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Flash grafting of functional random copolymers for surface neutralization

Federico Ferrarese Lupi、Tommaso Jacopo Giammaria、Gabriele Seguini 等 9 位作者2014-01-01Journal of Materials Chemistry C

Rapid Thermal Processing (RTP) technology was employed to perform flash grafting reactions of a hydroxyl terminated poly(styrene- <italic>r</italic> -methylmethacrylate) random copolymer to a silicon surface.

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresNanofabrication and Lithography Techniques

The multiple core–shell structure in Cu24Ln6 cluster with magnetocaloric effect and slow magnetization relaxation

Gang Xiong、Hang Xu、Jian‐Zhong Cui 等 5 位作者2014-01-01Dalton Transactions

Triple core-shell structures in the Cu24Gd6 and Cu24Dy6 clusters were first observed and structurally characterized. The magnetic investigations reveal that Cu24Gd6 possesses the significant magnetic entropy change (-ΔSm) of 21.2 J kg(-1) K(-1) for ΔH = 7 T, and a slow magnetization relaxation is observed in Cu24Dy6.

Magnetic and transport properties of perovskites and related materialsMagnetism in coordination complexesNanocluster Synthesis and Applications

Improved efficiency of bulk heterojunction hybrid solar cells by utilizing CdSe quantum dot–graphene nanocomposites

Michael J. Eck、Chuyen Van Pham、Simon Züfle 等 11 位作者2014-01-01Physical Chemistry Chemical Physics

We present a significant efficiency enhancement of hybrid bulk heterojunction solar cells by utilizing CdSe quantum dots attached to reduced graphene oxide (rGO) as the electron accepting phase, blended with the PCPDTBT polymer. The quantum dot attachment to rGO was achieved following a self-assembly approach, recentl…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Reversible photocontrolled disintegration of a dimeric tetraurea-calix[4]pyrrole capsule with all-trans appended azobenzene units

Laura Osorio‐Planes、Mónica Espelt、Miquel À. Pericàs 等 4 位作者2014-01-01Chemical Science

The light-induced <italic>trans</italic> -to- <italic>cis</italic> -isomerization of a single azobenzene moiety triggers the disintegration of a dimeric tetraurea calix[4]pyrrole capsule.

Luminescence and Fluorescent MaterialsPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Nanoalloying bulk-immiscible iridium and palladium inhibits hydride formation and promotes catalytic performances

Claudia Zlotea、F. Morfin、Thanh‐Son Nguyen 等 8 位作者2014-01-01Nanoscale

The hydrogen sorption properties of oxide-supported Ir-Pd nanoalloys have been determined for the first time, and correlated with their catalytic behavior. The addition of Ir to Pd suppresses hydride formation and leads to improved catalytic performances with respect to pure metals in the preferential oxidation of CO…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceNanomaterials for catalytic reactions

Highly sensitive and multispectral responsive phototransistor using tungsten-doped VO 2 nanowires

Junpeng Lü、Hong Wei Liu、Suzi Deng 等 10 位作者2014-01-01Nanoscale

In this work, we report a novel and feasible strategy for the practical applications of one-dimensional ultrasensitive phototransistors made of tungsten-doped VO2 single nanowires. The photoconductive response of the single nanowire device was investigated under different visible light excitations (405 nm, 532 nm, and…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsGa2O3 and related materials

Graphene oxide hydration and solvation: an in situ neutron reflectivity study

Alexeï Vorobiev、Andrew J. C. Dennison、Dmitry Chernyshov 等 6 位作者2014-01-01Nanoscale

Graphene oxide membranes were recently suggested for applications in separation of ethanol from water using a vapor permeation method. Using isotope contrast, neutron reflectivity was applied to evaluate the amounts of solvents intercalated into a membrane from pure and binary vapors and to evaluate the selectivity of…

Graphene research and applicationsMembrane Separation TechnologiesNanopore and Nanochannel Transport Studies

Pentaarylbiimidazole, PABI: an easily synthesized fast photochromic molecule with superior durability

Hiroaki Yamashita、Jiro Abe2014-01-01Chemical Communications

We report a new type of fast photochromic imidazole dimer, pentaarylbiimidazole (PABI), which shows a few μs fast photochromism with high fatigue resistance against light irradiation. PABI has an unusual spiroconjugated imidazoisoindole skeleton and its derivatives can be prepared by simple synthetic procedures.

Radical Photochemical ReactionsPorphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence Chemistry

Facile synthesis of self-assembled spherical and mesoporous dandelion capsules of ZnO: efficient carrier for DNA and anti-cancer drugs

Vijay Bhooshan Kumar、Koushi Kumar、Aharon Gedanken 等 4 位作者2014-01-01Journal of Materials Chemistry B

complex, in medical biotechnology. The fabrication of such self-assembled idiosyncratic capsules is very simple, feasible, and cost effective; moreover, it demonstrates improved performance in drug and gene delivery applications.

Advanced biosensing and bioanalysis techniquesMesoporous Materials and CatalysisCopper-based nanomaterials and applications

An active-core/active-shell structure with enhanced quantum-cutting luminescence in Pr–Yb co-doped monodisperse nanoparticles

Wenjuan Zhu、Daqin Chen、Lei Lei 等 5 位作者2014-01-01Nanoscale

Monodisperse Pr(3+)/Yb(3+):NaGdF₄@NaYF₄ active-core/inert-shell nanoparticles, which exhibit efficient near-infrared quantum-cutting luminescence, are successfully prepared. In order to relieve the adverse effect caused by concentration quenching in the core, the extra Yb(3+) ions are introduced into the shell, formin…

Luminescence Properties of Advanced MaterialsLuminescence and Fluorescent MaterialsOptical properties and cooling technologies in crystalline materials

Synthesis and Structural Analysis of Nanocrystalline MnFe2O4

T. Shanmugavel、S. Gokul Raj、G. Ramesh Kumar 等 4 位作者2014-01-01Physics Procedia

Nanocrystalline form of manganese ferrite (MnFe2O4) has been synthesized by simple sol-gel auto combustion method using citric acid as chelating agent. The obtained nanocrystalline powders of manganese ferrite were subjected to structural and magnetic measurements. Temperature dependent magnetization was also carried…

Magnetic Properties and Synthesis of FerritesIron oxide chemistry and applicationsCharacterization and Applications of Magnetic Nanoparticles

Finite Element Simulation of Residual Stresses in Cryogenic Machining of AZ31B Mg Alloy

Z. Pu、Domenico Umbrello、O. W. Dillon 等 4 位作者2014-01-01Procedia CIRP

Magnesium alloys are lightweight materials primarily used in transportation industry, and are also emerging as a potential material for biodegradable fixation implants. However, unsatisfactory corrosion resistance largely limits the application of these materials. Residual stresses were reported to have significant in…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Silver- and sulfadiazine-loaded nanostructured silica materials as potential replacement of silver sulfadiazine

Ágnes Szegedi、Margarita Popova、Krassimira Yoncheva 等 6 位作者2014-01-01Journal of Materials Chemistry B

Silver sulfadiazine (AgSD) is the leading topical antibacterial agent for the treatment of burn wound infections. Antibacterial effect of AgSD is limited by its poor aqueous solubility, and antibacterial activity develops only by decomposition of AgSD to silver ions and sulfadiazine. In this study, it is for the first…

Nanoparticles: synthesis and applicationsNanomaterials for catalytic reactionsAdvanced Nanomaterials in Catalysis

Free-standing carbon nanotube/graphene hybrid papers as next generation adsorbents

Anthony B. Dichiara、Tyler J. Sherwood、Jared Benton-Smith 等 6 位作者2014-01-01Nanoscale

The adsorption of a series of aromatic compounds from aqueous solution onto purified, free-standing single-walled carbon nanotube/graphene nanoplatelet hybrid papers is studied both experimentally and theoretically. Experimental data is obtained via changes in optical absorption spectra of the aqueous solutions and is…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

A facile, morphology-controlled synthesis of potassium-containing manganese oxide nanostructures for electrochemical supercapacitor application

N. Sankara Subramanian、B. Viswanathan、Thirukkallam Kanthadai Varadarajan2014-01-01RSC Advances

A chemical reduction-based, morphology-controlled synthesis of K-containing manganese oxide nanostructures for electrochemical supercapacitor application.

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionSupercapacitor Materials and Fabrication

Size Dependence of Magnetic and Optical Properties of Co 3 O 4 Nanoparticles

A.K. Sarfraz、S. K. Hasanain2014-01-01Acta Physica Polonica A

The eect of particle size on the magnetic and optical properties of cobalt oxide Co3O4 has been investigated. Single phase Co3O4 nanoparticles were synthesized by co-precipitation route and their structure was conrmed through X-ray diraction analysis. The average crystallite sizes of the nanoparticles as determined fr…

Magnetic properties of thin filmsZnO doping and propertiesMagnetic Properties and Synthesis of Ferrites

Fabrication and characterization of silica nanotubes with controlled dimensions

Wenjian Zhang、Chun‐Yan Hong、Cai‐Yuan Pan2014-01-01Journal of Materials Chemistry A

Silica nanotubes with controlled diameters and lengths were fabricated by a template-directed method. Nanowires composed of poly(2-dimethylaminoethyl methacrylate)-block-polystyrene (PDMAEMA–PS), which were fabricated by RAFT dispersion polymerization of styrene in methanol using PDMAEMA as a macro-RAFT agent, were us…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesElectrophoretic Deposition in Materials Science

Photoelectrochemical and electrocatalytic properties of thermally oxidized copper oxide for efficient solar fuel production

Angel T. Garcia‐Esparza、Kevin Limkrailassiri、Frédéric Leroy 等 7 位作者2014-01-01Journal of Materials Chemistry A

A thorough characterization of thermally obtained Cu( <sc>i</sc> )/Cu( <sc>ii</sc> ) oxide (photo)electrodes has been conducted for applications of solar fuel generation.

Advanced Photocatalysis TechniquesZnO doping and propertiesCopper-based nanomaterials and applications

Electronic structure study of Ce 1−x A x O 2 (A = Zr & Hf) nanoparticles: NEXAFS and EXAFS investigations

Aditya Sharma、Mayora Varshney、Hyun‐Joon Shin 等 8 位作者2014-01-01Physical Chemistry Chemical Physics

Single phase nanoparticles (NPs) of CeO2, Ce0.5Zr0.5O2, Ce0.5Hf0.5O2 and Ce0.5Hf0.25Zr0.25O2 were successfully synthesized by co-precipitation method at constant pH and temperature. The X-ray diffraction results revealed that the additive atoms did not segregate to form secondary phases but led to grain size variation…

ZnO doping and propertiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Structural effect on the resistive switching behavior of triphenylamine-based poly(azomethine)s

Wenbin Zhang、Cheng Wang、Gang Liu 等 6 位作者2014-01-01Chemical Communications

Linear and hyperbranched poly(azomethine)s (PAMs)-based on triphenylamine moieties are synthesized and used as the functioning layers in the Ta/PAM/Pt resistive switching memory devices. Comparably, the hyperbranched PAM with isotropic architecture and semi-crystalline nature shows enhanced memory behaviors with more…

Organic Electronics and PhotovoltaicsAdvanced Memory and Neural ComputingConducting polymers and applications