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Studies of the solid‐state thermal degradation of PVC. I. Autocatalysis by hydrogen chloride

K. D. Patel、Areli I. Velazquez、H. S. Calderon 等 4 位作者1992-09-05Journal of Applied Polymer Science

Abstract The thermal degradation of virgin and HCI‐treated PVC in powder form, as well as of PVC films of different thicknesses, has been studied as a function of time and temperature. The rate of dehydrochlorination was determined conductimetrically and from the polyene sequence distributions as obtained by UV spectr…

Polymer Science and PVC

Improved Graphite Damage Model for Predicting Property Changes of HTGR Graphites under Isothermal and Nonisothermal Irradiations

Taketoshi ARAI、H. Cords、Hubertus Nickel1992-09-01Journal of Nuclear Science and Technology

Graphite components of a High Temperature Gas-Cooled Reactor (HTGR) core will be subjected to fast neutron irradiation-induced damages causing changes in engineering properties which are dependent significantly on irradiation temperature and neutron fluence. A Graphite Damage Model (GDM) elaborated to interpret observ…

Nuclear reactor physics and engineeringGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Thermoplastic epoxies from n‐alkylamines

Jan‐Chan Huang、Fan Gu1992-09-01Advances in Polymer Technology

Abstract Thermoplastic epoxy resins have some special applications. In this study, the diglycidyl ether of bisphenol‐A and three different monoamines—butylamine, hexamine, and dodecylamine—at different epoxy–amine ratios were used to make epoxy resins. Relative viscosity, hardness, Vicat softing temperature, volume re…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Controlled potential coulometric method to determine the average titanium oxidation state of titanium chlorides in sodium chloride

Charles E. Baumgartner1992-09-01Analytical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTControlled potential coulometric method to determine the average titanium oxidation state of titanium chlorides in sodium chlorideCharles E. BaumgartnerCite this: Anal. Chem. 1992, 64, 17, 2001–2002Publication Date (Print):September 1, 1992Publication History Published onlin…

Thermal and Kinetic Analysis

Three‐dimensional calculation of linear magnetic fields of not axisymmetrical winding arrangements in transformers

T. H. Janisch、G. Buchgraber1992-09-01European Transactions on Electrical Power

Abstract Whenever asymmetrical winding arrangements of transformers are to investigate, the use of three‐dimensional calculation methods is essential. In this paper an alternative method to the classical Finite Element formulation is used, based on reduced and total scalar potentials. The basic equations of this metho…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsInduction Heating and Inverter Technology

X-Ray Powder Diffraction Data for Tetragonal Zirconia Solid Solutions in System ZrO 2 -YTaO 4

Dae‐Joon Kim、C. R. Hubbard1992-09-01Powder Diffraction

Abstract Tetragonal zirconia ( t - ZrCO 2 ) can be stabilized with 15 to 22 mol% YTaO 4 . X-ray powder diffraction data for the end members of the solid solution series Zr 0.76 Y 0.12 Ta 0.12 O 2 and Zr 0.66 Y 0.17 Ta 0.17 O 2 are reported along with lattice parameters across the single phase region. These tetragonal…

Advanced ceramic materials synthesisThermal and Kinetic AnalysisNuclear materials and radiation effects

PmP111. Effects of dopant Nb+5on lead zirconate-titanate

Terumasa Kato、Noriaki Yamada、Atsuo Imai1992-09-01Ferroelectrics

Impurity effects of Nb+5 dopants were investigated on optimum calcination temperatures and grain growth in sintering process. As the amount of Nb+5 dopant increased, optimum calcination temperatures increased. Grain sizes in sintered ceramics decreased in inverse proportion to the amount of Nb+5. Experimental results…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisThermal Expansion and Ionic Conductivity

Nonlinear kinetics of spinodal decomposition, and dissolution of inhomogeneities formed by spinodal decomposition in polymer blends

A. Ziya Akcasu、Burak Erman、İvet Bahar1992-09-01Makromolekulare Chemie Macromolecular Symposia

Abstract Nonlinear kinetics of both spinodal decomposition at early stages, and the dissolution of homogeneities formed during spinodal decomposition, is studied. Variation of the scattering intensity during a complete cycle consisting of a step temperature change from T 1 in the one‐phase region to T 2 in the two‐pha…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesThermal and Kinetic Analysis

Actin-Actin Contact: Inhibition of Actin-Polymerization by Subdomain 4 Peptide Fragments1

Kouichirou Hori、Fumi Morita1992-09-01The Journal of Biochemistry

F-Actin was digested with alpha-chymotrypsin in 6 M urea, and two peptide fragments from subdomain 4 of actin molecule [Kabsch, W., Mannherz, H.G., Suck, D., Pai, E.F., & Holmes K.C. (1990) Nature 347, 37-44] were purified by reverse-phase HPLC and Sephadex G-50 gel filtration. The peptide fragments were identified as…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesMarine Biology and Environmental Chemistry

Relation of eddy current losses with domain wall movement of very thin 3%Si-Fe strip-wound cores

Y.H. Kim、M. Yamaguchi、K.I. Arai1992-09-01IEEE Transactions on Magnetics

The authors discuss the relation of eddy current losses to dynamic domain behavior for very thin 3%Si-Fe strip-wound cores up to 5 kHz. The dynamic domain behavior was observed by using scanning electron microscope. The stripe domain structure B/sub 8/, and H/sub c/ were recovered after the strip was wound into a core…

Silicon Carbide Semiconductor TechnologiesMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

A low loss transformer using a rotating magnetic field

T. Nakata、N. Takahashi、Koji Fujiwara 等 5 位作者1992-09-01IEEE Transactions on Magnetics

A type of transformer with reduced iron loss, which is excited by a semirotating magnetic field, has been investigated. Factors (method of excitation and slits in the core) affecting iron losses are examined. The iron loss of this type of transformer can be reduced below the material loss as measured for normal AC exc…

Magnetic Properties and ApplicationsPower Transformer Diagnostics and InsulationNon-Destructive Testing Techniques

One-dimensional vibrations and disorder: TheZr1−xHfxS3solid solution

A. Aı̈t-Ouali、S. Jandl、P. Marinier 等 5 位作者1992-09-01Physical review. B, Condensed matter

In the trichalcogenide family of compounds ${\mathrm{Zr}}_{1\mathrm{\ensuremath{-}}\mathit{x}}$${\mathrm{Hf}}_{\mathit{x}}$${\mathrm{S}}_{3}$ there is a frequency range where the optic modes are expected to be describable by a simple one-dimensional model. It is shown that the disorder-induced linewidth in the relevan…

Organic and Molecular Conductors ResearchIron-based superconductors researchInorganic Chemistry and Materials

Domain Reorientation Effects on the Temperature Dependence of Piezoelectric Properties in Pb(Zn1/3Nb2/3)O3-PbTiO3-PbZrO3 Ceramics

Sung-Kwon Wi Sung-Kwon Wi、Ho‐Gi Kim1992-09-01Japanese Journal of Applied Physics

For the PZN-PT-PZ ceramic system, the difference in the temperature characteristics of piezoelectric properties between the tetragonal phase and the rhombohedral one was studied from the viewpoint of a domain reorientation mechanism. From the measurement of thermal expansion and the change of high-temperature X-ray di…

Ferroelectric and Piezoelectric MaterialsUltrasonics and Acoustic Wave PropagationAcoustic Wave Resonator Technologies

Thermomagnetic study of the high-temperature oxidation behavior of Nd-Fe-B permanent magnets and powders

D. Lemarchand、Jérôme Delamare、P. Vigier1992-09-01Journal of Applied Physics

Thermomagnetic measurements were used to determine the oxidation kinetics of bulk and powdered Nd-Fe-B magnets under a pressure of 1 Pa in the 360–600 °C temperature range. Those conditions are roughly similar to those undergone by sintered or rapidly quenched magnets during heat treatment. The first step of the oxida…

Rare-earth and actinide compoundsHydrogen Storage and MaterialsMagnetic Properties of Alloys

Palygorskite occurrence in northwest Nelson, South Island, New Zealand

R. Soong1992-09-01New Zealand Journal of Geology and Geophysics

Abstract Palygorskite has been identified at Canaan, Thomson Hill, and Riwaka in northwest Nelson, South Island. The clay mineral appears in sheet‐like form; hand‐picked specimens have been examined by chemical analysis, X‐ray diffraction (XRD), infrared spectroscopy (IR), and transmission and scanning electron micros…

Geological and Geochemical AnalysisSoil and Unsaturated FlowClay minerals and soil interactions

Elemental Lead by XPS

Michael J. Bozack、Kenneth W. Bryant1992-09-01Surface Science Spectra

An XPS spectrum of elemental lead (Pb) is presented. The Pb foil was supplied commercially (Goodfellow Corp.) as a 0.1 mm thick specimen of quoted purity 99.95%. The BE range 1000–0 eV is documented.

Electron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysisSurface and Thin Film Phenomena

Magnetic properties of (Sm/sub 1-x/R/sub x/)/sub 2/ Fe/sub 17/N/sub y/ (R=Dy, Er) compounds

O. Tegus、Y. Lu、Ning Tang 等 9 位作者1992-09-01IEEE Transactions on Magnetics

The effects of the substitutions of Dy and Er for Sm on the crystal structure and magnetic properties of Sm/sub 2/Fe/sub 17/ and Sm/sub 2/Fe/sub 17/N/sub y/ compounds have been investigated. The structures of (Sm/sub 1-x/R/sub x/)/sub 2/ Fe/sub 17/N/sub y/ compounds with R=Dy and Er and the hosts change from Th/sub 2/…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

PmP113. Frequency dependence of the piezoelectric d31coefficient as a function of ceramic tetragonality

Jesús Mora Vicente、B. Jiménez1992-09-01Ferroelectrics

Measurements have been made of the complex piezoelectric coefficient (d31), by a quasistatic method, so as to determine its real and imaginary components as a function of frequency (f = 10−3 - 103 Hz) and temperature. Results obtained with Ca-modified lead titanate and lead lanthanum titanate-zirconate ceramic samples…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesOptical and Acousto-Optic Technologies

Electrochemical characterization of vacuum sintered copper alloyed austenitic stainless steel

F. Deflorian、L. Ciaghi、J. Kazior1992-09-01Materials and Corrosion

Abstract The aim of this work is the study of the electrochemical behaviour and corrosion resistance of copper alloyed vacuum sintered stainless steel. The presence of copper can improve the passivability of sintered stainless steel and, as a consequence, the corrosion resistance; moreover, vacuum sintering allows mat…

Hydrogen embrittlement and corrosion behaviors in metalsAdvanced materials and compositesPowder Metallurgy Techniques and Materials

Flight capabilities of high-speed-missile radome materials

James Kouroupis1992-09-01OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)

Flight-performance modeling is conducted to compare the qualities of four radome materials in the light of three radome materials currently in use. The current radome materials are slip-cast fused silica, Rayceram 8, and Pyroceram 9606, and the ceramics tested for possible application are celsian, nitroxyceram, hot-pr…

Advanced ceramic materials synthesisHigh-Velocity Impact and Material BehaviorGraphite, nuclear technology, radiation studies