Materials Literature
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The Sternheimer quadrupole antishielding factor ${\ensuremath{\gamma}}_{\ensuremath{\infty}}$ including self-consistency effects have been studied for several closed-shell ions isoelectronic with He, Ne, A, Kr, Xi, ${\mathrm{Cu}}^{+}$, and ${\mathrm{Ag}}^{+}$ in both free state as well as in ionic solid-state systems.…
Elemental sulfur undergoes oxidation to sulfate when heterogeneous mixtures of sulfur and water absorb ionizing radiation in deaerated systems. No sulfur-containing product other than sulfuric acid is formed in measurable yield. The reaction is initiated by OH radicals from water, and these are evidently involved in s…
KEYWORDS: radioactive combustible wasteswaste processingvolume reductionacid digestionion exchange resinsorganic waste materialshydrogen peroxide
A new rechargeable cell Na/Na + ion in molten is described. This cell operates at temperatures in the range of 180°–250°C and has an open‐circuit voltage of 4.2V. The discharge process involves the reduction of tetravalent sulfur to the elemental state; sulfur can be further reduced to sulfide. The preferred sodium io…
A single crystal LaB6 electron gun for variably shaped beams was developed. For the 50 A/cm2 density, 3 μm length maximum beam size, and 1 μA maximum beam current, the best electron gun characteristics were analysed. Optimum brightnesss is 2.5×105 A/cm2 sr. The product of crossover diameter and beam divergence semiang…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEntropy, enthalpy, and side-arm porphyrins. 2. Crystal and molecular structure of a 5-coordinate zinc porphyrin with a four-atom chain attaching the pyridyl ligand to the tetraphenylporphyrinMichael A. Bobrik and F. Ann WalkerCite this: Inorg. Chem. 1980, 19, 11, 3383–3390Pu…
Infrared absorption spectra between 50 and 350 cm−1 have been obtained of argon matrices containing UO3 and UO2. The frequencies of all three expected low-frequency vibrational modes of U16O3 have been identified and measured (±0.1 cm−1): ?3(A1)=186.2, ?5(B1)=211.6, and ?6(B2)=151.5 cm−1. The effects of 18O-substituti…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal and molecular structure of cofacial dicopper hexyldiporphyrin-7Marcos H. Hatada, A. Tulinsky, and C. K. ChangCite this: J. Am. Chem. Soc. 1980, 102, 23, 7115–7116Publication Date (Print):November 5, 1980Publication History Published online1 May 2002Published inissue…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTResponse of Catalyst Surface Concentrations to Forced Concentration Oscillations in the Gas Phase. The NO, CO, O2 System over Pt-AluminaL. Louis Hegedus, Charles C. Chang, David J. McEwen, and Elaine M. SloanCite this: Ind. Eng. Chem. Fundamen. 1980, 19, 4, 367–373Publicatio…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolybdenum(V) tetraphenylporphyrin complexes revisited. Preparation and characterization of oxohydroxo(5,10,15,20-tetraphenylporphyrinato)molybdenum(V), O = Mo(TPP)OHHenry J. Ledon, Michel C. Bonnet, Yves Brigandat, and Francois VaresconCite this: Inorg. Chem. 1980, 19, 11,…
A scanning electron microscope investigation has been conducted on selected line-pipe steels that had been exposed to the hydrogen sulfide in the British Petroleum test. The results show that: (1) Hydrogen induced blister cracking initiates at elongated manganese sulfide inclusions confirming the findings of other wor…
Abstract In its present state this model should be effective as an aid in analyzing and optimizing cure cycles for vulcanizing articles. It is clearly necessary to have accurate thermo-physical data when simulating the SOC in thick articles. Additional improvements could be realized by more careful treatment of the he…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAn efficient, high conversion photoinduced emulsion polymerization. Magnetic field effects on polymerization efficiency and polymer molecular weightNicholas J. Turro, Ming-Fea Chow, Chao-Jen Chung, and Chen-Ho TungCite this: J. Am. Chem. Soc. 1980, 102, 24, 7391–7393Publicat…
Young's modulus at room temperature and the fracture surface energy, up to 1200°C, were determined for boron carbide specimens with 0 to 15% porosity. Sonic modulus measurements indicated that the Young's modulus decreased as porosity increased in a manner characteristic of the cylindrical pore model. The fracture sur…
Abstract Interactions of lime, phosphorus (P), and zinc (Zn) in two coarse‐textured Ultisols from southeastern Nigeria were examined by means of factorial soil incubation and phosphate sorption experiments. In both soils, liming reduced exchangeable aluminum (Al) saturation from 45% to < 5% at pH 5.0 and soil solut…
The structure and inhibitive properties of benzotriazole on copper, copper-based alloys, silver, and other metals.
Kinetic studies on the thermal and oxidative decomposition of untreated cellulosic insulation have been carried out with thermal analytical techniques (TGA and DSC) to provide input parameters for smoldering studies of this material. In dry nitrogen, the weight loss proceeds in one overall step that follows a diffusio…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTExcess entropies and related quantities in glass-forming liquidsV. P. PrivalkoCite this: J. Phys. Chem. 1980, 84, 24, 3307–3312Publication Date (Print):November 1, 1980Publication History Published online1 May 2002Published inissue 1 November 1980https://pubs.acs.org/doi/10.…
Abstract— Carotenoid to porphyrin singlet‐singlet energy transfer has been observed in a new covalently linked carotenoid‐porphyrin ester. Nuclear magnetic resonance studies reveal that the relatively high energy transfer efficiency (˜ 25%) is a result of a stacked conformation in which the 26 π electron carotenoid ch…
The hydrogen storage compound LaNi 5 is an exchange-enhanced Pauli paramagnet with susceptibility chi (LaNi 5 )=4.6*10 -6 EMU g -1 . Hydrogen absorption leads to a decrease of the susceptibility of chi (LaNi 5 H 6.0 )=1.3*10 -6 EMU g -1 . This decrease is usually covered by a strong irreversible increase of surface ma…