Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTDetermining the Young's Modulus of Polyelectrolyte Multilayer Films via Stress-Induced Mechanical Buckling InstabilitiesAdam J. Nolte, Michael F. Rubner, and Robert E. CohenView Author Information Departments of Materials Science an…
Abstract This report constitutes an introductory report of interest to the standardization community on the advances made in the atomic and molecular nanotechnology regarding the ability to systematically organize and manipulate properties and behaviors of matter at the atomic and molecular levels. Basics of nanotechn…
We show that the dissociation probability of O2 on the reconstructed, Au111-herringbone surface is dramatically increased by the presence of some atomic oxygen on the surface. Specifically, at 400 K the dissociation probability of O2 on oxygen precovered Au111 is on the order of 10(-3), whereas there is no measurable…
Abstract We present recent development and applications of a surface‐enhanced Raman scattering (SERS) technology for use in medical diagnostics and biological imaging. For medical diagnostics, we use Raman‐active dye‐labeled DNA gene probes and nanostructured metallic substrates as SERS‐active platforms. The surface‐e…
A series of highly extensive quinoidal oligothiophenes carrying a dicyanomethylene group at both terminal positions is synthesized. As the quinoidal structures extend, they have highly amphoteric abilities and show strong electronic absorptions in the visible to near-infrared region. The higher homologues, quinquethio…
Properties of the perovskite ferroelectrics Na0.5Bi0.5TiO3 (NBT), K0.5Bi0.5TiO3 (KBT) and their solid solutions are reviewed. Consideration of the NBT behavior draws attention to phenomena of the ion ordering, coexistence of several phase regions within a crystal lattice, phase transition diffusion and to a quite new…
A brief review of the methods used for broadband complex permeability measurement of magnetic thin films up to microwave frequencies is given. In particular, the working principles of the transmission-line perturbation methods for the characterization of magnetic thin films are discussed, with emphasis on short-circui…
Dendrimers containing 1,4-triazole linkages between each generation were grown divergently via the Click chemistry inspired Huisgen 1,3-dipolar cycloaddition reaction in the presence of a Cu(I) catalyst. The monomeric unit (1-propargylbenzene-3,5-dimethanol) contained the alkyne functionality, while the core (1,2-bis(…
Abstract We had recently demonstrated that the diphenylalanine peptide, the core recognition motif of the Alzheimer's ß‐amyloid polypeptide, self‐assembles into a novel class of peptide nanotubes. The formation of well‐ordered supramolecular structures at the nanoscale by such a simple peptide was consistent with our…
This review highlights the developments in dendrimer-based micelles for drug delivery. Dendrimers, the perfectly branched monodisperse macromolecules, have certain structural advantages that make them attractive candidates as drug carriers for controlled release or targeted delivery. As polymeric micelle-based approac…
Abstract A nanotechnological app#roach aims at making tailor‐made developments for storage materials by combining different scientific disciplines and focussing on processes on the microscale. The approach has already been successful in achieving major advances in the field of novel solid materials for hydrogen storag…
Spiropyran dyes were attached to fluorescent core-shell CdSe/ZnS nanocrystals via thiol-containing linkers. Photoisomerization of the dye to its merocyanine form by UV irradiation caused a dramatic loss in the intrinsic nanoparticle fluorescence, which was regained upon reversing the isomerization with visible light.…
Important cellulose solvents are described based on the systematization of derivatizing and non-derivatizing solvents. Advances and limitations of the homogeneous phase chemistry of the biopolymer will be discussed based on new results considering adequately own research work in the field.
It has been known that the electrical breakdown of insulating materials is strongly affected by the formation of space charge in the bulk of the materials. Many researchers have attempted to study the relationship between the space charge and the breakdown; however, it has not been clarified yet. Although the pulsed e…
A diarylethene fused trimer, 1-(5-(2-(3,5-dimethyl-2-thienyl)hexafluorocyclopententen-1-yl)-2,4-dimethyl-3-thienyl)-2-(5-(2-(2,4-dimethyl-5-phenyl-3-thienyl)hexafluorocyclopentene-1-yl)-2,4-dimethyl-3-thienyl)hexafluorocyclopentene, was synthesized. The diarylethene derivative showed full-color photochromic performanc…
Increasing power densities and decreasing transistor dimensions are hallmarks of modern computer chips. Both trends are increasing the thermal management challenge within the chip and surrounding packaging, as well as accelerating research progress on high-conductivity materials. This article reviews recent materials…
The three-dimensional structure of large packings of monosized spheres with volume fractions ranging between 0.58 and 0.64 has been studied with x-ray computed tomography. We search for signatures of organization, classifying local arrangements and exploring the effects of local geometrical constrains on the global pa…
Abstract The controlling of the internal interaction in multichromophores leads to functional dyes with novel properties. Such a controlling is demonstrated with perylene dyes and offers a manifold of novel possibilities.
The effects of side chain length on the molecular aggregation states and surface properties of poly(fluoroalkyl acrylate) [PFA-C y, where y is the fluoromethylene number of the R f groups] thin films were systematically investigated. Spin-coated PFA-C y thin films were characterized by static and dynamic contact angle…
Abstract Surface‐enhanced Raman spectroscopy (SERS) is a powerful technique for the sensitive and selective detection of low‐concentration analytes. This paper includes a discussion of the early history of SERS, the concepts that must be appreciated to optimize the intensity of SERS and the development of SERS‐based s…