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Combustion Behavior and Thermal Oxidative Degradation of EVA Containing Intumescent Flame Retardant

Kun Wu、Shen Min-min、Yuan Hu2010-11-22Polymer-Plastics Technology and Engineering

Microencapsulated ammonium polyphosphate (VAPP) with poly(vinyl alcohol)- melamine-formaldehyde (VMF) shell was introduced in ethylene vinyl acetate copolymer (EVA) to improve its flame retardancy. Due to the presence of VMF shell, VAPP shows better compatibility, flame retardancy and water resistance compared with am…

Flame retardant materials and propertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Glass-Forming Exogenous Silicon Contamination in Solid Oxide Fuel Cell Cathodes

J. Andreas Schuler、Zacharie Wuillemin、Aïcha Hessler‐Wyser 等 4 位作者2010-11-22Electrochemical and Solid-State Letters

Spatially resolved analyses, by energy-dispersive X-ray spectroscopy (EDS) and scanning electron microscopy, allowed the quantification of exogenous Si contamination in a solid oxide fuel cell (SOFC) cathode after operation. The Si quantification, taking into account the endogenous Si impurity level, correlated well w…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Effect of complementary small molecules on the properties of bicomponent hydrogel of riboflavin

Abhijit Saha、Bappaditya Roy、Aluri Esterrani 等 4 位作者2010-11-22Organic & Biomolecular Chemistry

Three new bicomponent hydrogels of riboflavin (R) with salicylic acid (S), dihydroxybenzoic acid (B) and acetoguanamine (D) in 1:1 molar ratio have been reported. FTIR and UV-vis spectra suggest formation of H-bonded complexes in 1:1 molar ratio of the components. The network consists of tape, bar and helical tubes fo…

Hydrogels: synthesis, properties, applicationsSupramolecular Self-Assembly in MaterialsPhotoreceptor and optogenetics research

Mechanisms of Texture Development in Lead-Free Piezoelectric Ceramics with Perovskite Structure Made by the Templated Grain Growth Process

Toshio Kimura、Yi Yuan、Fumito Sakurai2010-11-22Materials

The mechanisms of texture development were examined for BaTiO3 and a (K,Na,Li)(Nb,Ta)O3 solid solution made by the templated grain growth method, and compared with the mechanism in Bi0.5(Na,K)0.5TiO3. The dominant mechanism was different in each material; grain boundary migration in BaTiO3, solid state spreading in Bi…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Solvothermal Syntheses, Crystal Structures, and Thermal Properties of the First Example of Selenidostannates with Mixed Ethylene Polyamine‐Coordinated Transition Metal Complexes as Counterions

Jingjing Liang、Jiangfang Chen、Jing Zhao 等 6 位作者2010-11-22Zeitschrift für anorganische und allgemeine Chemie

Abstract The compounds [Ni(en) 3 ] 2 Sn 2 Se 6 ( 1 ), [Ni(en)(trien)] 2 Sn 2 Se 6 ( 2 ), [Co(en)(trien)] 2 Sn 2 Se 6 ( 3 ), and [Ni 2 (trien) 2 (μ‐trien)]Cl 4 · 2H 2 O ( 4 ) (en = ethylenediamine, trien = triethylenetetramine) were solvothermally synthesized by the reactions of NiCl 2 · 6H 2 O (or CoCl 2 · 6H 2 O), ti…

Crystal Structures and PropertiesOrganometallic Compounds Synthesis and CharacterizationInorganic Chemistry and Materials

Origin of suppressed polarization in BiFeO3 films

Joon‐Seo Park、Seung‐Hyub Baek、Pingping Wu 等 9 位作者2010-11-22Applied Physics Letters

We have studied the origin of suppressed remanent polarization in 4-variant BiFeO3 by correlating microscopic observations of ferroelectric/ferroelastic domain structures and ferroelectric measurements of (001) epitaxial BiFeO3 thin films with 2- and 4-ferroelastic domain variants. Piezoelectric force microscopy revea…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsUnderwater Acoustics Research

Flexible cold cathode with ultralow threshold field designed through wet chemical route

Uday Narayan Maiti、Soumen Maiti、Ranjit Thapa 等 4 位作者2010-11-22Nanotechnology

A flexible cold cathode based on a uniform array of ZnO nanowires over carbon fabrics was designed via a simple wet chemical route. The structural parameters of the nanowires (i.e. length, diameter) as well as their arrangement over the carbon fibers were tailored by adjusting nutrient solution composition and growth…

ZnO doping and propertiesSemiconductor materials and devicesGa2O3 and related materials

Evaluation of a steady-state test of foam stability

Stefan Hutzler、Dörte Lösch、Enda Carey 等 6 位作者2010-11-22The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

We have evaluated a steady-state test of foam stability, based on the steady-state height of a foam produced by a constant velocity of gas flow. This test is mentioned in the book by Bikerman [Foams, Springer, Berlin, 1973] and an elementary theory was developed for it by Verbist et al. [J. Phys. Condens. Matter 8 (19…

Polymer composites and self-healingPickering emulsions and particle stabilizationPolymer Foaming and Composites

Tunable Nanostructure and Photoluminescence of Columnar ZnO Films Grown by Plasma Deposition

Pablo Romero‐Gómez、Johann Toudert、Juan R. Sánchez‐Valencia 等 6 位作者2010-11-22The Journal of Physical Chemistry C

Nanoporous ZnO thin films presenting a tunable nanostructure and photoluminescence (PL) were grown by plasma enhanced vapor deposition on surface oxidized Si substrates. These films consist of c -axis oriented wurtzite ZnO nanocolumns whose topology, crystallinity, and PL can be tuned through the substrate temperature…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Structural characteristics of low torque and ring spun yarns

Ying Guo、XM Tao、Bingang Xu 等 5 位作者2010-11-22Textile Research Journal

In this paper we present a comparative study on the structural characteristics of three-dimensional fiber configurations in low torque and ring spun yarns. Three-dimensional configurations of tracer fibers in the two types of yarns were measured by a continuous measurement system. Critical parameters were obtained, in…

Mechanical Behavior of CompositesTextile materials and evaluationsStructural Analysis and Optimization

Luminescent properties of dye–PMMA composite nanospheres

Xumei Wang、Shuping Xu、Weiqing Xu2010-11-22Physical Chemistry Chemical Physics

The luminescent properties of two types of dye-poly(methyl methacrylate) (PMMA) composite nanospheres were discussed and compared. Dye molecules (Ru(bpy)(3)Cl(2)) were combined with PMMA nanospheres in two strategies: embedding dye molecules during PMMA nanosphere formation (Em-PMMA NPs) and adsorbing dye molecules on…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsLanthanide and Transition Metal Complexes

Fabrication of Ordered Nanostructures of Sulfide Nanocrystal Assemblies over Self-Assembled Genetically Engineered P22 Coat Protein

Liming Shen、Ningzhong Bao、Peter E. Prevelige 等 4 位作者2010-11-22Journal of the American Chemical Society

Ordered ZnS and CdS nanocrystal assemblies have been synthesized by a facile bioinspired approach consisting of an initial self-assembly of engineered proteins into spherical biotemplates and a subsequent protein-directed nucleation and growth of ZnS and CdS nanocrystals symmetrically distributed over the self-assembl…

Quantum Dots Synthesis And PropertiesSilk-based biomaterials and applicationsDiatoms and Algae Research

Atmospheric pressure plasma modification of polyester fabric for improvement of textile-specific properties

Keiko Gotoh、Akemi Yasukawa2010-11-22Textile Research Journal

Polyester fabrics were treated by atmospheric pressure plasma (APP) to enhance hydrophilic behavior of the fiber surfaces. Damage of the fabric due to the APP exposure was not significantly observed. It was found that the APP exposure increased the wettability, oxygen concentration and roughness of the polyester fiber…

Surface Modification and SuperhydrophobicityPlasma Applications and DiagnosticsElectrospun Nanofibers in Biomedical Applications

Microwave-promoted synthesis of polyolesters for lubrication oil using a composite catalyst in a solvent-free procedure

Fengxiu Zhang、Guangxian Zhang2010-11-22Green Chemistry

A rapid, highly efficient and green synthetic approach to polyol esters for lubrication oils is proposed. Using sulfuric acid and p-toluene sulfonic acid as a composite catalyst and C5–C9 straight-chain monocarboxylic acids, with pentaerythritol (PE) and dipentaerythritol (di-PE) as starting materials, a series of lub…

Chemical Synthesis and ReactionsSynthesis and properties of polymersMicrowave-Assisted Synthesis and Applications

Anisotropic Stokes Drag and Dynamic Lift on Cylindrical Colloids in a Nematic Liquid Crystal

Joel B. Rovner、Clayton P. Lapointe、Daniel H. Reich 等 4 位作者2010-11-22Physical Review Letters

We have measured the Stokes drag on magnetic nanowires suspended in the nematic liquid crystal 4-cyano-4'-pentylbiphenyl (5CB). The effective drag viscosity for wires moving perpendicular to the nematic director differs from that for motion parallel to the director by factors of 0.88 to 2.4, depending on the orientati…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsAdvanced Materials and Mechanics

Dielectric Anomaly in Mg Doped ZnO Thin Film Deposited by Sol–Gel Method

Amanpal Singh、Dinesh Kumar、P. K. Khanna 等 5 位作者2010-11-22Journal of The Electrochemical Society

Magnesium doped ZnO polycrystalline thin film was deposited on p-type Si by sol–gel method, and the same was annealed at in oxygen rich environment. The magnesium doping in lattice structure of zinc oxide was examined by X-ray diffraction measurements. The dielectric phase transition observed at indicated the existenc…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsAcoustic Wave Resonator Technologies

Controlling the directionality of charge transfer in phthalocyaninato zinc sensitizer for a dye-sensitized solar cell: density functional theory studies

Liang Wan、Dongdong Qi、Yuexing Zhang 等 4 位作者2010-11-22Physical Chemistry Chemical Physics

Density functional theory (DFT) calculation on the molecular structures, charge distribution, molecular orbitals, electronic absorption spectra of a series of eight unsymmetrical phthalocyaninato zinc complexes with one peripheral (E)-2-cyano-3-(5-vinylthiophen-2-yl) acrylic acid substituent at 2 or 3 position as an e…

TiO2 Photocatalysis and Solar CellsPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

Synthesis of Cyclododeciptycene Quinones

Kaiyan Lou、Allan M. Prior、Bernard Wiredu 等 5 位作者2010-11-22Journal of the American Chemical Society

Cycloiptycenes are elusive and synthetically challenging molecules. We report the first synthesis of two substituted cyclododeciptycene tetraquinones via a sequence of intermolecular and intramolecular Diels-Alder reactions from cis,cis-heptiptycene tetraquinone 2 and substituted 7,16-dihydro-7,16-(o-benzeno)heptacene…

Porphyrin and Phthalocyanine ChemistrySynthesis and Properties of Aromatic CompoundsSynthetic Organic Chemistry Methods

Flexible Sm–Fe/polyvinylidene fluoride heterostructural film with large magnetoelectric voltage output

Shifeng Zhao、Jianguo Wan、Mengliang Yao 等 6 位作者2010-11-22Applied Physics Letters

The Sm–Fe/polyvinylidene fluoride (PVDF) heterostructural film was prepared by depositing Sm–Fe nanoclusters onto the flexible PVDF film using cluster beam deposition method. The PVDF film acts as both piezoelectric layer and substrate. The heterostructural film showed the well-defined microstructures in which the Sm–…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Tailoring drug release profile of low-molecular-weight hydrogels by supramolecular co-assembly and thiol–ene orthogonal coupling

David Díaz Díaz、Emmanuelle Morin-Picardat、Eva M. Schön 等 6 位作者2010-11-22Journal of Materials Chemistry

We describe a general user-friendly platform for fine-tuning the drug release properties of low-molecular-weight hydrogels by a combination of supramolecular co-assembly of complementary molecular structures and controlled photochemical thiol–ene cross-linking. Other critical features such as thermomechanical stabilit…

Supramolecular Chemistry and ComplexesLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials