Materials Literature
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This paper presents a hybrid CNT/CMOS chemical sensor system that comprises of a carbon nanotube sensor array and a CMOS interface chip. The full system, including the sensor, consumes 32 muW at 1.83 kS/s readout rate, accomplished through an extensive use of CAD tools and a model-based architecture optimization. A re…
Graphene nanoribbon FETs (GNRFETs) are promising devices for beyond-CMOS nanoelectronics because of their excellent carrier transport properties and potential for large scale processing and fabrication. This paper combines atomistic quantum transport modeling with circuit simulation to perform technology exploration f…
The misfit oxide, Bi$_{2}$Ba$_{1.3}$K$_{0.6}$Co$_{2.1}$O$_{y}$, made of alternating rocksalt-structured [BiO/BaO] layers and hexagonal CoO$_{2}$ layers, was studied by angle-resolved photoemission spectroscopy. Detailed electronic structure of such a highly strained oxide interfaces is revealed for the first time. We…
We calculate the properties of the 4$d$ ferromagnet SrRuO$_3$ in bulk and thin film form with the aim of understanding the experimentally observed metal to insulator transition at reduced thickness. Although the spatial extent of the 4$d$ orbitals is quite large, many experimental results have suggested that electron-…
It is shown that current saturation in semiconducting carbon nanotubes is indistinguishable from metallic nanotubes if the carrier density is above a critical value determined by the bandgap and the LO phonon energy. This feature stems from the higher number of current-carrying states in the semiconducting tubes due t…
We have performed a depth profile study of thermally diffused Mn/GaAs (001) interfaces using photoemission spectroscopy combined with Ar$^+$-ion sputtering. We found that Mn ion was thermally diffused into the deep region of the GaAs substrate and completely reacted with GaAs. In the deep region, the Mn 2$p$ core-leve…
Purpose The paper aims to establish and introduce seam pucker assessment indicators and their dependence upon the fabric characteristics and parameters of a sewing machine. Design/methodology/approach Seams pucker defect is specific to garment from lightweight fabrics, therefore the investigation was performed with th…
Hyper-Raman spectra were obtained for zinc phthalocyanine in a dilute pyridine solution at excitation wavelengths that are two-photon resonant with the one-photon-allowed B band (360-380 nm) as well as with the two-photon absorption near 440 nm reported by Drobizhev et al. ( J. Chem. Phys. 2006, 124, 224701 ). In both…
ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTHighly Porous Polysilsesquioxane Networks via Hydrosilylative Polymerization of Macrocyclic Oligomeric SilsesquioxanesJin Han and Sixun Zheng*View Author Information Department of Polymer Science and Engineering, Shanghai Jiao Tong…
Two tetranuclear Mn complexes with an average Mn oxidation state of +2.5 have been prepared. These valence isomers have been characterized by a combination of X-ray crystallography, X-ray absorption spectroscopy, and magnetic susceptibility. The Mn(II)3Mn(IV) tetramer has the Mn ions arranged in a distorted tetrahedro…
Using hydrothermal synthesis, a series of indium iodates α-K 3 In(IO 3 ) 6 ( 1 ), β-K 3 In(IO 3 ) 6 ( 2 ), In(OH)(IO 3 ) 2 ·H 2 O ( 3 ), and In(IO 3 ) 3 ( 4 ) from zero-dimensional, one-dimensional, to two-dimensional have been prepared. Compound 1 crystallizes in an orthorhombic system with space group Fdd 2, a = 39.…
Purpose The paper aims to investigate thermal comfort properties, such as heat and moisture transmission through male business clothing systems, by using a sweating thermal manikin Coppelius that simulates heat and moisture production in a similar way to the human body and measures the influence of clothing on heat ex…
The extraordinary stability of the photoinduced red form of a cationic spiropyran ( k approximately 10 (-6) s (-1) in water and approximately 10 (-6) to less than 10 (-8) s (-1) in the solid state) was employed to obtain in situ X-ray diffraction evidence of its molecular structure. By UV excitation under selected exp…
To evaluate the effect of polymer architecture on surface tension, glass transition, and other thermodynamic properties, we synthesized a series of 4-arm and 11-arm symmetric star polystyrenes. Surface tension was measured as a function of molecular weight of the stars and temperature in the melt using a modified Wilh…
The meta-cleavage pathway for catechol is a central pathway for the bacterial dissimilation of a wide variety of aromatic compounds, including phenols, methylphenols, naphthalenes, and biphenyls. The last enzyme of the pathway is a bifunctional aldolase/dehydrogenase that converts 4-hydroxy-2-ketovalerate to pyruvate…
This experimental study explores the capture and manipulation of micrometer-scale particles by single surface-immobilized nanoparticles. The nanoparticles, approximately 10 nm in diameter, are cationic and therefore attract the micrometer-scale silica particles in an analyte suspension. The supporting surface on which…
A series of novel supramolecular architectures were built around a tin tetraphenyl porphyrin platform 6--functionalized by a 2-fold 1-ethyl-3-3-(3-dimethylaminopropyl)carbodiimide (EDC) promoted condensation reaction--and chiral depsipeptide dendrons of different generations 1-4. Here, implementation of a Hamilton rec…
Single-crystalline Zn 2 GeO 4 nanorods were formed by submerging Zn-containing Ge nanoparticles (ZCGNs) in water at room temperature. These nanorods with the diameter ranging from several tens to more than 100 nm and the length of several micrometers exhibit a blue-green luminescence peak at 450 nm. Due to the surface…
In this paper, the effects of K 2 O promoter on the activity, stability, and coke deposition of nickel catalysts supported on mesoporous nanocrystalline zirconia powder with high surface area and pure tetragonal crystallite phase were investigated in methane reforming with carbon dioxide. The samples were characterize…
In situ electrochemical surface enhanced Raman spectra (SERS) for an immobilized monolayer of a flavin analogue (isoalloxazine) at nanostructured silver surfaces are reported. Unique in the present study, the flavin is not directly adsorbed at the Ag surface but is attached through a chemical reaction between cysteami…