Materials Literature
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The infrared spectra of Cu(en)(TCNQ)2 and Cu(en)2(TCNQ)2(en: ethylenediamine, TCNQ: 7,7,8,8-tetracyanoquinodimethane) have been shown to exhibit totally symmetric TCNQ Ag bands activated by a vibronic process in addition to inherently i.r.-active Bu bands. In the spectrum of Cu(en)2(TCNQ)3 some Ag modes were developed…
Bis[1,2,5]thiadiazolo-tetracyanoquinodimethane (1) was prepared and found to form a highly conductive complex with tetrathianaphthacene.
A prerequisite for the aseptic packaging of food is the UHT or HTST process used for sterilizing the food. These processes are defined. The history, microbiology, and engineering principles of aseptic processing and packaging are covered. Attainment of sterility and acceptable levels of spoilage are discussed. Methods…
The catalytic effect of the mercury(II) ion on metalloporphyrin formation provides the basis for determination of the stability constant of the zinc (II) porphyrin, the rate of formation of which is extremely slow in the absence of mercury(II).
Electrochemical properties of {[NBun4][BF4]·3 toluene} are described; the hydrocarbon medium allows, for the first time, the observation of all members of the [Fe4S4(SPh)4]n– electron-transfer Series, n= 1–4.
The hydrogen reduction of a series of alumina- and silica-supported iron–ruthenium catalysts has been studied in situ by iron-57 Mössbauer spectroscopy. The data, complemented by results from temperature-programmed reduction experiments, show that ruthenium enhances the reducibility of iron and that the metal–support…
The experimental approach for carrying out electrochemical impedance measurements for coated metals is described. Models for the impedance behavior have been developed for different coating systems, and methods for the analysis of experimental impedance diagrams in terms of coating and interface properties and their c…
Conformational analysis studies on the tertiary structure of cello-tetraose, methyl-β-cellotetraoside, and single cellulose chains were carried out by using calculation of van der Waal, H-bond, electrostatic, and torsional energy interactions between the atoms and molecular groups in both the skeleton and side chains…
The contents of pyrophosphate-extractable carbon and iron, EDTA-extractable iron, dithionite-EDTA-extractable iron and silicon, total carbon, and sodium hydroxide-extractable silicon were determined in thirty soil samples from Denmark and Tanzania in order to investigate the general influence of organic matter and sil…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTKinetics of displacement and charge transfer reactions probed by SERS: evidence for distinct donor and acceptor sites on colloidal gold surfacesClaude J. Sandroff and D. R. HerschbachCite this: Langmuir 1985, 1, 1, 131–135Publication Date (Print):January 1, 1985Publication H…
Aliphatic esters of rufigallol with formula have been prepared and their phase transitions studied by differential scanning calorimetry, x-ray diffraction, and optical methods. Compounds with 6 < m < 13 give enantiotropic columnar mesophases; those with 7 < m < 9 give also a monotropic mesophase. Both melting temperat…
Compounds of the type [Cu(CN)Ln][L = diethylamine, (1), triethylamine, (2), 4-methylpyridine, (3), or 1,10-phenanthroline, (4)] have been synthesized by recrystallization of copper(I) cyanide from (or with) the parent base and their crystal structures have been determined by single-crystal X-ray diffraction methods; n…
Montmorillonite containing PdCl2 anchored via pendant phosphinated groups in the interiamellar region has been synthesized, characterized, and found to hydrogenate terminal alkenes and alkynes selectively.
Grain boundary fracture in molybdenum was investigated by the four-point bending test at 77 K as a function of misorientation angle, by using bicrystals with various 〈110〉 twist boundaries. Main results obtained are as follows:(1) Fracture always occurs at the grain boundary. (2) The fracture strength and strain to fr…
Abstract CsTe 4 entsteht aus Gemengen von Caesium und Tellur im Molverhältnis 1:4, wenn man diese in abgeschlossenen Ampullen einer Schmelzreaktion bei 570°C unterwirft. Die Elementgemenge stellt man der, indem man CsN 3 und Te (1:4) zusammengibt und anschließend durch kontrollierte Zersetzung des Azids den Stickstoff…
The influence of calcination temperature on alumina and on alumina-supported nickel has been systematically studied. Identification of the nickel species has been made using the techniques of X-ray photoelectron spectroscopy (X.p.s.) and X-ray diffraction (X.r.d.). Hydrogen and oxygen adsorption measurements were used…
Attaching a second metalloporphyrin to a zinc(II) porphyrin via a short flexible chain results in quenching of both excited singlet and triplet states of the ZnII porphyrin. The extent of quenching depends markedly upon the nature of the central metal ion contained within the second porphyrin ring (MnIII≈ FeIII > CuII…
Electrochemically doped poly(N-vinylcarbazole) functions as a positive electrode material for a secondary lithium battery.
In the newly synthesized compound MORA12 [S-4-0-(6 methyl)octylresorcylidene-4'-dodecylaniline], we observed a novel intermediate phase (which we call ${P}^{\mathrm{*}}$) between two tilted smectic liquid-crystal phases, ${C}^{\mathrm{*}}$ and X. The ${C}^{\mathrm{*}}$ phase has a helicoidal structure whereas the X ph…
The relative influence of water–surface and water–cation interactions in hydrates of the charge-deficient expanding-lattice layer silicates montmorillonite and vermiculite have been studied using high-resolution quasi-elastic neutron-scattering (QENS) measurements made with the back-scattering spectrometer at ILL, Gre…