Materials Literature
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[4′-(Dimethylamino)biphenyl-4-yl]dimesitylborane (BNB) and [4′-(dimethylamino)phenylazophenyl-4-yl]dimesitylborane (BNA) have been prepared and studied by a solvatochromic technique. The high second-order hyperpolarisability coefficients βCT determined by this technique, 37 and 240 × 10–30 esu, respectively, show that…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTGraft copolymer compatibilizers for blends of polypropylene and ethylene-propylene copolymersDavid J. Lohse, Sudhin Datta, and Edward N. KresgeCite this: Macromolecules 1991, 24, 2, 561–566Publication Date (Print):January 1, 1991Publication History Published online1 May 2002…
VPI-7: the first microporous zincosilicate to contain 3-membered rings (3MR) is reported.
Infrared spectroscopy has been used to analyse the gas-phase reaction products, and the related adsorbed species, obtained from the decomposition of methanol over TiO2, ZrO2 or HfO2 catalysts after consecutive 10 min heating periods at 50 °C intervals between room temperature and 400 °C. Somewhat different results wer…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCarbon black filled natural rubber. 1. Structural investigationsJ. C. Kenny, V. J. McBrierty, Z. Rigbi, and D. C. DouglassCite this: Macromolecules 1991, 24, 2, 436–443Publication Date (Print):January 1, 1991Publication History Published online1 May 2002Published inissue 1 J…
INTRODUCTION. THE CONCEPT OF CONTROLLED DRUG DELIVERY AND DRUG TARGETING. INTERACTION OF I.V. ADMINISTERED CARRIERS WITH BLOOD COMPONENTS AND THE RETICULOENDOTHELIAL SYSTEM. IN VIVO FATE OF I.V. ADMINISTERED DRUG CARRIERS. BIODEGRADABLE CARRIERS FOR DRUG DELIVERY. LOCALIZATION OF CARRIERS IN THE TARGET TISSUE. TARGETI…
The effect of supports such as silica, alumina, amorphous aluminosilicate and magnesia on the activity of heteropoly acids (HPA) for reactions requiring strong and very strong acid sites has been studied. It has been found that 12-tungstophosphoric acid (HPW) mounted on alumina and silica catalyses cumene cracking at…
Abstract The compounding of thermoplastic starch can be regarded as a combined process consisting of extrusion cooking and plastic compounding. The quality of the product is determined largely by the degree of mechanical shear, temperature and water content. These parameters can be influenced both by the machine syste…
In order to get a better understanding of the mechanisms governing corrosion of Zr-based alloys, several examinations have been performed on a variety of samples with uniform and nodular corrosion and different oxide layer thicknesses. The results point to a barrier layer concept. The oxide layer becomes porous at a c…
Abstract The results of ultrasonic irradiation of polystyrene solutions in toluene, benzene and carbon tetrachloride are described. The effect of a range of conditions such as ultrasonic intensity, solution concentration and varying solvents were investigated. The non‐random nature of the degradation process was clear…
The bis(1,3-dithiolium) dication salts 8a–c have been synthesised in three steps (31–51% overall yields) starting from 1,4-bis(bromomethyl)naphthalene, 9,10-bis(chloromethyl)anthracene and 4,4′-bis(chloromethyl)biphenyl, respectively. The bis(halogenomethyl) compounds 5 were converted into the dipiperidiniumbis(dithio…
Calculations of energy deposition in cylindrical target volumes of diameter and height 1-100 nm, including those similar to the dimensions of biological molecules and structures such as DNA, nucleosomes and chromatin fibre, have been made. The calculations used the Monte Carlo track structure program MOCA8B for electr…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure and properties of partially neutralized poly(acrylic acid) gelsF. Schosseler, F. Ilmain, and S. J. CandauCite this: Macromolecules 1991, 24, 1, 225–234Publication Date (Print):January 1, 1991Publication History Published online1 May 2002Published inissue 1 January…
Two allotropic forms of zirconium oxide, monoclinic and tetragonal, have been identified in the scales formed on zirconium alloys. The transition from tetragonal to monoclinic has been followed by X-ray measurements and Raman laser spectroscopy. Information on the average content of the tetragonal phase was obtained b…
Hydrogen-induced loss increases are known to occur in optical fibers, due both to the presence of molecular H<sub>2</sub> and to the reaction of hydrogen with defects in the fibers. To predict the long-term loss increases expected for fibers under normal conditions, it is necessary to rely on accelerated aging experim…
Ferroresonance can occur in power transformers or reactors fed through capacitive coupling from neighbouring phases or lines. Ritz's method of harmonic balance is used to formulate an analytical solution to the problem of fundamental frequency ferroresonance. A two-term polynomial of order 11 is used to accuratel…
Textiles as clothing material must fit the human body and senses. This fitting is an important performance of the textiles besides the utility performance of textiles such as fabric strength. For many years, the performance concerning this fitness has been evaluated subjectively by hand judgement. The fabric property…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRedox-switched molecular aggregates: the first example of vesicle formation from hydrophobic ferrocene derivativesJulio C. Medina, Isabelle Gay, Zhihong Chen, Luis Echegoyen, and George W. GokelCite this: J. Am. Chem. Soc. 1991, 113, 1, 365–366Publication Date (Print):Januar…
A wide range of ceramic coatings has been deposited on metal substrates by a reaction occurring during dielectric breakdown at the anode surface in an electrochemical cell, which is accompanied by visible sparking at the anode/electrolyte interface. While the majority of work reported has been on oxide coatings deposi…
Recent developments in instrumentation for electron energy loss spectroscopy (EELS) at Gatan R&D are reviewed. A 10-channel intrinsic Si detector with single-electron detection capa- bility is being developed for fast energy-filtered imaging and elemental mapping in the STEM mode. A new type of an imaging filter…