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Cholesterol-based dimeric liquid crystals: synthesis and mesomorphic behaviour

C. V. Yelamaggad、S. Anitha Nagamani、Uma S. Hiremath 等 4 位作者2001-07-01Liquid Crystals

Chiral non-symmetric dimeric liquid crystals consisting of a cholesteryl ester moiety as chiral entity and a biphenyl aromatic core, interconnected through n-butyl (C4) or n-pentyl (C5) parity alkylene spacers, have been synthesized and investigated for their liquid crystalline properties. All the dimers exhibit enant…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Stack gate PZT/Al2O3 one transistor ferroelectric memory

Albert Chin、M.Y. Yang、Chia‐Liang Sun 等 4 位作者2001-07-01IEEE Electron Device Letters

We have developed a single transistor ferroelectric memory using stack gate PZT/Al/sub 2/O/sub 3/ structure. For the same /spl sim/40 /spl Aring/ dielectric thickness, the PZT/Al/sub 2/O/sub 3//Si gate dielectric has much better C-V characteristics and larger threshold voltage shift than those of PZT/SiO/sub 2//Si. Be…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesElectronic and Structural Properties of Oxides

Faceted drops on heterogeneous surfaces

Thomas Cubaud、Marc Fermigier2001-07-01Europhysics Letters (EPL)

We report an experimental study of the shape of large liquid drops spreading on surfaces with patterns of wettability. A heterogeneous surface exhibits multiple energy minima of free energy for the three-phase system. In particular, when the distribution of defects on the substrate is periodic (square or hexagonal), i…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferNanomaterials and Printing Technologies

Predicting Garment Drape with a Fuzzy-Neural Network

Jintu Fan、Edward Newton、Raymond Au 等 4 位作者2001-07-01Textile Research Journal

This paper proposes to use a fuzzy-neural network system to predict and display the drape image of garments made of different fabrics and styles. The new approach is used to develop a prototype drape prediction system to predict the drape of a lady's dress style made from different fabrics. The advantages and disadvan…

3D Shape Modeling and AnalysisTextile materials and evaluationsColor Science and Applications

In Situ Reaction Synthesis of Silicon Carbide–Boron Nitride Composites

Guojun Zhang、Tatsuki Ohji2001-07-01Journal of the American Ceramic Society

SiC–BN composites were prepared via the proposed in situ reaction, which used Si 3 N 4 , B 4 C, and carbon as reactants. Adding SiC powder to the reactants controlled the BN content in the composite. For comparison, SiC–BN composites with the same phase compositions were produced via conventional processing. The in si…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchAdvanced materials and composites

Magnetic properties of high frequency Ni-Zn ferrites doped with CuO

Ovidiu Florin Caltun、Leonard Spînu、Al. Stancu2001-07-01IEEE Transactions on Magnetics

Cu substituted Ni-Zn ferrites, with different copper content, were prepared by a conventional ceramic technique. Structural and magnetic properties of the ferrites were characterized by X-ray diffraction, scanning electron microscopy, frequency dependent power loss, and high frequency (10/sup 6/-10/sup 9/ Hz) permeabi…

Magnetic properties of thin filmsMagnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materials

One-Pot Synthesis of Novel Branched Polylactide Through the Copolymerization of Lactide with Mevalonolactone

Fumitaka Tasaka、Yuichi Ohya、Tatsuro Ouchi2001-07-01Macromolecular Rapid Communications

Polylactide, which is a biodegradable and bio-absorbable polymer having low immunogenicity and good biocompatibility, has been mainly studied for biomedical applications. Branched polymers have different rheological and mechanical properties compared with their linear counterparts owing to their molecular architecture…

biodegradable polymer synthesis and properties

Segmental Mobility in Phosphorus-Containing Dendrimers. Studies by Fluorescent Spectroscopy

Laurent Brauge、Anne‐Marie Caminade、Jean‐Pierre Majoral 等 5 位作者2001-07-01Macromolecules

Steady-state fluorescence spectra and decays of excitations of a phosphorus-containing dendrimer labeled with 12 internal labels and of an iminophosphorane model compound bearing two labels dissolved in acetonitrile, diglyme, 1,4-dioxane, triethylene glycol, and cyclohexanol revealed that the interior of dendrimers co…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

A Better Enzyme to Cope with Cold

Ádám Svingor、József Kardos、István Hajdú 等 5 位作者2001-07-01Journal of Biological Chemistry

3-isopropylmalate dehydrogenase (IPMDH) from the psychrotrophic bacterium Vibrio sp. I5 has been expressed in Escherichia coli and purified. This cold-adapted enzyme is highly homologous with IPMDHs from other organisms, including mesophilic E. coli and thermophilic Thermus thermophilus bacteria. Its molecular propert…

Protein Structure and DynamicsEnzyme Catalysis and ImmobilizationEnzyme Structure and Function

Solvothermal Synthesis, Crystal Structure, and Thermoanalytical Investigations of the New Layered Thioantimonate(III) [Fe(C4H13N3)2]Sb6S10 · 0.5 H2O

R. Stähler、Christian Näther、Wolfgang Bensch2001-07-01European Journal of Inorganic Chemistry

The novel thioantimonate(III) [Fe(C4H13N3)2]Sb6S10 · 0.5 H2O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b = 8.5697(4), c = 24.620(2) Å, β =…

Crystal Structures and PropertiesX-ray Diffraction in CrystallographyMineralogy and Gemology Studies

Maleic anhydride modification of polyolefin in an internal mixer and a twin‐screw extruder: Experiment and kinetic model

Jaehyug Cha、James L. White2001-07-01Polymer Engineering and Science

Abstract There has been little effort. to quantitatively understand graft copolymerization in batch and continuous mixers. Little information exists on the evolution of grafting reactions with respect to residence time in an internal mixer or along the screw axis in a twin‐screw extruder. In this study, maleic anhydri…

Polymer crystallization and propertiesMicroplastics and Plastic PollutionRecycling and Waste Management Techniques

Microstructural Evolution in Liquid‐Phase‐Sintered SiC: Part I, Effect of Starting Powder

Huiwen Xu、Tania Bhatia、S. Deshpande 等 6 位作者2001-07-01Journal of the American Ceramic Society

The effect of starting SiC powder (β‐SiC or α‐SiC), with simultaneous additions of Al 2 O 3 and Y 2 O 3 , on the microstructural evolution of liquid‐phase‐sintered (LPS) SiC has been studied. When using α‐SiC starting powder, the resulting microstructures contain hexagonal platelike α‐SiC grains with an average aspect…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Growth and characterization of mesoporous silica films

Karen J. Edler、S.J. Roser2001-07-01International Reviews in Physical Chemistry

The synthesis of surfactant-templated silicate materials has developed rapidly over the past decade. The uniform controlled pore sizes created in the amorphous silicate framework by this method show promise as catalyst supports, sensors, filtration membranes and in a variety of optoelectronic applications. Formation o…

Mesoporous Materials and CatalysisSilicone and Siloxane Chemistry

Surface treatment and characterization of PMMA, PHEMA, and PHPMA

Hyuneui Lim、Yeonhee Lee、Seunghee Han 等 5 位作者2001-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Poly(methylmethacrylate) (PMMA), poly(2-hydroxyethyl methacrylate (PHEMA), and poly(2-hydroxypropyl methacrylate) (PHPMA) were modified to improve the wettability by two techniques: plasma and plasma source ion implantation. The modified surfaces were characterized to investigate the dependence of the modification and…

Surface Modification and SuperhydrophobicityDiamond and Carbon-based Materials ResearchPolymer Nanocomposite Synthesis and Irradiation

Effect of compatibilization on the breakup of polymeric drops in shear flow

Sachin Velankar、Peter Van Puyvelde、Jan Mewis 等 4 位作者2001-07-01Journal of Rheology

A block copolymer may be added as a compatibilizer during polymer processing in order to promote intimate mixing of thermodynamically immiscible homopolymers. The action of this compatibilizer can only partially be attributed to its effect on the interfacial tension between the immiscible homopolymers. Here the additi…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Science and PVC

Metal/ceramic interfaces: a microscopic analysis

J. Th. M. De Hosson、Bart J. Kooi2001-07-01Surface and Interface Analysis

Abstract This contribution treats the fundamental and practical aspects of the analysis of interfaces between metals and ceramic materials. It is shown that, in principle at least, it is possible to assess the bond strength by investigating the atomic structure of the dislocation cores. We have chosen to exemplify our…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesHigh Temperature Alloys and Creep

CrO2 by XPS: Comparison of CrO2 Powder to CrO2 Films on TiO2(110) Single Crystal Surfaces

Heather A. Bullen、Simon J. Garrett2001-07-01Surface Science Spectra

Chromium dioxide is a ferromagnetic metallic oxide utilized in data storage applications. Here, the XP spectrum of CrO2 bulk powder is compared to a CrO2(110) film grown on a TiO2(110) single crystal surface by chemical vapor deposition. The spectra compare the Cr 2p and O 1s regions for the two materials. In both mat…

ZnO doping and propertiesCatalytic Processes in Materials ScienceCopper-based nanomaterials and applications

Refinement of the atomic structure of CdTe single crystals

М. Х. Рабаданов、И. А. Верин、Y. Ivanov 等 4 位作者2001-07-01Crystallography Reports

A comparative refinement of the anharmonic and disordered models of the atomic structure was performed based on precision X-ray diffraction data sets collected from a CdTe single crystal at 295, 376, 491, and 583 K. Although both models provide the asymmetric contributions of Cd and Te to the structure factors, the an…

Quantum Dots Synthesis And PropertiesX-ray Diffraction in CrystallographyThermodynamic and Structural Properties of Metals and Alloys

Transient Electromagnetic Phenomena in the Secondary Circuits of Voltage and Current Transformers in GIS (Measurements and Calculations)

A.M. Miri、Zlatan Stojković2001-07-01IEEE Power Engineering Review

This paper presents numerical and experimental evaluations of the transient behavior of gas insulated substations (GIS). The electrical equivalent circuits chosen to represent the main components of GIS are implemented in the electro-magnetic transients program (EMTP). The effect of mutual couplings between phases are…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaThermal Analysis in Power Transmission

Kinetics and Mechanism for the Oxidation of CS2 and COS at High Temperature

Yoshinori Murakami、Masami Kosugi、Kenji Susa 等 5 位作者2001-07-01Bulletin of the Chemical Society of Japan

Abstract The rate constants for the thermal decompositions of CS2 and COS were investigated by measuring the time profiles of S atom using atomic resonance absorption spectroscopy behind the incident shock of CS2/Ar or COS/Ar mixtures, and the rate constants were determined to be k = (4.0 ± 0.1) × 1014 exp (−295 ± 20…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsIndustrial Gas Emission Control