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Significant entry of tubocurarine into the brain of rats by adsorption to polysorbate 80–coated polybutylcyanoacrylate nanoparticles: Anin situbrain perfusion study

R. N. Alyautdin、E. B. Tezikov、Peter Ramge 等 6 位作者1998-01-01Journal of Microencapsulation

The possibility of using polysorbate 80-coated polybutylcyanoacrylate nanoparticles to deliver low molecular polar hydrophilic drugs to the CNS has been studied. Tubocurarine (a quaternary ammonium salt) does not penetrate the normal intact blood-brain barrier. However, the injection of this drug directly into the cer…

Nanoparticle-Based Drug DeliverySupramolecular Chemistry and ComplexesLanthanide and Transition Metal Complexes

The response of T4 lysozyme to large‐to‐small substitutions within the core and its relation to the hydrophobic effect

Jian Xu、Walter A. Baase、Enoch P. Baldwin 等 4 位作者1998-01-01Protein Science

To further examine the structural and thermodynamic basis of hydrophobic stabilization in proteins, all of the bulky non-polar residues that are buried or largely buried within the core of T4 lysozyme were substituted with alanine. In 25 cases, including eight reported previously, it was possible to determine the crys…

Protein Structure and DynamicsEnzyme Structure and FunctionHemoglobin structure and function

Synthesis of MCM-48 single crystals

Ji Man Kim、Ryong Ryoo1998-01-01Chemical Communications

Truncated rhombic dodecahedral crystals of the mesoporous molecular sieve MCM-48 are synthesised by a hydrothermal procedure using sodium silicate, hexadecyltrimethylammonium bromide and various kinds of alcohol.

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisPorphyrin and Phthalocyanine Chemistry

Large aligned-nanotube bundles from ferrocene pyrolysis

C. N. R. Rao、Rahul Sen1998-01-01Chemical Communications

Aligned-nanotube bundles have been obtained in copious quantities by the pyrolysis of ferrocene or ferrocene–acetylene mixtures.

Carbon Nanotubes in CompositesGraphene research and applicationsBoron and Carbon Nanomaterials Research

Structure and molecular magnetism of the rutile-related compounds M(dca)2, M = CoII, NiII, CuII, dca = dicyanamide, N(CN)2−

Stuart R. Batten、Richard Robson、Stuart R. Batten 等 6 位作者1998-01-01Chemical Communications

The isomorphous rutile-related network structures of Co(dca)2, Ni(dca)2 and Cu(dca)2, dca = dicyanamide, N(CN)2–, are shown to behave as ferromagnets (Tc = 9 and 20 K) and a near-paramagnet, respectively.

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal Complexes

The Chemistry of Conducting Polythiophenes

Richard D. McCullough1998-01-01Advanced Materials

Directing the structure and function of polythiophenes (PTs) can lead to remarkable enhancements in the electronic and photonic properties of the resultant materials, as discussed in this comprehensive review of the chemistry and synthesis of PTs. The Figure illustrates the use of heteroatom-functionalized PTs as chem…

Molecular Sensors and Ion DetectionConducting polymers and applicationsPorphyrin and Phthalocyanine Chemistry

Influence of the nature of the organic precursor on the textural and chemical properties of silsesquioxane materials

Geneviève Cerveau、Robert J. P. Corriu、Cédric Lepeytre 等 4 位作者1998-01-01Journal of Materials Chemistry

The hydrolytic sol-gel polymerization of molecular organosilicon precursors with a rigid geometry C6H4[Si(OMe)3]2-1,4 and C6H3[Si(OMe)3]3-1,3,5 2 was investigated and compared to the results obtained with precursors having a more flexible structure C6H4RR-1,4 [R=R=CH2Si(OMe)3 3; R=R=CH2CH2Si(OMe)3 4]. Compounds 1-4 ha…

Dental materials and restorationsSilicone and Siloxane ChemistryMaterial Properties and Applications

Investigation of the Electrochemical Corrosion Behavior and Passive Film for Fe-Mn, Fe-Mn-Al, and Fe-Mn-Al-Cr Alloys in Aqueous Solutions

Xingrui Zhu、Y. S. Zhang1998-01-01CORROSION

The corrosion behavior of austenitic Fe-(17 wt% to 31 wt%) Mn-(1 wt% to 9 wt%) Al-(1 wt% to 7 wt%) Cr alloys in different aqueous solutions and the corrosion protection mechanism induced by adding Al or Al and Cr, were studied by anodic polarization and Auger electron spectroscopic/x-ray photo-electron spectroscopic (…

Corrosion Behavior and InhibitionHigh-Temperature Coating BehaviorsHydrogen embrittlement and corrosion behaviors in metals

A highly conducting partially oxidized salt of axially substituted phthalocyanine. Structure and physical properties of TPP[Co(Pc)(CN)2]2 {TPP=tetraphenylphosphonium, [Co(Pc)(CN)2]=dicyano(phthalocyaninato)cobalt(III)}

Hiroyuki Hasegawa、T. Naito、Tamotsu Inabe 等 5 位作者1998-01-01Journal of Materials Chemistry

A highly conducting partially oxidized salt of TPP[Co(Pc)(CN)2 ]2 can be obtained by electrocrystallization of TPP[Co(Pc)(CN)2 ]. The crystal is composed of one-dimensional TPP arrays surrounded by slipped-stacked one-dimensional [Co(Pc)(CN)2 ] chains. The electrical conductivity at room temperature is quite high, 120…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryOrganic and Molecular Conductors Research

Source of Palygorskite in Gypsiferous Aridisols and Associated Sediments from Central Iran

Hossein Khademi1998-01-01Clay Minerals

A B S T R A C T: Arid soils in central Iran that evolved from the weathering ofpost-Tethyan sediments contain palygorskite. Clay fractions of gypsiferous oils and their associated sediments from different landforms from central Iran were investigated. Palygorskite was the dominant silicate clay mineral in clay fractio…

Groundwater and Isotope GeochemistryClay minerals and soil interactionsGeological and Geophysical Studies Worldwide

Complementary application of electron microscopy and micro-Raman spectroscopy for microstructure, stress, and bonding defect investigation of heteroepitaxial chemical vapor deposited diamond films

Johann Michler、Y. von Kaenel、J.O. Stiegler 等 4 位作者1998-01-01Journal of Applied Physics

The evolution and interdependence of microstructure, stress, and bonding defects of heteroepitaxial diamond films deposited on silicon substrates has been investigated by applying scanning electron microscopy, transmission electron microscopy (TEM), and micro-Raman spectroscopy to the same places in the films. For thi…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Phonons in nanocrystallineNi3Fe

H. N. Frase、Brent Fultz、J. L. Robertson1998-01-01Physical review. B, Condensed matter

Inelastic neutron-scattering spectra were measured to obtain the phonon density of states (DOS) of nanocrystalline fcc ${\mathrm{Ni}}_{3}\mathrm{Fe}.$ The materials were prepared by mechanical alloying, and were also subjected to heat treatments to alter their crystallite sizes and internal strains. In comparison to m…

Microstructure and mechanical propertiesHigh-pressure geophysics and materialsRare-earth and actinide compounds

Incorporation of A2Q into HgQ and Dimensional Reduction to A2Hg3Q4 and A2Hg6Q7 (A = K, Rb, Cs; Q = S, Se). Access of Li Ions in A2Hg6Q7 through Topotactic Ion-Exchange

Enos A. Axtell、Younbong Park、Konstantinos Chondroudis 等 4 位作者1998-01-01Journal of the American Chemical Society

The synthesis of the one-dimensional K 2 Hg 3 Q 4 (Q = S, Se) and Cs 2 Hg 3 Se 4 and the three-dimensional A 2 Hg 6 S 7 (A = K, Rb, Cs), and A 2 Hg 6 Se 7 (A = Rb, Cs) in reactive A 2 Q x fluxes is reported. Pale yellow, hexagonal plates of K 2 Hg 3 S 4 crystallize in space group Pbcn, with a = 10.561(5) Å, b = 6.534(…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Thermal Decomposition of Urea and Urea Derivatives by Simultaneous TG/(DTA)/MS.

Jian Ping Chen、Kimio Isa1998-01-01Journal of the Mass Spectrometry Society of Japan

Simultaneous TG-MS (TG: thermogravimetry, MS: mass spectrometry) measurement, a mass spectrometer connected with a thermogravimetry by a transfer line and an interface or by the skimmer coupling, was used to investigate decomposition of urea.A simple decomposition reaction of urea to form ammonia and cyanic acid (or i…

Thermal and Kinetic Analysis

A pulsed GTEM system for UHF sensor calibration

M.D. Judd、O. Farish1998-01-01IEEE Transactions on Instrumentation and Measurement

A system for measuring the sensitivity of electric field sensors at UHF using a novel gigahertz transverse electromagnetic (GTEM) cell is described. The system was developed to enable calibration of UHF couplers that are used to detect insulation defects in gas insulated substations. The frequency response of a sensor…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaMagneto-Optical Properties and Applications

Freshwater Algae from the Mattagami Formation (Albian), Ontario: Paleoecology, Botanical Affinities, and Systematic Taxonomy

Pierre Zippi1998-01-01Micropaleontology

Pierre A. Zippi, Freshwater Algae from the Mattagami Formation (Albian), Ontario: Paleoecology, Botanical Affinities, and Systematic Taxonomy, Micropaleontology, Vol. 44, Supplement 1: Freshwater Algae from the Mattagami Formation (Albian), Ontario: Paleoecology, Botanical Affinities, and Systematic Taxonomy (1998), p…

Diatoms and Algae Research

Carbon nanotubes

M. S. Dresselhaus、G. Dresselhaus、Peter Eklund 等 4 位作者1998-01-01Physics World

Carbon nanotubes are unique nanostructures with remarkable electronic and mechanical properties. Interest from the research community first focused on their exotic electronic properties, since nanotubes can be considered as prototypes for a one-dimensional quantum wire. As other useful properties have been discovered,…

Carbon Nanotubes in Composites

Nonadiabatic scanning calorimeter

Haruhiko Yao、Kenji Ema、Carl W. Garland1998-01-01Review of Scientific Instruments

A high-resolution computerized calorimeter capable of fully automatic operation in either ac or relaxation modes is described. Emphasis is given to a new version of the relaxation technique in which the heater power is ramped linearly in time. This improvement results in superior performance and convenience in studyin…

Material Dynamics and PropertiesSpectroscopy and Quantum Chemical Studiesthermodynamics and calorimetric analyses

Green's function boundary conditions in two-dimensional and three-dimensional atomistic simulations of dislocations

S.I. Rao、Cuauhtemoc Benixoo Guzmán Hernández、Jeff Simmons 等 5 位作者1998-01-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

A method for dynamically updating the boundary conditions of atomistic simulations is presented. The lattice Green's function boundary relaxation method, originally introduced by Sinclair et al. in 1978, is extended to treat three-dimensional (3D) simulations. The boundary conditions for two-dimensional (2D) and 3D de…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsAluminum Alloys Composites Properties