Materials Literature
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Homogenous ZnxGa2O3+x (0 ≤ x ≤ 1) solid solution nanocrystals were successfully prepared by a solvothermal approach and characterized by X-ray powder diffraction (XRD), X-ray spectra in fluorescence (XRF), transmission electron microscopy (TEM), UV-vis spectroscopy, and X-ray photoelectron spectrum (XPS). XRD pattern…
In this paper, we report a facile, “green”, phosphine-free, low-cost, and non-injection method to obtain size-, shape-, and assembly-controllable Cu2−xSe nanocrystals which can be used as uniform building blocks. Different sizes of monodispersed Cu2−xSe nanocrystals were synthesized successfully by simply controlling…
Abstract Wood polymer composite (WPC) was prepared by using solution blended high density polyethylene, low density polyethylene, polypropylene, and poly(vinyl chloride) with Phragmites karka wood flour and polyethylene‐ co ‐glycidyl methacrylate (PE‐ co ‐GMA). The effect of addition of nanoclay and ZnO on the propert…
A simple model is proposed to simulate contact angle hysteresis in drops on a planar surface. The model is based on assuming a friction force acting on the triple contact line in such a way that the contact line keeps fixed for contact angles comprised between the advancing angle and the receding one and is allowed to…
We have developed a new SERS substrate based on the reduction of silver nitrate in the presence of ZnS-capped CdSe quantum dots. This substrate showed higher sensitivities as compared to a hydroxylamine-reduced silver sol. On the basis of this new substrate, at-line SERS detection was coupled with capillary liquid chr…
We report the synthesis of three different Janus topologies from one single specific triblock terpolymer, poly( tert -butoxystyrene)- block -polybutadiene- block -poly( tert -butyl methacrylate) (tSBT). By controlling the phase transitions via pretreatment and cross-linking conditions of the lamella–cylinder equilibri…
Abstract A new technique to provide melt elasticity using flexible fine fibers prepared from a polymer with high melting point is demonstrated. A polymer composite of poly(propylene) with a small amount of fine fibers of poly(butylene terephthalate) shows marked strain‐hardening behavior in elongational viscosity, i.e…
The nonmetal cation polyborate salt of stoichiometry [H(2)en](2)[B(11)O(18)(OH)]·7H(2)O is obtained from the reaction of 1,2-diaminoethane and boric acid (1:5 ratio) in H(2)O/MeOH. An X-ray crystallographic study of the product reveals that the polyborate moiety is composed of two isolated hydrated polyborate anions:…
Superconductivity and ferromagnetism are two antagonistic cooperative phenomena, which makes it difficult for them to coexist. Here we demonstrate experimentally that they do coexist in EuFe₂(As(1-x)P(x))₂ with 0.2 ≤ x ≤ 0.4, in which superconductivity is associated with Fe 3d electrons and ferromagnetism comes from t…
An in situ sacrificial oxidative template route has been developed for the bulk synthesis of two-dimensional polyaniline nanostructures, such as nanorings and flat hollow capsules. In the reaction system, VOPO 4 ·2H 2 O nanoplates formed spontaneously in V 2 O 5 /H 2 O 2 /H 3 PO 4 mixture can serve as both oxidant and…
The synthesis, crystal structure, nonlinear optical (NLO) property and some other properties of a new material, Hg(2)BrI(3), are reported. The crystal structure has been established by single crystal X-ray diffraction studies. Hg(2)BrI(3) belongs to the HgBrI type and crystallizes in the orthorhombic space group Cmc21…
SnO(2) nanorod arrays have been deposited on 4 inch SiO(2)/Si and Si wafers and stainless steel substrates by plasma-enhanced chemical vapor deposition without any high temperature treatment or additional catalysis. The SnO(2) nanorods grow up from seed nanocrystals along the [110] preferential direction by a self-cat…
Abstract An important strategy used in the polymer industry in recent years is blending two bio‐based polymers to attain desirable properties similar to traditional thermoplastics, thus increasing the application potential for bio‐based and bio‐degradable polymers. Miscibility of poly(3‐hydroxybutyrate‐ co ‐3‐hydroxyv…
Abstract A series of new waterborne polyurethanes (WPUs) was successfully prepared by prepolymer process from renewable source, hydroxytelechelic natural rubber (HTNR), with different amounts of DMPA (1.6–8.4 wt %), different molecular weights (1000–4000 g mol −1 ), and different levels of epoxide (0%–20%) of HTNR. It…
Dimethylamine-borane, (CH(3))(2)NHBH(3), has been considered as one of the attractive materials for the efficient storage of hydrogen, which is still one of the key issues in the "Hydrogen Economy". In a recent communication we have reported the synthesis and characterization of 3-aminopropyltriethoxysilane stabilized…
Abstract In this study, it was aimed to prepare polyvinyl borate/polyvinyl alcohol blend nanofibers by electrospinning process. Polyvinyl borate was synthesized by the condensation reaction of polyvinyl alcohol and boric acid. Polyvinyl borate itself was not suitable for electrospinning process. To improve fiber forma…
An innovative way to produce chalcogenide glasses and glass-ceramics for infrared devices is reported. This new method of synthesis at low temperature combining ball-milling and sintering by SPS (Spark Plasma Sintering) is a technological breakthrough to produce efficient infrared chalcogenide glasses and glass-cerami…
The work demonstrates a polarizer-free bistable reflective electro-optical switch that is based on dichroic dye-doped cholesteric liquid crystal (DDCLC). Bistable opaque and transparent states can be achieved using the planar and ULH textures of CLC, respectively. In the planar texture, the liquid crystal and dye mole…
We demonstrate the assembly of extremely robust and pH-responsive thin shell LbL microcapsules from silk fibroin counterparts modified with poly(lysine) and poly(glutamic) acid, which are based on biocompatible silk ionomer materials in contrast with usually exploited synthetic polyelectrolytes. The microcapsules are…
A series of four spiropyrans bearing different substituents on the indolic nitrogen were synthesized and their capability of binding mono and bivalent transition metal cations in solution was assessed via UV-visible absorption spectroscopy. All the compounds responded selectively to the presence of Cu(ii) ions produci…