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Triplet Dynamics of Conformationally Distorted Porphyrins: Time-Resolved Electron Paramagnetic Resonance

Ayelet Regev、Tamar Galili、Craig J. Medforth 等 7 位作者1994-03-01The Journal of Physical Chemistry

The photoexcited triplet states of the nonplanar porphyrins, free base and zinc 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrins (OETPPs), were examined by laser excitation-time resolved EPR spectroscopy. Measurements were carried out at low temperatures in glassy matrices, and over a wide temperature ra…

Porphyrin and Phthalocyanine ChemistrySpectroscopy and Quantum Chemical StudiesElectron Spin Resonance Studies

Roles of Buffer Layers in Epitaxial Growth of SrTiO3 Films on Silicon Substrates

Bum Ki Moon、Hiroshi Ishiwara1994-03-01Japanese Journal of Applied Physics

Heteroepitaxial growth of SrTiO 3 (STO) films with and without buffer layers on Si(100) and (111) substrates has been conducted by a focused electron beam evaporation method. It has been found that thin metallic layers such as Ti and Sr are effective for improving the quality of overgrown STO films, which is probably…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesElectronic and Structural Properties of Oxides

Transient Modeling of 3-Way Catalytic Converters

K. N. Pattas、A. M. Stamatelos、Panaylotis Pistikopoulos 等 7 位作者1994-03-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">The modeling of transient phenomena occurring inside an automotive 3-way catalytic converter poses a significant challenge to the emissions control engineer. Since the significant progress that has been observed with steady-state models cannot be directly exploited in this directi…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Hydrodesulfurization Studies

Optimum Electrode Materials for Ta2O5 Capacitors for High- and Low-Temperature Processes

Hideaki Matsuhashi、Satoshi Nishikawa Satoshi Nishikawa1994-03-01Japanese Journal of Applied Physics

In this paper, we describe the effects of electrode materials on the leakage current of Ta 2 O 5 films, and show optimum electrode materials for high- and low-temperature processes. The leakage current depends on the electrode material and varies with the annealing temperature. The leakage current is mainly determined…

Semiconductor materials and devicesCopper Interconnects and ReliabilityElectrical Contact Performance and Analysis

Corrosion of Carbon Steels, Stainless Steels, and Titanium in Aqueous Lithium Bromide Solution

J. L. Guiñón、J. García‐Antón、V. Pérez‐Herranz 等 4 位作者1994-03-01CORROSION

Effects of lithium bromide (LiBr) concentration, pH, temperature, exposure time, and the action of some inhibitors on corrosion of several carbon (C) steels, stainless steels (SS), and a titanium (Ti) alloy were studied. Corrosion rates were determined by the polarization resistance method and compared to rates determ…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Functionalized elastomeric compatibilizer in PA 6/PP blends and binary interactions between compatibilizer and polymer

R. Holsti‐Miettinen、Jukka Seppälä、Olli Ikkala 等 4 位作者1994-03-01Polymer Engineering and Science

Abstract Superior impact properties were obtained when maleic anhydride grafted styrene ethylene/butylene styrene block copolymer (SEBS‐g‐MAH) was used as a compatibilizer in blends of polyamide 6 (PA 6) and isotactic polypropylene (PP), where polyamide was the majority phase and polypropylene the minority phase. The…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

A New Skin Equivalent

Tomoko Maruguchi、Yukiya Maruguchi、Shigehiko Suzuki 等 6 位作者1994-03-01Plastic & Reconstructive Surgery

Three types of artificial skin containing keratinocytic components were prepared and tested for comparison. Keratinocytes were cultured on the artificial skin dermis (collagen sponge) by the air-liquid interface culture method. In order to create continuous keratinocytic layers on the artificial skin dermis, pores of…

3D Printing in Biomedical ResearchSilk-based biomaterials and applications

On the thickness of ferroelastic twin walls in lead phosphate Pb3(PO4)2 an X-ray diffraction study

B. Wruck、Ekhard K. H. Salje、Ming Zhang 等 5 位作者1994-03-01Phase Transitions

The effective thickness of ferroelastic twin-walls (W-walls) in Pb3(PO4)2 at room temperature (≈ 0.7 T c ) was determined by X-ray diffraction. The diffraction profiles were analysed using a wall profile e=eotanh x/w where W is the effective wall thickness including the effects of wall bending and surface relaxations.…

Ferroelectric and Piezoelectric MaterialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Semiconducting Barium Titanate Ceramics Prepared by Boron‐Containing Liquid‐Phase Sintering

In‐Chyuan Ho1994-03-01Journal of the American Ceramic Society

Semiconducting BaTiO 3 ceramics have been prepared by adding BN as a sintering aid. Density as high as 93% of theoretical and grain size as large as 16 μm are obtained after sintering at 1160°C. Most significant is that the semiconducting BaTiO 3 is obtained at sintering temperatures as low as 1100°C. The low‐temperat…

Ferroelectric and Piezoelectric MaterialsSemiconductor materials and devicesMicrowave Dielectric Ceramics Synthesis

Holographic Recording, Using Liquid Crystalline Side Chain Polymers

Klaus Anderle、Joachim H. Wendorff1994-03-01Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals

The review describes the principles of a holographic storage process based on the liquid crystalline state of organic polymeric materials. Such materials are capable of forming anisotropic glasses, which can be obtained as thin films. By suitable means one is able to align the optical axis of the uniaxial system withi…

Liquid Crystal Research AdvancementsPhotorefractive and Nonlinear OpticsAdvanced Optical Imaging Technologies

Influence of Chain Entanglement on the Failure Modes in Block Copolymer Toughened Interfaces

Costantino Creton、Hugh R. Brown、V. R. Deline1994-03-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInfluence of Chain Entanglement on the Failure Modes in Block Copolymer Toughened InterfacesC. Creton, H. R. Brown, and V. R. DelineCite this: Macromolecules 1994, 27, 7, 1774–1780Publication Date (Print):March 1, 1994Publication History Published online1 May 2002Published i…

Theoretical and Computational PhysicsBlock Copolymer Self-AssemblyMachine Learning in Materials Science

Ferroelectric Behavior in Metal-Containing Liquid Crystals: A Structure-Activity Study

María Jesús Baena、J. Barbera、Pablo Espinet 等 6 位作者1994-03-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFerroelectric Behavior in Metal-Containing Liquid Crystals: A Structure-Activity StudyM. J. Baena, J. Barbera, P. Espinet, A. Ezcurra, M. B. Ros, and J. L. SerranoCite this: J. Am. Chem. Soc. 1994, 116, 5, 1899–1906Publication Date (Print):March 1, 1994Publication History Pu…

Liquid Crystal Research Advancements

Photooptical Switching of Polymer Film Waveguide Containing Photochromic Diarylethenes

Norihisa Tanio、Masahiro Irie1994-03-01Japanese Journal of Applied Physics

Fabrication of a photooptical switching device based on the photo-induced refractive index change of polymer film doped with photochromic compounds is described. 1,2-bis(2-methylbenzo[b]thiophen-3-yl) perfluorocyclopentene (BFCP) and 1,2-dicyano-1,2-bis(2,4,5-trimethyl-3-thienyl)ethene (CMTE) were used as the photochr…

Neurobiology and Insect Physiology ResearchPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Improved Surface Smoothness of YBa2Cu3Oy Films and Related Multilayers by ArF Excimer Laser Deposition with Shadow Mask “Eclipse Method”

Kazuya Kinoshita、Hiroshige Ishibashi Hiroshige Ishibashi、Takeshi Kobayashi1994-03-01Japanese Journal of Applied Physics

By simply placing a shadow mask between the target material and substrate, the particle (or droplet) problem peculiar to the excimer laser deposition technique was completely eliminated. It is tentatively called the “ eclipse method ”, in which the deposition proceeds through only diffusion. Mirrorlike YBa 2 Cu 3 O y…

Physics of Superconductivity and MagnetismZnO doping and propertiesSemiconductor materials and devices

Room-temperature persistent spectral hole burning in Sm^2+-doped fluoride glasses

Atusi Kurita、T. Izumitani、Michimasa Matsukawa 等 4 位作者1994-03-01Optics Letters

Persistent spectral hole burning is observed in Sm(2+)-doped glasses at room temperature. The holes are burned in the (7)F(0) ? (5)D(0), (5)D(1) lines of the Sm(2+) ions in three kinds of fluoride glass. The dependence of the burning efficiency on the sample and on the burning intensity is measured. The intensity depe…

Glass properties and applicationsQuantum optics and atomic interactionsRandom lasers and scattering media

Nonlinear Optical Properties of Poled Polymer of Phenoxy Resin Containing α-Cyano Unsaturated Carboxylate

Okihiro Sugihara、Hideki Nakayama、Naomichi Okamoto 等 5 位作者1994-03-01Japanese Journal of Applied Physics

A new nonlinear optical polymer of phenoxy resin containing 2-cyano-5-(4-methoxyphenyl)-2,4-pentadienoate as a pendant group is synthesized. A high concentration (84%) of chromophores with a relatively high value of hyperpolarizability ( 50×10 -30 esu) is obtained. The corona-poled polymer film shows hypochromic shift…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchNonlinear Optical Materials Studies

Effects of neutron irradiation on vanadium-base alloys

D.L. Smith、B.A. Loomis、H.M. Chung1994-03-01Plasma devices and operations

Vanadium-base alloys of the V-Cr-Ti-Si system are attractive candidates for use as structural materials in fusion reactors. The vanadium-base alloys exhibit relatively low long-term activation, irradiation induced afterheat and neutron-induced helium transmutation rates. Because of favorable physical properties these…

Fusion materials and technologiesNuclear Materials and PropertiesMetal Alloys Wear and Properties

Charge‐sensitive secondary electron imaging of diamond microstructures

A. B. Harker、D. G. Howitt、J.F. DeNatale 等 4 位作者1994-03-01Scanning

Abstract The surface orientation and detailed defect microstructure of polycrystalline diamond can be observed in a scanning electron microscope through local changes in the surface conductivity. The electron contrast in uncoated samples is straightforward to distinguish when the rms surface roughness is less than abo…

Diamond and Carbon-based Materials ResearchAdvanced Electron Microscopy Techniques and ApplicationsForce Microscopy Techniques and Applications

Analysis of a Hysteresis Motor on Asynchronous Speed Using Complex Permeability

Tatsuo Horii、N. Yuge、Genjiro Wakui1994-03-01IEEE Translation Journal on Magnetics in Japan

This paper deals with a method for determining the complex permeability in analysis of hysteresis motors. The method assumes that the magnetic intensity distribution is sinusoidal in the direction of rotation. Analysis of the asynchronous speed of a hysteresis motor is then performed for cylindrical coordinates, using…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsNon-Destructive Testing Techniques