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Poly(2-Vinyl-4,4-dimethylazlactone)-Functionalized Magnetic Nanoparticles as Carriers for Enzyme Immobilization and Its Application

Xiaoyu Mu、Juan Qiao、Qi Li 等 5 位作者2014-10-31ACS Applied Materials & Interfaces

Fabrication of various efficient enzyme reactors has triggered increasing interests for its extensive applications in biological and clinical research. In this study, magnetic nanoparticles were functionalized by a biocompatible reactive polymer, poly(2-vinyl-4,4-dimethylazlactone), which was synthesized by reversible…

Polymer Surface Interaction StudiesNanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applications

A New ε Crystal Modification Found in Stereodefective Isotactic Polypropylene Samples

Bernard Lotz2014-10-31Macromolecules

High Resolution Image Download MS PowerPoint Slide The main features of an original crystal modification of isotactic polypropylene (iPP) are described. This form is obtained with a stereodefective or “an-isotactic” iPP produced with a zirconene catalyst by Rieger et al. [ Macromolecules 1990, 23, 3559−3568]. In thin…

biodegradable polymer synthesis and propertiesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Carbon-allotropes: synthesis methods, applications and future perspectives

P. Karthik、A. L. Himaja、Surya Prakash Singh2014-10-31Carbon letters

The element carbon has been used as a source of energy for the past few hundred years, and now in this era of technology, carbon has played a significant and very prominent role in almost all fields of science and technology. So as an honour to this marvellous element, we humans should know about its various forms of…

Graphene research and applicationsCarbon Nanotubes in CompositesFullerene Chemistry and Applications

Effect of carbon black on electrical and rheological properties of graphite nanoplatelets/poly(ethylene-butyl acrylate) composites

Henrik Oxfall、Giampaolo Ariu、Thomas Gkourmpis 等 5 位作者2014-10-31eXPRESS Polymer Letters

The effect of adding carbon black on the electrical and rheological properties of graphite nanoplatelets/poly(ethylene-butyl acrylate) copolymer composites produced via melt or solution mixing was studied. By adding a small amount of low-or high-structured carbon black to the nanocomposite, the electrical percolation…

Polymer Nanocomposite Synthesis and IrradiationHigh voltage insulation and dielectric phenomenaPolymer Nanocomposites and Properties

Thermo-stabilized, porous polyimide microspheres prepared from nanosized SiO2 templating via in situ polymerization

M. Q. Liu、Junping Duan、Xiaoran Shi 等 5 位作者2014-10-31eXPRESS Polymer Letters

In this article, we addressed a feasible and versatile method of the fabrication of porous polyimide microspheres presenting excellent heat resistance. The preparation process consisted of two steps. Firstly, a novel polyimide/nano-silica composite microsphere was prepared via the self-assembly structures of poly(amic…

Synthesis and properties of polymersMesoporous Materials and CatalysisSilicone and Siloxane Chemistry

Enhancing the mechanical properties of electrospun polyester mats by heat treatment

Mariya Kancheva、Antoniya Toncheva、Nevena Manolova 等 4 位作者2014-10-31eXPRESS Polymer Letters

Microfibrous materials with a targeted design based on poly(L-lactic acid) (PLA) and poly(!-caprolactone) (PCL) were prepared by electrospinning and by combining electrospinning and electrospraying. Several approaches were used: (i) electrospinning of a common solution of the two polymers, (ii) simultaneous electrospi…

Silicone and Siloxane ChemistryElectrospun Nanofibers in Biomedical Applicationsbiodegradable polymer synthesis and properties

Delocalized Quantum States Enhance Photocell Efficiency

Yiteng Zhang、Sangchul Oh、Fahhad H. Alharbi 等 5 位作者2014-10-31arXiv

The high quantum efficiency of photosynthetic complexes has inspired researchers to explore new routes to utilize this process for photovoltaic devices. Quantum coherence has been demonstrated to play a crucial role within this process. Herein, we propose a three-dipole system as a model of a new photocell type which…

Materials ScienceChemical Physicsquant-ph

Oxygen vacancy andEC− 1 eV electron trap in ZnO

Gauthier Chicot、Pierre Muret、Jean‐Louis Santailler 等 5 位作者2014-10-31Journal of Physics D Applied Physics

Fourier transform deep level transient spectroscopy has been performed between 80 and 550 K in five n -type ZnO samples grown by different techniques. The capture cross section and ionization energy of four electron traps have been deduced from Arrhenius diagrams. A trap 1 eV below the conduction band edge is systemat…

ZnO doping and propertiesElectronic and Structural Properties of OxidesCopper-based nanomaterials and applications

Ratiometric fluorescent pH probes based on aggregation-induced emission-active salicylaldehyde azines

Xiaofeng Ma、Jinghui Cheng、Jiaoyan Liu 等 5 位作者2014-10-31New Journal of Chemistry

AIE-active salicylaldehyde azines (SAs) display strong blue, green, and red fluorescence with large Stokes shifts in MeCN–water and solid medium and can be used as ratiometric fluorescent pH probes in water and test paper.

Click Chemistry and ApplicationsLuminescence and Fluorescent MaterialsMolecular Sensors and Ion Detection

Tailored design of boron-doped diamond electrodes for various electrochemical applications with boron-doping level and sp2-bonded carbon impurities

Takeshi Watanabe、Yuki Honda、Kazuhiro Kanda 等 4 位作者2014-10-31physica status solidi (a)

The effects of sp2-bonded carbon impurities on the electrochemical properties of boron-doped diamond were investigated in moderately ([B] < 1020 cm−3) and heavily ([B] > 1021 cm−3) boron doping levels. Significant influences of sp2-bonded carbon impurities, which show glassy carbon-like electrochemical properties afte…

Diamond and Carbon-based Materials ResearchElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

BaFe2Se3: A HighTCMagnetic Multiferroic with Large Ferrielectric Polarization

Shuai Dong、Jun‐Ming Liu、Elbio Dagotto2014-10-31Physical Review Letters

The iron selenides are important because of their superconducting properties. Here, an unexpected phenomenon is predicted to occur in an iron-selenide compound with a quasi-one-dimensional ladder geometry: ${\mathrm{BaFe}}_{2}\mathrm{S}{\mathrm{e}}_{3}$ should be a magnetic ferrielectric system, driven by its magnetic…

Iron-based superconductors researchMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Proton transport through one atom thick crystals

S. Hu、M. Lozada-Hidalgo、F. C. Wang 等 13 位作者2014-10-31arXiv

Graphene is impermeable to all gases and liquids, and even such a small atom as hydrogen is not expected to penetrate through graphene's dense electronic cloud within billions of years. Here we show that monolayers of graphene and hexagonal boron nitride (hBN) are unexpectedly permeable to thermal protons, hydrogen io…

Mesoscale and Nanoscale PhysicsMaterials Science

Nanomorphology of Annealed P3HS and P3HS:PCBM Films for OPV Applications

Samuele Lilliu、Mejd Alsari、Marcus S. Dahlem 等 4 位作者2014-10-31arXiv

Atomic Force Microscopy (AFM) and Grazing Incidence X-Ray Diffraction (GI-XRD) are used to characterize the nanomorphology of spin-coated low (LMW, Mn = 12 kg/mol, regioregularity RR = 84%) and high (HMW, Mn = 39 kg/mol, RR = 98%) molecular weight poly(3-hexylselenophene) (P3HS) films and blend films of P3HS with [6,6…

Materials ScienceSoft Condensed Matter

Spin pumping using an Ni80Fe20 thin film annealed in a magnetic field

Hideki Shimogiku、Naoyuki Hanayama、Yoshio Teki 等 5 位作者2014-10-31arXiv

Spin pumping controlled with the ferromagnetic resonance of an Ni80Fe20 thin film annealed in a magnetic field was performed in order to investigate the simple and efficient generation method of the pure spin current. At the spin-pumping using the Ni80Fe20 on an annealed Pd/Ni80Fe20 stacked structure, the electromotiv…

Materials Science

Clocking the anisotropic lattice dynamics of multi-walled carbon nanotubes by four-dimensional ultrafast transmission electron microscopy

Gaolong Cao、Shuaishuai Sun、Zhongwen Li 等 6 位作者2014-10-31arXiv

Recent advances in the four-dimensional ultrafast transmission electron microscope (4D-UTEM) with combined spatial and temporal resolutions have made it possible to directly visualize structural dynamics of materials at the atomic level. Herein, we report on our development on a 4D-UTEM which can be operated properly…

Mesoscale and Nanoscale PhysicsMaterials Science

Reproducible x-ray reflectometry optimization: statistical analysis of differential evolution fitting of multilayer structural models

Donald Windover、David Gil、Yasushi Azuma 等 4 位作者2014-10-31arXiv

We test the reproducibility of X-ray reflectometry(XRR) measurements and optimizations using an National Metrology Institute of Japan (NMIJ)/National Institute of Advanced Industrial Science and Technology (AIST) pre-standard. Based on bootstrap analysis of repeated refinements, using several CPU-years of time, we pro…

Materials Sciencephysics.ins-det

Engineering relativistic effects in ferroelectric SnTe

Evgeny Plekhanov、Paolo Barone、Domenico Di Sante 等 4 位作者2014-10-31arXiv

Spin-orbit coupling is increasingly seen as a rich source of novel phenomena, as shown by the recent excitement around topological insulators and Rashba effects. We here show that the addition of ferroelectric degrees of freedom to a semiconductor featuring topologically-non-trivial properties, such as SnTe, merges th…

Materials Science

High performance shape memory polyimides based on π–π interactions

Qihua Wang、Yongkang Bai、Yu Chen 等 6 位作者2014-10-31Journal of Materials Chemistry A

The high temperature shape memory properties of polyimides based on π–π interaction are investigated in this study.

Photochromic and Fluorescence ChemistryPolymer composites and self-healingConducting polymers and applications

Supramolecular assembly-induced yellow emission of 9,10-distyrylanthracene bridged bis(pillar[5]arene)s

Nan Song、Daixiong Chen、Meng-Chan Xia 等 8 位作者2014-10-31Chemical Communications

9,10-Distyrylanthracene has been introduced to bridge two pillarenes to form a dimeric host, which can assemble into a linear supramolecular polymer upon cooperatively binding to a neutral guest linker, exhibiting yellow fluorescence emission in solution and solid states.

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Machine learning for many-body physics: The case of the Anderson impurity model

Louis-François Arsenault、Alejandro López‐Bezanilla、O. Anatole von Lilienfeld 等 4 位作者2014-10-31Physical Review B

Machine learning methods are applied to finding the Green's function of the Anderson impurity model, a basic model system of quantum many-body condensed-matter physics. Different methods of parametrizing the Green's function are investigated; a representation in terms of Legendre polynomials is found to be superior du…

Advanced Chemical Physics StudiesMachine Learning in Materials ScienceQuantum many-body systems