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Calotropis proceraextract induces apoptosis and cell cycle arrest at G2/M phase in human skin melanoma (SK-MEL-2) cells

Aparna Joshi、Pratiksha H. Roham、Rooth Mhaske 等 8 位作者2015-01-27Natural Product Research

Calotropis procera (family: Asclepiadaceae) contains cardiac glycosides which are cytotoxic to cancer cells. The extracts of C. procera have been reported to be cytotoxic to many cancer cell lines and this is the first report against the human skin melanoma cells (SK-MEL-2). The SK-MEL-2 cells treated with C. procera…

Bioactive Compounds and Antitumor AgentsPhytochemical compounds biological activitiesPhytochemistry and Bioactive Compounds

New methods in time-resolved Laue pump–probe crystallography at synchrotron sources

Philip Coppens、Bertrand Fournier2015-01-27Journal of Synchrotron Radiation

Newly developed methods for time-resolved studies using the polychromatic and in particular the pink-Laue technique, suitable for medium and small-size unit cells typical in chemical crystallography, are reviewed. The order of the sections follows that of a typical study, starting with a description of the pink-Laue t…

Crystallography and molecular interactionsEnzyme Structure and FunctionX-ray Diffraction in Crystallography

Lanthanide Complex Hybrid System for Fluorescent Sensing as Thermometer

Xiang Shen、Ye Lu、Bing Yan2015-01-27European Journal of Inorganic Chemistry

Abstract A mixed lanthanide complex was synthesized hydrothermally with two kinds of organic ligands, adenine and biphenyl‐4,4′‐dicarboxylic acid, and is formulated as Ad/Tb0.999Eu0.001/BPDC (Ad = adeninate, BPDC = biphenyl‐4,4′‐dicarboxylate). The photophysical properties, especially the fluorescent sensing propertie…

Luminescence Properties of Advanced MaterialsLanthanide and Transition Metal ComplexesAnalytical Chemistry and Sensors

Two-internal variable thermodynamics modelling of severe plastic deformation: Dislocation and flow stress evolutions

H. Parvin、M. Kazeminezhad2015-01-27Materials Science and Technology

Two-internal variable thermodynamics model is presented to investigate the evolution of microstructure and flow stress during severe plastic deformation. Previous studies have shown that due to heterogeneous distribution of dislocations during severe plastic deformation, the use of multivariable models is needed. In t…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metals

Synthesis, Crystal Structure, Resistivity, Magnetic, and Theoretical Study of ScUS3

Jai Prakash、Adel Mesbah、M.D. Ward 等 8 位作者2015-01-27Inorganic Chemistry

Single crystals of ScUS3 were synthesized in high yield in a single step at 1173 K. ScUS3 crystallizes in the FeUS3 structure type in the space group D2h(17)–Cmcm of the orthorhombic system with four formula units in a cell of dimensions a = 3.7500(8) Å, b = 12.110(2) Å, and c = 9.180(2) Å. Its structure consists of e…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyOrganometallic Compounds Synthesis and Characterization

Study on mechanical properties and hydrogen embrittlement susceptibility of 7075 aluminium alloy

W. J. Qi、Renguo Song、Y. Zhang 等 6 位作者2015-01-27Corrosion Engineering Science and Technology The International Journal of Corrosion Processes and Corrosion Control

The mechanical properties and hydrogen embrittlement susceptibility of 7075 aluminium alloy were studied by means of cathodic H permeation, hydrogen determinator, slow strain rate test (SSRT), energy dispersive X-ray spectroscopy (EDS) and scanning electron microscope (SEM). The results showed that both before and aft…

Corrosion Behavior and InhibitionAluminum Alloy Microstructure PropertiesHydrogen embrittlement and corrosion behaviors in metals

Plasmonic octagonal quasicrystals for surface enhanced Raman sensing

Lucia Petti、Massimo Rippa、Rossella Capasso 等 8 位作者2015-01-27Advanced Device Materials

Surface enhanced Raman scattering (SERS) on eight-fold quasicrystal arrays with precisely controlled size and spacing fabricated via electron beam lithography was investigated. This SERS substrate shows high efficiency at 785 nm excitation in the detection of p-mercaptoaniline (pMA), and a SERS enhancement factor (EF…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Theoretical study of the physical properties of BiS2 superconductors

Chang-Liang Dai、Yang Yang、Wansheng Wang 等 4 位作者2015-01-27Physical Review B

Recent angle-resolved photoemission reveals that the doping level in some ${\mathrm{BiS}}_{2}$-based superconductors is much lower than the nominal one. Here we determine the pairing function at such a realistic low doping level by a functional renormalization group (FRG) and study the resulting physical properties by…

Physics of Superconductivity and MagnetismAdvanced Condensed Matter PhysicsIron-based superconductors research

Polydopamine assisted preparation of Ti4+‐decorated magnetic particles for selective and rapid adsorption of phosphorylated proteins

Xiangdong Ma、Li Jia2015-01-27Journal of Chemical Technology & Biotechnology

Abstract BACKGROUND Phosphorylated proteins have attracted widespread attention due to their crucial roles in regulating biological processes. Therefore, development of effective methods for identification and detection of phosphorylated proteins is an indispensable step to understand the roles of protein phosphorylat…

Protease and Inhibitor MechanismsPolymer Surface Interaction StudiesPhytase and its Applications

Minimality via second variation for microphase separation of diblock copolymer melts

Vesa Julin、Giovanni Pisante2015-01-27Journal für die reine und angewandte Mathematik (Crelles Journal)

Abstract We consider a non-local isoperimetric problem arising as the sharp interface limit of the Ohta–Kawasaki free energy introduced to model microphase separation of diblock copolymers. We perform a second order variational analysis that allows us to provide a quantitative second order minimality condition. We sho…

Theoretical and Computational PhysicsRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Gold–Oxoborate Nanocomposites and Their Biomedical Applications

Katarzyna Wybrańska、Jan Paczesny、Katarzyna Serejko 等 12 位作者2015-01-27ACS Applied Materials & Interfaces

A novel inorganic nanocomposite material, called BOA, which has the form of small building blocks composed of gold nanoparticles embedded in a polyoxoborate matrix, is presented. It is demonstrated that cotton wool decorated with the BOA nanocomposite displays strong antibacterial activity toward both Gram-positive an…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsGraphene and Nanomaterials Applications

Metallic core conduction in unintentionally doped ZnO nanowire

Andrés de Luna Bugallo、Fabrice Donatini、Corinne Sartel 等 5 位作者2015-01-27Applied Physics Express

The conduction through unintentionally doped ZnO nanowires grown by metalorganic chemical vapor deposition versus temperature (4 to 300 K) and nanowire radius (50 to 175 nm) was investigated. To obtain a reliable picture of the electrical conduction, controlled experimental conditions were used to master the influence…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Room temperature fabrication of ZnO/ST-cut quartz SAW UV photodetector with small temperature coefficient

Wen-Che Tsai、Hui-Ling Kao、Kun-Hsu Liao 等 6 位作者2015-01-27Optics Express

Room-temperature fabricated ZnO/ST-cut quartz is adopted for SAW ultraviolet (UV) photodetector. The ST-cut quartz substrate and ZnO layer are used for SAW excitation and photodetection, respectively. High resolution x-ray diffraction (XRD) and photoluminescence (PL) measurement indicate that high quality ZnO films ca…

ZnO doping and propertiesAcoustic Wave Resonator TechnologiesGa2O3 and related materials

Type-II second-harmonic-generation properties of YCOB and GdCOB single crystals

Yanqing Liu、Hongwei Qi、Qingming Lu 等 7 位作者2015-01-27Optics Express

As excellent nonlinear optical (NLO) crystals, YCa(4)O(BO(3))(3) (YCOB) and GdCa(4)O(BO(3))(3) (GdCOB) have been paid much attention since their first appearance in 1990's. From that time to now, almost all of related researches and applications have focused on their type-I phase-matching (PM) configurations which pos…

Crystal Structures and PropertiesPhotorefractive and Nonlinear OpticsSolid State Laser Technologies

Latest methods of fluorescence-based protein crystal identification

Arne Meyer、Christian Betzel、Marc L. Pusey2015-01-27Acta Crystallographica Section F Structural Biology Communications

Successful protein crystallization screening experiments are dependent upon the experimenter being able to identify positive outcomes. The introduction of fluorescence techniques has brought a powerful and versatile tool to the aid of the crystal grower. Trace fluorescent labeling, in which a fluorescent probe is cova…

Protein Structure and DynamicsMass Spectrometry Techniques and ApplicationsEnzyme Structure and Function

Predictions of Volume Relaxation in Glass Forming Materials Using a Stochastic Constitutive Model

Grigori A. Medvedev、James M. Caruthers2015-01-27Macromolecules

In a previous publication ( Macromolecules 2012, 45, 7237), a stochastic model of the glassy state that acknowledges dynamic heterogeneity was shown to describe the classic Kovacs poly(vinyl acetate) volume relaxation data set with the exception of the expansion gap and the pressure dependence of the glass transition…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Synthesis and Properties of a Clean and Sustainable Deicing Additive for Asphalt Mixture

Chao Peng、Jianying Yu、Zhijie Zhao 等 7 位作者2015-01-27PLoS ONE

A clean and sustainable deicing additive was prepared via the adsorption of acetate anions (Ac-) by magnesium (Mg) and aluminum (Al) calcined layered double hydroxide (Mg/Al-CLDH). Fourier transform infrared spectroscopy spectrums proved that Ac- had intercalated into LDH structure. X-ray diffraction patterns, scannin…

Layered Double Hydroxides Synthesis and ApplicationsChemical Synthesis and CharacterizationMagnesium Oxide Properties and Applications

Engineered Therapeutic-Releasing Nanoporous Anodic Alumina-Aluminum Wires with Extended Release of Therapeutics

Cheryl Suwen Law、Abel Santos、Tushar Kumeria 等 4 位作者2015-01-27ACS Applied Materials & Interfaces

In this study, we present a nanoengineered therapeutic-releasing system based on aluminum wires featuring nanoporous anodic alumina layers and chitosan coatings. Nanoporous anodic alumina layers are produced on the surface of aluminum wires by electrochemical anodization. These nanoporous layers with precisely enginee…

Nanopore and Nanochannel Transport StudiesAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Wettability Engendered Templated Self-assembly (WETS) for Fabricating Multiphasic Particles

Sai P. R. Kobaku、Gibum Kwon、Arun K. Kota 等 7 位作者2015-01-27ACS Applied Materials & Interfaces

Precise control over the geometry and chemistry of multiphasic particles is of significant importance for a wide range of applications. In this work, we have developed one of the simplest methodologies for fabricating monodisperse, multiphasic micro- and nanoparticles possessing almost any composition, projected shape…

Polymer Surface Interaction StudiesNanomaterials and Printing TechnologiesPickering emulsions and particle stabilization

Direct fabrication of carbon nanotube-graphene hybrid films by a blown bubble method

Shiting Wu、Enzheng Shi、Yanbing Yang 等 6 位作者2015-01-27Nano Research

Hybridization of carbon nanotubes (CNT) with graphene provides a promising means of integrating the attributes of both materials, thereby enabling widespread application. Here, we present a method to directly assemble hybrid CNT-graphene films by a blown bubble method combined with selective substrate annealing. We us…

Carbon Nanotubes in CompositesGraphene research and applicationsSupercapacitor Materials and Fabrication