Materials Literature
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Layer-by-layer deposition of polyelectrolytes on porous supports is a convenient method for producing ultrathin membranes with moderate ion-transport selectivities. This study shows that the capping of poly(styrene sulfonate) (PSS)/poly(allylamine hydrochloride) (PAH) membranes with a few layer pairs of poly(acrylic a…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTPolystyrene Bead-Assisted Self-Assembly of Microstructured Silica Hollow Spheres in Highly Alkaline MediaGuangshan Zhu, Shilun Qiu, Osamu Terasaki, and Yen WeiView Author Information Department of Chemistry and State Key Laboratory of Inorganic Synthesis & Preparative…
NMR spectroscopy and computer modeling were used to characterize tiopronin monolayer-protected gold clusters (MPCs). These MPCs contain gold cores with a distribution of radii ranging from 0.4 to 2.6 nm. NOESY and HMQC spectra yielded assignments for all NMR sensitive nuclei in the tiopronin ligands. DOSY and T 2 expe…
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We report a study of oxygen isotope effects on low temperature specific heat, magnetization, and resistivity of La$_{1-x}$Ca$_{x}$MnO$_{3}$ and (La$_{1-y}$Pr$_{y})_{0.67}$Ca$_{0.33}$MnO$_{3}$. For the metallic compositions of La$_{1-x}$Ca$_{x}$MnO$_{3}$ and for charge-ordered La$_{0.5}$Ca$_{0.5}$MnO$_{3}$ no change in…
Using density-functional theory (DFT) we calculate the Gibbs free energy to determine the lowest-energy structure of a RuO_2(110) surface in thermodynamic equilibrium with an oxygen-rich environment. The traditionally assumed stoichiometric termination is only found to be favorable at low oxygen chemical potentials, i…
We discuss the rich vibrational dynamics of nanometer-scale semiconducting and insulating crystals as probed by localized electronic impurity states, with an emphasis on nanoparticles that are only weakly coupled to their environment. Two principal regimes of electron-phonon dynamics are distinguished, and a brief sur…
Scaling theory, duality symmetry, and numerical simulations of a random network model are used to study the magnetoresistance of a metal/insulator/perfect conductor composite with a disordered columnar microstructure. The phase diagram is found to have a critical line which separates regions of saturating and non-satu…
The ultrafast time-dependence of the energy absorption of covalent solids upon excitation with femtosecond laser pulses is theoretically analyzed. We use a microscopic theory to describe laser induced structural changes and their influence on the electronic properties. We show that from the time evolution of the energ…
Tissue engineering is a relatively young field that combines engineering, clinical science, and life sciences to, in part, repair or regrow tissues. Adipose tissue has recently become a focus area for tissue engineering, encouraged by the large number of reconstructive, cosmetic, and correctional indications that coul…
The dielectric constant of quantum paraelectric ${\mathrm{EuTiO}}_{3},$ which contains ${\mathrm{Eu}}^{2+}$ with $S=7/2$ spin and ${\mathrm{Ti}}^{4+},$ has been measured under a magnetic field. The dielectric constant shows a critical decrease at the antiferromagnetic ordering of the Eu spins at 5.5 K, as well as a su…
In situ synchrotron wide-angle X-ray diffraction (WAXD) was used to monitor crystallization of isotactic polypropylene (i-PP) in the subcooled melt at 140 °C after step shear. The melt was subjected to a shear strain of 1430% at three different shear rates (10, 57, and 102 s -1 ) using a parallel-plate shear apparatus…
Abstract The complex formation of organogels based on poly( N ‐vinylcaprolactam) (PVCa) and organic dyes [5‐(4‐dimethylaminobenzylidene) rhodanine, α‐nitroso‐β‐naftol, and dithizone] and the properties of the complexes in salt aqueous solutions were studied. PVCa gels absorbed these dyes in organic media (ethanol and…
Syntheses, lanthanide quantitative analyses, mass spectrometry and luminescence spectroscopy, and decay dynamics of crystals containing pentanuclear hetero-lanthanide(III) nanoclusters [(Ln'(5-x)Ln(x))(NO(3))(6)(mu(5)-OH)(mu(4)-L)(2)] (0 < or = x < or = 5), Ln' = Eu or Tb; Ln = La-Nd, Sm-Ho (hereafter Ln'(5-x) Ln(x))…
Homopolymerization of the unsaturated cyclic ester, 6,7-dihydro-2(5 H )-oxepinone (DHO), and copolymerization with ε-caprolactone (εCL) are an easy way to produce unsaturated aliphatic polyesters in a controlled manner. Polymerization of DHO initiated by Al(O i Pr) 3 in toluene at room temperature proceeds by a coordi…
In this work, the synthesis of a novel substituted bisphthalocyanine, the bis[octakis(propyloxy)phthalocyaninato] samarium(III) complex, is reported. Langmuir−Blodgett (LB) films of this compound have been prepared. The influence of the propyloxy groups in the structure of the LB films and in their spectroscopic, chem…
Abstract Segmented polyurethane (PU) films from castor‐oil‐based PU prepolymer with different hard‐segment compositions and nitrolignin (NL) were synthesized. Diisocyanates (DIs), such as 2,4‐tolylene DI (TDI) and 4,4′‐diphenylmethane DI (MDI), 1,4‐butanediol (BDO) as a chain extender, and trimethanol propane (TMP) as…
Heterologous expression of the phaGPs and the phaClPs genes encoding 3-hydroxyacyl acyl carrier protein-coenzyme A transacylase and polyhydroxyalkanoate (PHA) synthase from Pseudomonas sp. 61-3, respectively, was performed in the phbCRe negative mutant, Ralstonia eutropha PHB-4. The recombinant strain of the R. eutrop…
Abstract The synthesis of aromatic polyphosphonates based on the step polymerization of various bisphenols and dichlorophenyl phosphine oxide was investigated. The effect of catalyst, type, concentration, and polymerization time were systematically varied to obtain high molecular weight polymers. Very high molecular w…
The hydroxysilsesquioxanes ( c -C 5 H 9 ) 7 Si 8 O 12 (OH) ( I ) and ( c -C 5 H 9 ) 7 Si 7 O 9 (OH) 2 OSiMePh 2 ( II ) have been studied as model supports for silica-grafted aluminum alkyl species. Treatment of AlMe 3 with I gave polymeric {[( c -C 5 H 9 ) 7 Si 8 O 13 ]AlMe 2 } n ( 1a ), which is readily transformed i…