformly twisted nematic structure can be represented by two mutually orthogonal elliptically polarized normal modes, one wit…
The dynamic structure factor S(q,\ensuremath{\omega}) of electrons in highly oriented pyrolytic graphite for q\ensuremath{\parallel}c and q\ensuremath{\perp}c with 0.37<q<2.06 a.u. was measured at 0.8 eV resolution by inelastic scattering of synchrotron x radiation. The energy-transfer regions both of interband…
We present a Landau theory of the martensitic structural phase transformation undergone by bcc Li into the 9R phase. We propose that the transition occurs via incomplete softening of the ((1/3 1) /3 0) ${\ensuremath{\Sigma}}_{4}$ phonon. Even though this branch does not soften to zero frequency (or even close to zero…