Materials Literature
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We investigate thermal behavior of transparent film heaters (TFH) made of single-walled carbon nanotubes. We fabricate the TFH by using the spray coating method. We studied the temperature dependence of the electrical resistance of the TFH in terms of Joule and external heating in various gas environments. Test result…
This report describes the reduction of a niobium(V) phthalocyanine complex and investigation of the electronic structure of the resulting products. The reduction of PcNbCl(3) (Pc = phthalocyanine dianion) with 5.5 equiv of potassium graphite in 1,2-dimethoxyethane (DME) resulted in the isolation of K(2)PcNbO.5DME (1a)…
Superconducting thin films of ${\text{Fe}}_{1.08}\text{Te}:{\text{O}}_{x}$ have been epitaxially grown on ${\text{SrTiO}}_{3}$ substrates by pulsed-laser deposition in controlled oxygen atmosphere. Although the bulk ${\text{Fe}}_{1.08}\text{Te}$ is not superconducting, thin films with oxygen are superconducting with a…
The acute toxicity of polymer-coated CdSe/ZnS quantum dots (QDs) to Daphnia magna was investigated using 48-h exposure studies. The principal objective was to relate the toxicity of QDs to specific physical and chemical aspects of the QD. As such, two different CdSe core diameters, 2 nm QDs (green-emitting) and 5 nm Q…
The spontaneous capillary imbibition and drainage processes are studied using many-body dissipative particle dynamics (MDPD) simulations. By adjusting the solid-liquid interaction parameter, different wetting behavior between the fluid and the capillary wall, corresponding to the static contact angle ranging from 0 de…
In this work the photochromic behaviors of four Reversacol compounds from James Robinson Ltd., previously investigated in solution, have been studied in a microcrystalline solid phase and embedded in a poly(methyl methacrylate) matrix (PMMA). The compounds studied belong to the classes of spirooxazines and naphthopyra…
Single-crystalline anatase TiO 2 nanowires have been synthesized using a novel, room-temperature method involving the use of seed particles and a radio frequency magnetron sputter deposition technique. Also, the growth time required was less than 60 min. Transmission electron microscopy and X-ray absorption near-edge…
A shallow grating triple-layer guided-mode resonance (GMR) filter and its properties are presented. For this type of GMR filter, the grating layer has the equal refractive index to the waveguide layer. It is shown that the GMR filter with shallow grating has good characteristics of narrow bandwidth, symmetrical line s…
The effect of Fe-doping on the oxygen vacancy energy formation and on the electronic structure of stoichiometric bulk and (001) surface of TiO 2 anatase has been studied by means of periodic density functional calculations within the GGA+U approach. The vacancy energy formation is always lower for the surface than for…
A novel combination of time-resolved hard X-ray diffraction, diffuse reflectance infrared spectroscopy, and mass spectrometry reveals how Pd nanoparticles dissociate CO and store atomic carbon and how this carbon storage dynamically changes the population of linear and bridging CO species at the surface of the Pd nano…
Sheltered growth: A novel atomic layer deposition (ALD) method to synthesize highly uniform ultrafine supported metal nanoparticles is described. The ALD process includes growing protected metal nanoparticles and new support layers simultaneously at low temperature. In the final stage, the activation of the metal nano…
Ab initio calculations have been performed on [Fe(II)(bpy)3](2+) (bpy = bipyridine) to establish the variation of the energy of the electronic states relevant to light-induced excited-state spin trapping as a function of the Fe-ligand distance. Light-induced spin crossover takes place after excitation into the singlet…
The magnetocaloric effect (MCE) was measured to probe the nature of phase coexistence of structurally different ferromagnetic metallic (FMM) and charge-ordered insulating phases in ${\text{La}}_{5/8\ensuremath{-}y}{\text{Pr}}_{y}{\text{Ca}}_{3/8}{\text{MnO}}_{3}$ $(y=0.275)$ single crystals. The MCE peaks with both po…
The effects of various factors on the resonance coupling between elongated Au nanocrystals and organic dyes have been systematically investigated through the preparation of hybrid nanostructures between Au nanocrystals and the electrostatically adsorbed dye molecules. A nanocrystal sample is chosen for each dye to mat…
We present a microelectromechanical systems (MEMS) nanoreactor that enables high-resolution transmission electron microscopy (TEM) (HRTEM) of nanostructured materials with atomic-scale resolution during exposure to reactive gases at 1 atm of pressure. This pressure exceeds that of existing HRTEM systems by a factor of…
RENbO 4 (RE = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) materials were synthesized by solid-state reactions and then systematically investigated by vibrational spectroscopy. Single-phase materials were obtained at optimized temperature and time conditions, which were probed by X-ray diffraction and Raman…
We describe the self-assembly of biomimetic isotropic films which display structural color amenable to potential applications in coatings. Isotropic structures can produce color if there is a pronounced characteristic length-scale comparable to the wavelength of visible light and wavelength-independent scattering is s…
We study spatial symmetry in general $ABA$-stacked multilayer graphene to illustrate how electronic spectra at the two valleys are related in a magnetic field. We show that the lattice of multilayers with an even number of layers as well as that of monolayer graphene satisfy spatial inversion symmetry, which rigorousl…
This study involves two aspects of our investigations of plasmonics-active systems: (i) theoretical and simulation studies and (ii) experimental fabrication of plasmonics-active nanostructures. Two types of nanostructures are selected as the model systems for their unique plasmonics properties: (1) nanoparticles and (…
We present cluster-dynamic mean field theory (DMFT) (continuous time quantum Monte Carlo method) calculations based on a downfolded tight-binding model in order to study the electronic structure of vanadium dioxide $({\text{VO}}_{2})$ both in the low-temperature $({M}_{1})$ and high-temperature (rutile) phases. Motiva…