Materials Literature
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We present the first review of the current state of the literature on electronic properties and phase transitions in TlX and TlMX 2 (M = Ga, In; X = Se, S, Te) compounds. These chalcogenides belong to a family of the low-dimensional semiconductors possessing chain or layered structure. They are of significant interest…
We have analyzed theoretically the Zeeman splitting of hole-quantum-wire subband edges. As is typical for any bound state, their g factor depends on both an intrinsic g factor of the material and an additional contribution arising from a finite bound-state orbital angular momentum. We discuss the quantum-confinement-i…
Light elements in the iron-rich core of the Earth are important indicators for the evolution of our planet. Their amount and distribution, and the temperature in the core, are essential for understanding how the core and the mantle interact and for modelling the geodynamo which generates the planetary magnetic field.…
Exciton instability in graphene bilayer systems is studied in the case of a short-ranged Coulomb interaction and a finite voltage difference between the layers. Self-consistent exciton gap equations are derived and solved numerically and analytically under controlled approximation. We obtain that a critical strength o…
We have investigated electrical transport through the molecular model systems benzenedithiol, benzenediamine, hexanedithiol and hexanediamine. Conductance histograms under different experimental conditions indicate that measurements using mechanically controllable break junctions in vacuum are limited by the surface d…
and β-Sialon.
Strongly correlated electron insulators are one of the most important classes of materials in modern solid-state physics. We demonstrate that certain classes of Mott insulators, that usually are geometrically frustrated, exhibit unexpected charge effects: for certain spin textures, spontaneous circular electric curren…
By coating fibers with titania sol to generate a dual-size surface roughness, followed by hydrophobization with stearic acid, 1H,1H,2H,2H-perfluorodecyltrichlorosilane or their combination, hydrophilic cotton fabrics were made superhydrophobic. The surface wettability and topology of cotton fabrics were studied by con…
A series of multiferroic $(1\ensuremath{-}x){\text{BiFeO}}_{3}\ensuremath{-}x{\text{PbTiO}}_{3}$ solid solution ceramics were prepared by solid-state reactions. Structural characterization by x-ray diffraction reveals the existence of a morphotropic phase boundary (MPB) region in this system in which a tetragonal, a r…
In this paper, we investigated the fluorescent properties of gold nanoparticles (GNPs) with several tens of nanometers by ensemble fluorescence spectrometry, fluorescence correlation spectroscopy (FCS), and fluorescence microscopy. We observed that GNPs synthesized by the citrate reduction of chloroauric acid possesse…
Bulk Mg2Si crystals were grown using the vertical Bridgman melt growth method. The n-type and p-type dopants, bismuth (Bi) and silver (Ag), respectively, were incorporated during the growth. X-ray powder diffraction analysis revealed clear peaks of Mg2Si with no peaks associated with the metallic Mg and Si phases. Res…
Amyloids are self-assembled protein architectures implicated in dozens of misfolding diseases. These assemblies appear to emerge through a “selection” of specific conformational “strains” which nucleate and propagate within cells to cause disease. The short Aβ(16−22) peptide, which includes the central core of the Alz…
We report an environmentally benign process for the synthesis of nearly monodisperse silver nanoparticles in large quantities via a microwave-assisted “green” chemistry method in an aqueous system, using basic amino acids, such as l -lysine or l -arginine, as reducing agents and soluble starch as a protecting agent. T…
Time-dependent density functional theory calculations are employed to calculate the optical absorption spectra of silver tetrahedral Ag n ( n = 10, 20, 35, 56, 84, 120) clusters with emphasis on neutral and ion clusters that correspond to shell closings. For the Ag 20 cluster, the convergence properties of the spectra…
Electrochemical sensors for the analysis of TNT with enhanced sensitivities are described. The enhanced sensitivities are achieved by tailoring pi-donor-acceptor interactions between TNT and pi-donor-modified electrodes or pi-donor-cross-linked Au nanoparticles linked to the electrode. In one configuration a p-aminoth…
We have carried out optical-absorption and reflectance measurements at room temperature in single crystals of AWO 4 tungstates (A=Ba, Ca, Cd, Cu, Pb, Sr, and Zn). From the experimental results their band-gap energy has been determined to be 5.26 eV (BaWO 4 ), 5.08 eV (SrWO 4 ), 4.94 eV (CaWO 4 ), 4.15 eV (CdWO 4 ), 3.…
Spin-crossover coordination nanoparticles of the cyanide-bridged three-dimensional network Fe(pyrazine){Pt(CN) 4} were prepared at three different sizes using a microemulsion. The 14 nm particles present a transition centered around 265 K with a hysteresis of 6 K.
A highly stable porous lanthanide metal-organic framework, Y(BTC)(H2O).4.3H2O (BTC = 1,3,5-benzenetricarboxylate), with pore size of 5.8 A has been constructed and investigated for hydrogen storage. Gas sorption measurements show that this porous MOF exhibits highly selective sorption behaviors of hydrogen over nitrog…
We present a comparative study of optical and electronic properties for PbS nanocrystals and Au-PbS core-shell nanostructures. In Au-PbS nanostructures, we observed two nontrivial synergistic effects: (i) extinction enhancement due to coupling of surface plasmon resonance in the Au core to the excitonic states in the…
Abstract The growth and characteristics of nanocrystalline diamond thin films with thicknesses from 20 nm to less than 5 µm are reviewed. These materials contain between 95% and >99.9% diamond crystallites, the balance being made up from other forms of carbon. Within this class of materials there is a continuous ra…