Materials Literature
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Recently, osmium diboride (OsB2) has attracted considerable attention as an incompressible and hard material. We investigate the structural property, elastic constants, and electronic structure of orthorhombic OsB2 by the first-principles total energy calculations. The calculations are performed within the density fun…
Ferrocenyl cobaltocenium hexafluorophosphate (1) and ferrocenylene cobaltocenylenium hexafluorophosphate (2) are investigated by a range of spectroscopic methods. Both compounds are diamagnetic, in contrast to an earlier report indicating a temperature-dependent paramagnetism of 2. Electronic absorption spectra of 1 a…
The interaction of CpM(CO)3H (M = Mo, W) hydrides as proton donors with different bases (B = pyridine, (n-Oc)3PO, ((CH3)2N)3PO, H3BNEt3) was studied by variable temperature IR spectroscopy and theoretically by DFT/B3LYP calculations. The data obtained show for the first time the formation of intermolecular hydrogen bo…
Novel chelates PIP-DTPA, AZEP-DTPA, NETA, NPTA, and PIP-DOTA were synthesized and evaluated as potential magnetic resonance imaging (MRI) contrast enhancement agents. The T1 and T2 relaxivities of their corresponding Gd(III) complexes are reported. At clinically relevant field strengths, the relaxivities of the comple…
Polycondensations were performed at 70 degrees C in bulk using physically immobilized lipase B from Candida antarctica (CAL-B) as catalyst. Study of copolymerizations between sebacic acid and PEG diols of differing Mn values (200, 400, 600, 1000, 2000, and 10 000) showed that PEG 400 and 600 were most reactive (DP(avg…
The influence of postadsorption relaxation processes has been evaluated in the adsorption behavior of block copolymer micelles comprised of asymmetric poly( tert -butylstyrene- b -sodium 4-styrenesulfonate) (PtBS−NaPSS) diblock copolymers as well as star-block copolymers of similar size and composition. The adsorption…
We report results on the catalytic oxidation of carbon monoxide (CO) over clean Ir surfaces that are prepared reversibly from the same crystal in situ with different surface morphologies, from planar to nanometer-scale facets of specific crystal orientations and various sizes. Our temperature-programmed desorption (TP…
Scanning synchrotron radiation microdiffraction with an approximately 1 x 1 microm(2) beam has been used as a novel method for characterizing the decay of several T'ang dynasty (618-907 AD) silk fabrics. The crystalline fraction could be visualized based on beta-sheet 210 reflection intensities, extracted by recursive…
The purpose of this study is to develop a reliable method of functionalizing poly(ethylene terephthalate) with bioactive polymers to produce a "biointegrable" artificial anterior cruciate ligament. Radical graft polymerization of the sodium salt of styrene sulfonate (NaSS) onto poly(ethylene terephthalate) (PET) films…
ADVERTISEMENT RETURN TO ISSUEPREVNoteNucleation and Crystallization Behavior of Poly(butylene succinate) Induced by Its α-Cyclodextrin Inclusion Complex: Effect of StoichiometryTungalag Dong, Kyung-moo Shin, Bo Zhu, and Yoshio InoueView Author Information Department of Biomolecular Engineering, Tokyo Institute of Tech…
Multilayer polymer films composed of a ruthenium terpyridine complex containing poly( p -phenylenevinylene) ( Ru − PPV ) and sulfonated polyaniline ( SPAN ) were prepared by a layer-by-layer electrostatic self-assembly deposition. The deposition process was carried out from SPAN solution in water and Ru − PPV in dimet…
The large diameter of single-wall carbon nanohorns (SWNHs) allows various molecules to be easily incorporated in hollow nanospaces. In this report, we prove that the nanospaces of SWNHs even work as the chemical reaction field at high temperature; that is, Gd-acetate clusters inside SWNHs were transformed into ultrafi…
There is considerable interest in constructing supramolecular hollow tube architectures based on amphiphilic molecules. This can be achieved by using relatively expensive synthetic lipids. Herein, we report on the facile preparation of self-assembled microtubes from a novel low-cost lipid mixture that does not require…
Small-angle neutron scattering (SANS) is used with the “high-concentration” method to extract single-particle scattering from single-wall carbon nanotubes (SWNTs). The SWNT material was labeled by covalently attaching −C 4 H 9 or −C 4 D 9 groups by use of free radical chemistry. Mixtures of SWNT-C 4 H 9 and SWNT-C 4 D…
Combined small-angle and high energy wide-angle X-ray scattering measurements of nanoparticle size and structure permit interior strain and disorder to be observed directly in the real-space pair distribution function (PDF). PDF analysis showed that samples of ZnS nanoparticles with similar mean diameters (3.2-3.6 nm)…
A novel method is presented to monitor carbon nanotube (CNT) growth by formation of CNT stacks. By this process, CNT growth kinetics are investigated for densely packed CNT films in the gas-diffusion-controlled regime. CNT stacks are fabricated by water-assisted selective etching and the cyclic introduction of ethylen…
2,5-Diphenyl-1,3,4-oxadiazole (OXD) derivatives with terminal ethynyl- (4a,b) and butadiynyl- (8a,b) substituents have been synthesized in high yields. 2-Methyl-3,5-hexadiyn-2-ol has not been exploited previously in the synthesis of terminal butadiynes. Crystals of 8a and 8b are remarkably stable to long-term storage…
We have synthesized an amphiphilic rigid-flexible macrocycle (fcoil = 0.68) consisting of hexa-p-phenylene and aliphatic polyether chain. The macrocyclic molecule in bulk state self-organizes into a 2-D body-centered rectangular structure (a = 4.3 nm and b = 6.3 nm). In aqueous solution, the macrocycle self-assembles…
We extend the concepts of phase, polarization, and feedback control of matter to develop a general approach for guiding light in the nanoscale via nanoparticle arrays. The phase and polarization of the excitation source are first introduced as tools for control over the pathway of light at array intersections. Genetic…
In recent years there has been considerable interest in using natural plant fibers as reinforcements for plastics. The motivation includes cost, performance enhancement, weight reduction, and environment concerns. High performance flax fiber could potentially substitute for glass or carbon fibers as reinforcements for…