Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRhodium-rhodium stretching frequencies in oxygen-16, oxygen-18, and trideuteromethyl derivatives of Rh2(O2CCH3)4(PPh3)2Robin J. H. Clark, Andrew J. Hempleman, and Colin D. FlintCite this: J. Am. Chem. Soc. 1986, 108, 3, 518–520Publication Date (Print):February 1, 1986Publica…
A new compound, 12SrO·7Al 2 O 3 , is formed from an amorphous material prepared by the simultaneous hydrolysis of strontium and aluminum alkoxides. It has a cubic unit cell with a =1.2325 nm. The structure contains tetrahedral AlO 4 groups and octahedral AlO 6 groups. This compound decomposes into 3SrO·Al 2 O 3 and Sr…
Abstract Reaction of mixtures of cobalt nitrate, colloidal silica, and a metal hydroxide (MOH) under hydrothermal conditions produced a range of cobalt hydroxysilicates, the components of which depended upon the identity of M, temperature, and reactant ratios. At 250°C, if M = Na, a smectite of composition Na 0.06 Co…
This paper presents the most significant results of multiyear research carried out in order to evaluate the thermal endurance properties of insulating materials. The thermal life model, proposed by Dakin, has been analyzed and compared with the experimental data; the importance of the selection of properties and their…
The system Ba 2 SiO 4 ‐Ca 2 SiO 4 was studied by heating mixtures of Ba 2 SiO 4 and Ca 2 SiO 4 at 1723 K. Six distinct phases resulted; they were examined by both X‐ray diffraction and differential thermal analysis. The phases β ‐(Ba 0.05 Ca 1.95 )SiO 4 and α‐(Ba 0.15 Ca 1.85 )SiO 4 are isostructural with correspondin…
The crystal structure of BiVO4, which has a monoclinic, distorted scheelite structure at ambient conditions, has been determined above the high-pressure transition at 1.6 and 4.3 GPa, and 23°C. At these pressures BiVO4 has the tetragonal scheelite structure, which is also observed at high temperature above 250°C at ro…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXT.alpha.-Diazomethyl- and bis(.alpha.-diazomethyl)palladium complexes. Preparation, crystal and molecular structures, and reactionsShunichi Murahashi, Yasuo Kitani, Toru Uno, Takahiro Hosokawa, Kunio Miki, Tadashi Yonezawa, and Nobutami KasaiCite this: Organometallics 1986, 5…
Abstract Die Cluster (μ 3 ‐RC)CoMNiCp 2 (CO) 5 ( 1, 2 , M = Mo, W) entstanden aus (μ 3 ‐RC)Co 2 MCp(CO) 8 mit [CpNiCO] 2 . Aus den gleichen Ausgangsclustern wurden mit K 2 Fe(CO) 4 die Cluster (μ 3 ‐RC)FeCoMCp(CO) 8 H ( 5, 6 , M = Mo, W) erhalten. Mit dem optisch aktiven Substituenten R* = Menthyl bildete sich durch z…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTheory of nematic ordering in the melts of macromolecules with different flexibility mechanismsA. R. Khokhlov and A. N. SemenovCite this: Macromolecules 1986, 19, 2, 373–378Publication Date (Print):February 1, 1986Publication History Published online1 May 2002Published iniss…
Abstract A computer model of a single‐pass, rotary‐drum dryer with or without a centerfill flighting section, describes the drying behavior of wood particles within the drum. This part of a two‐part study examines heat and mass transfer, which are shown to be partly dependent on the pattern of particle flow and on ret…
Rabbits were prepared so that a variable capacitance displacement transducer (VCDT) could be used to monitor the eruptive movements of a previously-amputated lower incisor, and a strain gauge transducer mounted on a relay-controlled plate was used to place precisely controlled intermittent forces opposing the erupting…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNitroxyl adducts of copper(II) trihaloacetates. Diamagnetic copper(II) complexes with a novel dimeric structureLeigh C. Porter, Michael H. Dickman, and Robert J. DoedensCite this: Inorg. Chem. 1986, 25, 5, 678–684Publication Date (Print):February 1, 1986Publication History P…
Recent studies on the behavior of nematic liquid crystals (LC’s) in two basic configurations are described. The phase rate of change Δϕ/Δt is studied for the case of parallel aligned nematic cells. It is shown that Δϕ/Δt of approximately 3 rad/msec can be obtained with a 4-μm E-7 LC at λ = 0.63 μm. The optical transmi…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAdsorption of poly(diallyldimethylammonium chloride) on colloid silica from water and salt solutionEtsuo Kokufuta and Katsufumi TakahashiCite this: Macromolecules 1986, 19, 2, 351–354Publication Date (Print):February 1, 1986Publication History Published online1 May 2002Publi…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFacile reduction of pyridines with nickel-aluminum alloyGeorge Lunn and Eric B. SansoneCite this: J. Org. Chem. 1986, 51, 4, 513–517Publication Date (Print):February 1, 1986Publication History Published online1 May 2002Published inissue 1 February 1986https://pubs.acs.org/do…
Crystalline Cd(SPh) 2 is {(μ‐SPh) 6 Cd 4 (μ‐SPh) 4/2 } , an inorganic polymer. It consists of Cd 4 (SPh) 6 cages having adamantane‐like structure, each of which is linked with four surrounding cages by four SPh bridges. The three‐dimen‐ 113 Cd‐NMR spectrum indicates that the polymer forms Cd 10 (SPh) 20 molecules havi…
The performance of copper and mild steel plain heat exchanger tubes and an externally finned mild steel tube was studied under calcium carbonate scaling conditions. Under a constant heat flux for 70-h periods the fouling resistance generally increased linearly with time. The effect of velocity on the rate of scale for…
The photoelectrochemical behavior of n‐type Si electrode in aqueous solutions was investigated. Protection of the electrodes against photocorrosion was achieved by chemically depositing a thin film of manganese oxide on the surface. The electrodes have shown complete stability during oxygen evolution under continuous…
The four pair-wise potentials found in part I (Bacon and Liang 1986) to define model hexagonal-close-packed crystals in equilibrium have been used for the computer simulation of dislocation cores in the absence of external stress. Straight dislocations with Burgers vector b equal to either ⅓〈1120〉 or 1/3〈1123〉 have be…
The diffusion of impurities of low concentration in a surrounding dense medium is studied near the liquid-glass transition point. Within a simplified model we obtain an analytical solution in the long-time or small-frequency regime for a generalized diffusion constant, which is expressed in terms of Bessel functions.…