Materials Literature
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Epitaxial graphene field effect transistors were fabricated, characterized, and studied. Both the capacitance and transport measurements were performed on the same devices using an electrochemical gate. The quantum capacitance of the epitaxial graphene was extracted, which was similar to that of exfoliated graphene ne…
Two series of tetrahedral phthalocyanine-based systems presenting a central carbon or silicon atom have been synthesized and fully characterized. Ethynyl spacers connect the peripheral Pc units to the central core. Some of the structures contain four identical Pc moieties, whereas other ones bear either an electron-wi…
The effects of Zn2+ and Ti4+ substitutions on the microstructure and properties of low temperature sintered M-type barium hexaferrites Ba(ZnTi)xFe12−2xO19 have been studied in order to adapt the development of low temperature cofired ferrites technology and produce circulators with a multilayer process. It is found th…
We have utilized all-atom molecular dynamics simulations to study bimetallic Pt-Au nanoparticles supported by carbonaceous materials at 700 K. Nanoparticles containing 250 atoms with 25%, 50%, and 75% Pt (${\text{Pt}}_{62}{\text{Au}}_{188}$, ${\text{Pt}}_{125}{\text{Au}}_{125}$, and ${\text{Pt}}_{188}{\text{Au}}_{62}$…
The focusing of electron flow in a symmetric $p\text{\ensuremath{-}}n$ junction (PNJ) of graphene ribbon with different chiralities is studied. Considering the PNJ with the sharp interface, in a armchair ribbon, the electron flow emitting from $(\ensuremath{-}L,0)$ in $n$ region can always be focused perfectly at $(L,…
A conjugated tertiary amine-functionalized polymer, poly(9,9-bis(diethylaminopropyl)-2,7-fluorene-co-1,4-phenylene), was synthesized and employed in the supramolecular functionalization of single-walled carbon nanotubes. The formation of stable solutions in organic solvents, as well as in water upon protonation of the…
We introduce a novel method for fabricating nano- and microscale polyaniline particles containing an entrapped oxidoreductase enzyme for use in biosensing applications. This facile process utilizes the reprecipitation of the emeraldine base form of polyaniline from an aqueous−organic suspension, with hydrophobic colla…
In this paper we report on the light emitting properties of mesoporous silicon vertical-cavity optical resonators with II-VI colloidal quantum dots selectively deposited in the cavity layer. Optical resonator structures exhibit reflectivity stop bands of several hundred nanometres and resonant modes with line-widths l…
Spark plasma sintering technique had been applied to prepare bulk isotropic and anisotropic nanostructured Nd–Fe–B permanent magnets via hot pressing and subsequent hot deformation process. Influences of processing conditions and deformation height reduction on the structure and magnetic properties of the magnets were…
Magnetic nanoparticles for magnetocaloric applications should combine small coercivity, low demagnetization temperature, and high pyromagnetic coefficients while keeping the magnetization as high as possible. The strong dependence of the magnetic properties of cobalt-zinc mixed ferrite with specific dopant species ena…
We demonstrate high-quality epitaxial growth of Heusler alloy Co2FeSi on Ge(111) by molecular beam epitaxy (MBE) at 200 °C. Even for growth at such a low temperature, L21-ordered crystal structure is formed and highly uniform magnetic environments around the Fe sites are realized, by transmission electron diffraction…
We reported the synthesis of CdS semiconductor nanoparticles using a simple one-pot reaction by thermolysis of cadmium acetylacetonate in dodecanethiol. Optical measurements of the as-obtained CdS nanoparticles revealed that their optical properties were closely related to surface effects. Based upon the cocktail of p…
We report an approach to the functionalization of fibers and fiber-based materials that is based on the deposition of reactive azlactone-functionalized polymers and the "reactive" layer-by-layer assembly of azlactone-containing thin films. We demonstrate (i) that the azlactone-functionalized polymer poly(2-vinyl-4,4-d…
Reaction of [(Tp)Fe(CN)(3)](-) [Tp = hydrotris(pyrazolyl)borate] with respective Mn(III) Schiff bases led to the formation of four dimeric molecules, [(Tp)Fe(CN)(3)][Mn(1-napen)(H(2)O)].MeCN.4H(2)O [1; 1-napen = N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato) dianion], [(Tp)Fe(CN)(3)][Mn(5-Clsalen)(H(2)O)] [2; 5-Cl…
Samples of ZnxMg1−xFe2O4 (0≤x≤1) synthesized by the combustion reaction method were investigated by x-ray diffraction, Mössbauer spectroscopy, and Raman spectroscopy. All the samples are found to have a cubic spinel structure and the lattice parameter increases linearly with increasing Zn-content (x). The Mössbauer da…
Nanohybrids with magnetic iron-oxide nanoparticles (FeNPs) embedded in the multilayered silicate clay were synthesized by in situ Fe(2+)/Fe(3+) coprecipitation. The natural clay, sodium montmorillonite (Na(+)-MMT), was first modified with hydrophobic poly(oxypropylene)amine salts (POP at 2000 and 4000 g/mol M(w)). The…
Microcrystals of cuprous oxide (Cu 2 O) samples exhibiting different morphologies such as rods, hexapods, octahedra, and truncated octahedra with hollows were synthesized via a facile hydrothermal method and were then characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). It was observ…
Carbon nanotubes (CNTs), functionalized by a cycloaddition reaction, were studied by ultrahigh vacuum scanning tunneling microscopy (STM). The STM images provided evidence for partial or total unzipping of the outer CNT layer. The formation of graphene ribbons was triggered by the STM tip, under specific operating con…
Commercial magnetic recording media employ magnetic-field-induced two different magnetization states ±M to write data. In this paper, we present a magnetic memory cell in which electric-field-induced two different coercive-field Hc states (i.e., low-Hc and high-Hc) rather than ±M are served as writing data bits. A mul…
New organic−inorganic hybrid materials that combine a bent π-conjugated aromatic core with one linear or branched carbosilane unit have been synthesized and investigated, with respect to their self-assembly in liquid crystalline (LC) phases, by means of polarizing microscopy, differential scanning calorimetry (DSC), X…