Materials Literature
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Abstract Different grades of PVC resins and a variety of plasticizers are used to adjust processability and properties of plastisol. The plastisol, which is a dispersion of fine particles of PVC in plasticizer, is coated on a substrate and heated in an oven to gel and fuse. In the gelation stage the resin particles be…
We report on a systematic study of the thin-film growth and the electronic structure of the intrinsic molecular semiconductor lutetium–diphthalocyanine (LuPc2). The films were grown in ultrahigh vacuum. Starting from submonolayer coverage, thickness-dependent x-ray and ultraviolet photoemission spectroscopy (UPS) meas…
SUMMARY Potassium release and fixation were studied on Ferralsols (typic Eutrustox) of Southern Togo both by isotopic exchange with 42 K+ ions and by exchange with 1 M ammonium acetate. Experiments were conducted on soil samples taken from surface (0–30 cm) and subsoil (80–100 cm) layers of four plots. These plats, wi…
Abstract The behaviour of adenine and 2′‐deoxyadenosine‐5′‐monophosphate (dAMP) at positive surface potentials of a silver working electrode was investigated using surface‐enhanced Raman scattering (SERS). The use of positive potentials in the presence of adenine or dAMP leads to a rapid accumulation of an intense spe…
Research News: Freely suspended thin film of smectic liquid crystalline materials can be described as two‐dimensinal fluids with a regular layer structure in the third dimention. By reducing the internal pressure in the set up shown in the figure the films can be transferred onto solid supports allowing their study, m…
Abstract X-ray diffraction was used to analyse the distribution of clay minerals in the <2 µ m fraction of the lutitic and marly facies from the centre of the Basque-Cantabrian Basin (Basque Arc), where the sedimentary section is 2000 to 10,000 m thick. Most of the deposits were laid down during the Cretaceous and…
Two non-first-order kinetic peaks at about 350 and 500 K appear in the thermoluminescence (TL) spectra of single-crystal and polycrystalline ${\mathrm{MgAl}}_{2}$${\mathrm{O}}_{4}$ irradiated with ionizing radiation at room temperature. Among others, emission from ${\mathrm{Cr}}^{3+}$ and ${\mathrm{Mn}}^{2+}$ ions are…
Silicon dioxide films deposited from the plasma‐enhanced chemical vapor deposition (PECVD) reaction of silane and nitrous oxide in the presence of helium were studied to determine the effects of temperature and radio frequency (RF) power on the deposition process. Increased RF power density yielded oxides which were s…
We study the interaction of disclinations in the presence of an applied magnetic or extensional flow field, which tends to align the director. Disclinations and inversion walls in the director field of nematic thermotropic liquid-crystal polymers are imaged at high resolution using the lamellar decoration technique of…
Abstract The thermal behaviour of sepiolite and palygorskite treated with pyridine (Py) was investigated by DTA, TG, DTG and EGA (by MS) under a flow of air and inert gases (N 2 or Ar). The thermal analysis showed that the organic base was adsorbed by the clays, penetrating into the clay pores and replacing zeolitic a…
Abstract A new family of addition curing polyimides were prepared that contained 4‐amino [2.2]‐paracyclophane as the endcap. An improved synthesis of the endcap 4‐amino‐[2.2] cyclophane was accomplished increasing the yield to 60% and simplifying the procedure. DSC and rheological analysis of endcapped polyimide oligo…
A new metastable liquid-crystalline phase BPS was observed in pure chiral compounds. The BPS is transformed reversibly from the supercooled BPI and is thermodynamically stable with respect to the BPI and metastable to the cholesteric phase. Rhombic single crystals of the BPS probably indicate a cubic lattice structure…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAn x-ray crystallographic and single-crystal EPR investigation of the cationic, iron-centered radical tricarbonylbis(triphenylphosphine)iron(I), {Fe(CO)3(PPh3)2+}. A theoretical examination of the structural preferences of five-coordinated seventeen-electron complexesJoseph…
A continuum damage mechanics description of elastic-brittle fracture provides an appropriate constitutive model for impact simulations involving ceramic, rock, or similar materials. For an orthotropically damaged solid, a complementary energy function may be derived from a mesomechanical description of three orthogona…
The essential feature of small, modular high-temperature reactors (HTRs) is the inherent limitation in maximum accident temperature to below 1600°C combined with the ability of coated particle fuel to retain all safety-relevant fission products under these conditions. To demonstrate this ability, spherical fuel elemen…
A new class of lipids, arsonolipids or rac-1,2-diacyloxypropyl-3-arsonic acids, have been synthesized by acylating tetrabutyl ammonium hydrogen rac-1,2-dihydroxypropyl-3-arsonate with myristic, palmitic and stearic anhydrides in the presence of pyridine. The yields are moderate to low due to decomposition of rac-1,2-d…
Abstract It was demonstrated in a previous investigation that both horizontal and vertical shifting is required to produce master curves for the relaxation moduli from elevated temperature data for polyethylene gas pipe materials. In this study, the shift functions obtained from these stress relaxation tests are appli…
We have studied electrically driven convective flow in thin, freely suspended films of smectic-A liquid crystal. Here we report measurements of the two-dimensional velocity field of this flow as the driving voltage is varied. Our results are well described by the first few terms of an appropriate mode expansion over a…
Molecular-dynamics simulations have been carried out on a ``soft-sphere'' model for binary alloys quenched into supercooled states. The main emphasis of this work is on the dynamic characterization of the glass transition. In the vicinity of the glass transition jump motions of atoms are dominant for the diffusion pro…
The effects of temperature cycling and heating rate on the release behavior of 85Kr have been studied for U02 pellets irradiated in a commercial BWR during 3 and 4 cycles (burn-up: 23 and 28GWd/t), by using a post irradiation annealing technique. In addition, characteristics of intergranular bubbles in base-irradiated…