Materials Literature
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Abstract A simple, one‐step synthetic route to prepare ordered mesoporous silica monoliths with controllable quantities of metal oxide nanocrystals in their channels is presented. The method is based on the assisted assembly effect for mesostructure‐directing of the metal complexes formed by the interaction of metal i…
Abstract Copper nanocrystals with plate‐like morphologies and face‐centered cubic (fcc) structures have been synthesized in mixed reverse micelles with a large excess of reducing agent. High‐resolution transmission electron microscopy images and image simulations show the presence of multiple twin defects parallel to…
Abstract Preparation of coaxial (core–shell) CdS–ZnS and Cd 1– x Zn x S–ZnS nanowires has been achieved via a one‐step metal–organic chemical vapor deposition (MOCVD) process with co‐fed single‐source precursors of CdS and ZnS. Single‐source precursors of CdS and ZnS of sufficient reactivity difference were prepared a…
Abstract Hydrothermally stable thioether‐bridged mesoporous materials have been synthesized by one‐step co‐condensation of 1,4‐bis(triethoxysily)propane tetrasulfide (TESPTS) with tetramethoxysilane (TMOS) using cetyltrimethylammonimum bromide (CTAB) as the surfactant in basic conditions. The ordered mesoporous materi…
Filling in the gaps of activated carbon by chemical vapor decomposition of ethylene results in hierarchically structured carbon with carbon nanofibers (CNFs) nested inside and immobilized on the surface (see picture). The adsorption experiments show that this nanostructuring of carbon creates novel functions on the su…
This study explores the origin of the native donor in undoped In2O3. The electronic structure of various point defects in In2O3 clusters is studied using the first-principles molecular orbital calculation. The results show that an oxygen vacancy cannot act as a native donor, because the defect level formed is much low…
We report the results of magnetization, zero-field resistivity, and magnetoresistance measurements in the ferromagnetic Heusler alloy ${\mathrm{Co}}_{2}\mathrm{TiSn}$. There is a striking change in the character of electron transport as the system undergoes the paramagnetic to ferromagnetic transition. In the paramagn…
Abstract The Archimedean tiling (3 2 .4.3.4) is a regular but complex polygonal assembly of equilateral triangles and squares. This tiling pattern with mesoscopic repeating distance has been found for an ABC star‐branched three‐component polymer composed of polyisoprene, polystyrene, and poly(2‐vinylpyridine). In this…
We consider theoretically a current flowing perpendicular to interfaces of a spin-valve type ferromagnetic metallic junction. For the first time an effective approach is investigated to calculate a simultaneous action of the two current effects, namely, the nonequilibrium longitudinal spin injection and the transversa…
Abstract Recently, we have developed a novel family of functionalized nanostructures that exhibit liquid‐like behavior in the absence of solvents and preserve their nanostructure in the liquid state. The gallery of nanostructures developed so far includes functionalized silica and magnetic iron oxide nanoparticles, la…
We report angle resolved photoemission (ARPES) spectra of $η$-Mo$_4$O$_{11}$, a layered metal that undergoes two charge density wave (CDW) transitions at 109 K and 30 K. We have directly observed the ``hidden one-dimensional (hidden-1d)'' Fermi surface and an anisotropic gap opening associated with the 109 K transitio…
A new and known barium cerates doped by In and Ga were synthesized in air at 1700 K. The synthesis was performed by solid state reactions from BaCO3, CeO2, In2O3 or Ga2O3. X-ray diffraction profiles of the powdered samples were obtained with DRON-UM-1 and STADI-P diffractometers using monochromatized CuKa radiation. T…
The optical absorptions of different Au32 isomers in the whole frequency range from the far-infrared (FIR) to near-ultraviolet (UV) have been calculated using the relativistic density-functional method in order to identify their geometrical structures. It is found that there exists a distinctive difference between the…
The periodic deviations of ferromagnetic and antiferromagnetic spins from corresponding uniform configurations are shown to be energetically favorable close to a compensated interface of ferromagnetic antiferromagnetic bilayer. The amplitude of the deviations decreases exponentially into the film volumes as a function…
Carbon nanotubes (CNT) have a very large application potential in the rapid developing field of molecular electronics. Infinite single-wall metallic CNTs have theoretically a conductance of 4e2/h because of the two electronic bands crossing the Fermi level. For finite size CNTs experiments have shown that other values…
We consider the probability distribution for fluctuations in dynamical action and similar quantities related to dynamic heterogeneity. We argue that the so-called "glass transition" is a manifestation of low action tails in these distributions where the entropy of trajectory space is subextensive in time. These low ac…
Single-phase vanadium dioxide (VO2) thin films have been grown on Si3N4∕Si substrates by means of a well-controlled magnetron sputtering process. The deposited VO2 films were found to exhibit a semiconductor-to-metal transition (SMT) at ∼69°C with a resistivity change as high as 3.2 decades. A direct and clear-cut cor…
Abstract Titanium thin films, 400 nm to 1000 nm thick, fabricated by radio frequency (rf) sputter deposition are anodized in an electrolyte containing acetic acid and hydrofluoric acid to form optically transparent films of highly ordered titania nanotube arrays. Real‐time monitoring of the anodization current, at a f…
The approximate representation of a quantum solid as an equivalent composite semi-classical solid is considered for insulating materials. The composite is comprised of point ions moving on a potential energy surface. In the classical bulk domain this potential energy is represented by pair potentials constructed to gi…
Abstract ZnO fibers are synthesized by hydrothermal method from Zn(OH)42− starting solution. The morphologies of obtained ZnO fibers are closely related to the hydrothermal treatment temperature and Zn2+/OH− ratio, and the bunch-like growth phenomenon is revealed by scanning electron microscopy (SEM) and transmission…