Materials Literature
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Abstract The present work describes the synthesis of difluoro‐boradiazaindacenes (Bodipy) functionalized at the central 8‐position by phenylamino moieties easily transformable into phenyl amide scaffoldings. Molecules carrying three linear or branched chains were prepared and characterized. An X‐ray crystal structure…
The irradiation of SrTiO$_3$ single crystals with swift heavy ions leads to modifications of the surface. The details of the morphology of these modifications depends strongly on the angle of incidence and can be characterized by atomic force microscopy. At glancing angles, discontinuous chains of nanosized hillocks a…
Time-resolved X-ray microscopy is used to image the influence of alternating high-density currents on the magnetization dynamics of ferromagnetic vortices. Spin-torque induced vortex gyration is observed in micrometer-sized permalloy squares. The phases of the gyration in structures with different chirality are compar…
Dielectric permittivity spectra of yttrium-doped $\mathrm{Eu}\mathrm{Mn}{\mathrm{O}}_{3}$ in the composition range $0\ensuremath{\leqslant}x\ensuremath{\leqslant}0.5$ have been investigated in the terahertz frequency range. Magnetoelectric contributions to the permittivity were observed in all compositions for ac elec…
We present a general framework to describe the simultaneous para-to-ferromagnetic and semiconductor-to-metal transition in electron-doped EuO. The theory correctly describes detailed experimental features of the conductivity and of the magnetization, in particular, the doping dependence of the Curie temperature. The e…
The ground state energy of current carriers in graphene considered as a zero-gap semiconductor was calculated in the two-band approximation. The condition of the electronic (hole) system stability in graphene was obtained. The possibility of the zero-gap semiconductor-semimetal transition was discussed.
We derive and discuss expressions for the temperature-dependent electrostatic polarizabilities of off-center ions holding good under various experimental conditions. At low temperatures and electric-field strengths, all of them reasonably reduce to values characteristic of phonon-coupled two-level systems. Prospects f…
Polyhedral gold nanocrystals with decahedral, icosahedral, and truncated tetrahedral shapes are synthesized by a simple one-pot polyol process in the prescence of poly(vinyl pyrrolidone) (PVP). High PVP concentration up to 360 equiv of the gold precursor, HAuCl 4, effectively stabilizes decahedral seeds to yield unifo…
Abstract An intumescent flame retardant, poly(diaminodiphenyl methane spirocyclic pentaerythritol bisphosphonate) (PDSPB) has been covalently grafted onto the surfaces of multiwalled carbon nanotubes (MWNTs) to obtain MWNT‐PDSPB and according nanocomposites were prepared via melt blending. After high density PDSPB (65…
Quantum dots (QDs) are semiconductor nanocrystals that emit fluorescence on excitation with a light source. They have excellent optical properties, including high brightness, resistance to photobleaching and tunable wavelength. Recent developments in surface modification of QDs enable their potential application in ca…
Converging advances in the development of nanoparticle-based imaging probes and improved understanding of the molecular biology of brain tumors offer the potential to provide physicians with new tools for the diagnosis and treatment of these deadly diseases. However, the effectiveness of promising nanoparticle technol…
Carbon nanotubes are promising new materials for molecular delivery in biological systems. The long-term fate of nanotubes intravenously injected into animals in vivo is currently unknown, an issue critical to potential clinical applications of these materials. Here, using the intrinsic Raman spectroscopic signatures…
ADVERTISEMENT RETURN TO ISSUEPREVAdditions and Correc...Additions and CorrectionsEffect of Growth Rate History on Current Crystal Growth. 2. Crystal Growth of Sucrose, Al(SO4)2·12H2O, KH2PO4, and K2SO4Pareena Pantaraks, Masakuni Matsuoka, and Adrian E. FloodCite this: Cryst. Growth Des. 2008, 8, 3, 1078Publication Dat…
Abstract Nonisothermal and isothermal crystallization kinetics of an aromatic thermoplastic polyimide derived from 3,3′,4,4′‐oxydiphthalic dianhydride and 4,4′‐oxydianiline have been investigated by means of differential scanning calorimetry (DSC) and wide‐angle X‐ray diffraction. The results for nonisothermal crystal…
Abstract A lucky‐drift (LD) model for impact ionization has been recently successfully used to account for avalanche phenomenon in amorphous semiconductors. This model however leads to the dependence of the impact ionization coefficient on the sample thickness. However such dependence has not been confirmed experiment…
Abstract The synthesis, optical properties, spin‐polarization path and magnetic ground‐state studies of a novel nitronyl nitroxide biradical system based on the 2,6‐bis(pyrazolylmethyl)pyridine unit is reported. Besides the presence of σ conjugation and a non‐alternant pathway for spin polarization through the core as…
In situ x-ray reflectivity measurements are used to determine the cooling rate dependent freezing of capillary waves on the oligomer poly(propylene glycol). Only above the glass transition temperature ${T}_{\mathrm{G}}$ can the surface roughness $\ensuremath{\sigma}$ be described by the capillary wave model for simple…
The design of any fusion power plant requires information on the irradiation hardening of low-activation ferritic/martensitic steels beyond the range of most present measurements. Neural networks have been used by Kemp et al ( J. Nucl. Mater. 348 311–28) to model the yield stress of some 1811 irradiated alloys. The sa…
Fine (approximately 18 nm) particles of nickel ferrite were synthesized by the sol-gel technique, and their structural properties were evaluated by X-ray diffraction. Neoprene-based rubber ferrite composites were prepared by incorporating these nickel ferrite powders in the rubber matrix according to a specific recipe…
We report on development and characterization of new photoaligning polymers based on cellulose main chain and side fragments based on cinnamic acid containing alkenyl groups. The materials possess excellent photosensitivity, rather strong anchoring energy, low sticking parameter and can be considered as a promising ca…