Materials Literature
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We propose a concept of half-semiconductor antiferromagnets in which both spin-polarized valence and conduction bands belong to the same spin channel with completely compensated spontaneous magnetization. Using density functional theory plus Hubbard U (DFT+U) methods, we find a viable approach to achieve the half-semi…
We process one-dimensional (1D) NiO nanostructures in anodized alumina templates starting from electrochemically deposited Ni nanotubes (NTs), and characterize their morphology-dependent supercapacitance behavior. The morphology of the 1D NiO nanostructures is controlled by the time of annealing at 450°C. After 25 min…
Whispering-gallery-mode resonators have been extensively used in conjunction with different materials for the development of a variety of photonic devices. Among the latter, hybrid structures, consisting of dielectric microspheres and colloidal core/shell semiconductor nanocrystals as gain media, have attracted intere…
Pulsed electrodeposition of polyaniline (PANI) allows the fabrication of flexible, electrically conductive, nonwoven PANI-carbon nanotube (PANI-CNT) composite fabrics. They possess specific tensile strength and a modulus of toughness higher than that of aluminum matrix composites, titanium and aluminum alloys, steels,…
The directed assembly of nanoparticle building blocks is a promising method for generating sophisticated three-dimensional materials by design. In this work, we have used DNA linkers to synthesize nanoparticle superlattices that have greater complexity than simple binary systems using the process of topotactic interca…
Spins of negatively charged nitrogen-vacancy (NV${}^{\ensuremath{-}}$) defects in diamond are among the most promising candidates for solid-state qubits. The fabrication of quantum devices containing these spin-carrying defects requires position-controlled introduction of NV${}^{\ensuremath{-}}$ defects having excelle…
A high yield (>36 wt %) method has been developed of preparing monolayered tungsten dichalcogenide (WS2) quantum dots (QDs) with lateral size ∼8-15 nm from multilayered WS2 flakes. The monolayered WS2 QDs are, like monolayered WS2 sheets, direct semiconductors despite the flake precursors being an indirect semiconduct…
Upconversion nanophosphors have the ability to generate visible or near-infrared (NIR) emissions under continuous-wave NIR excitation. Utilizing this special photoluminescent properties, upconversion nanophosphors can be used as key components in complex nanocomposites for a wide range of applications. This review sum…
For the first time, polyethyleneimine (PEI) doping on multilayer MoS2field-effect transistors is investigated. A 2.6 times reduction in sheet resistance and 1.2 times reduction in contact resistance have been achieved. The enhanced electrical characteristics are also reflected in a 70% improvement in ON-current and 50…
Graphene electronic devices can be made by top-down (TD) or bottom-up (BU) approaches. This Perspective defines and explains those two approaches and discusses the advantages and limitations of each, particularly in the context of graphene fabrication. It is further exemplified using graphene nanoribbons as the protot…
The two-coordinate cationic Ni(I) bis-N-heterocyclic carbene complex [Ni(6-Mes)2]Br (1) [6-Mes =1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene] has been structurally characterized and displays a highly linear geometry with a C-Ni-C angle of 179.27(13)°. Density functional theory calculations reve…
We calculate from first principles the electronic structure and optical properties of a number of transition metal dichalcogenide (TMD) bilayer heterostructures consisting of MoS${}_{2}$ layers sandwiched with WS${}_{2}$, MoSe${}_{2}$, MoTe${}_{2}$, BN, or graphene sheets. Contrary to previous works, the systems are c…
Exposure to ultraviolet (UV) radiation may cause the significant degradation of many materials. UV radiation causes photooxidative degradation which results in breaking of the polymer chains, produces free radical and reduces the molecular weight, causing deterioration of mechanical properties and leading to useless m…
Park J., Khim J.S., Ryu J., Koh C.-H. and Witkowski A. 2013. An emended description of the genus Fogedia (Bacillariophyceae) with reports of four species new to science from a Korean sand flat. Phycologia 52: 437–446. DOI: 10.2216/12–120.1A taxonomic investigation of the microphytobenthos from the lower intertidal zon…
Abstract Real cloth exhibits bending effects, such as residual curvatures and permanent wrinkles. These are typically explained by bending plastic deformation due to internal friction in the fibre and yarn structure. Internal friction also gives rise to energy dissipation which significantly affects cloth dynamic beha…
In this work, we employ scanning near-field optical microscopy, full-vector finite difference time domain numerical simulations and fractional Fourier transformation to investigate the near-field and propagation behavior of the electromagnetic energy scattered at 1.56 μ m by dielectric arrays of silicon nitride nanopi…
The structural and thermodynamic properties of tetragonal-TiH2 under high temperatures and pressures are investigated by Ab initio calculations based on pseudo-potential plane-wave density functional theory method within using the generalized gradient approximation (GGA) and quasi-harmonic Debye model. Some ground sta…
Abstract The bacterial plastic poly(3‐hydroxybutyrate) ( PHB ) has many practical applications but its commercial potential is presently limited, partly due to the challenge of achieving appropriate mechanical performance characteristics. One method of tailoring the physical properties of the polymer is to control its…
Overbased calcium sulfonate is one of the largest commercially produced nanomaterials; the phase transformation mechanism involved in the key process of carbonation reaction for overbased detergent preparation has not yet been fully understood. Following our previous investigation based on the heavy alkylbenzene sulfo…
Ytterbium 3+ ions in alcohol were found to be reduced to the corresponding 2+ ions upon laser irradiation with a stepwise two-color two-photon excitation. The infrared (975-nm) pulse with a duration of 4 ns pumps the ground state to the 4f excited state with the transition of (2)F(5/2) ← (2)F(7/2), and the second phot…