Materials Literature
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The structure of alpha-D-glucose-NaCl is presented. C6H12O6.1/2(NaCl).0.39(H2O), Mr = 216.40, trigonal, P3(1)21, a = b = 9.721 (3), c = 17.06 (1) A, V = 1396 (1) A3, Dm = 1.54 (1), Dx = 1.54 g cm-3, lambda(Mo K alpha) = 0.71073 A, mu = 2.859 cm-1, F(000) = 683.4, T = 293 K, final R = 0.044 for 744 reflections with I g…
Dependences of secondary electron emission of copper bombarded by an electron and an ion on the angle of incidence are investigated for the bombarding energies from 100 eV to 1 MeV, using a Monte Carlo simulation of the kinetic emission. The inverse cosine of the angle measured from the normal to the surface overestim…
Cristallisation dans C2/m avec a=11,663, b=3,6532, c=8,92 A, β=90,91, Z=4, affinement jusqu'a R=0,056. Les octaedres deformes de VO 6 sont lies et forment des couches de V 2 O 5 paralleles a (001). Les ions Na sont situes entres ces couches et entoures par sept atomes O
It is shown that in the nonretarded regime, the frequency of the long-wavelength surface plasmon of a free-electron metal is directly related to the overlap of the metal's unperturbed electron density and the normalized, fluctuating potential of the surface plasmon. This result directly expresses the idea that the sur…
We present results for the temperature dependence of electrical conductivity for amorphous ${\mathrm{V}}_{\mathit{x}}$${\mathrm{Si}}_{1\mathrm{\ensuremath{-}}\mathit{x}}$ alloys. The alloys investigated span the composition range from x=0.5 to 0.1. For the alloys with more than 20 at. % V, the temperature dependence c…
We have measured the oxygen-nickel distance in Ni(111)-p(2\ifmmode\times\else\texttimes\fi{}2)O using the electron-energy-loss fine-structure technique. Using the phase shift obtained on a heavily oxidized sample, we obtained 1.94\ifmmode\pm\else\textpm\fi{}0.05 \AA{}. This value is in slight disagreement with that ob…
2C 8 H 12 N + •CuCl 4 2− (I) cristallise dans P cab avec a=7,328, b=7,295, c=36,618 A, Z=4, affinement jusqu'a R=0,068. 2C 8 H 12 N + •CuBr 4 2− cristallise dans P cab avec a=7,654, b=7,756, c=38,042 A, Z=4, affinement jusqu'a R=0,067. Chaque ion de cuivre forme quatre liaisons Cu-X (X=Cl − , Br − ) dans un arrangemen…
X-ray photoemission and synchrotron-radiation photoemission were used to study the reaction of metals and molecular oxygen at low temperatures. Combined core-level and valence-band measurements permit the identification of various oxygen species. When Li, Cs, K, and La are deposited on solid oxygen, an O 1s feature ne…
We develop a model to explain the universal low-temperature properties of glasses in the 1T10 K temperature range. Our model consists of elastic dipole ``defects'' which are placed randomly in an elastic continuum. We derive a Hamiltonian for defects interacting via their long-range strain fields. We simulate a system…
We derived equations for the target-strength term used in the modified hydrodynamic model that describes long rod penetration into ceramic targets. Since ceramics have tensile strengths that are usually an order of magnitude lower than their compressive strength, this model allows for tensile cracking. In addition, ou…
As many as thirty-seven $^{2\mathit{S}+1}$${\mathit{L}}_{\mathit{J}}$ multiplet manifolds of ${\mathrm{Nd}}^{3+}$(4${\mathit{f}}^{3}$) have been analyzed in the garnets ${\mathrm{Y}}_{3}$${\mathrm{Al}}_{5}$${\mathrm{O}}_{12}$ (YAG), ${\mathrm{Y}}_{3}$${\mathrm{Sc}}_{2}$${\mathrm{Al}}_{3}$${\mathrm{O}}_{12}$ (YSAG), ${…
We have reinvestigated the use of ionizing radiations to measure the molecular mass of water-soluble or membrane proteins. The test was performed by using the most straightforward aspect of the technique, which consists of SDS/PAGE analysis of the protein-fragmentation process. We found that exposure of purified stand…
High-purity silicas synthesized by various manufacturing methods were studied by electron-spin resonance after being irradiated by ArF excimer laser (6.4 eV) at room temperature. E' centers (?Si\ensuremath{\cdot}) are induced in all samples, while nonbridging oxygen hole centers (?Si-O\ensuremath{\cdot}) appear only i…
Affinement dans P nam avec a=23,490, b=21,245, c=4,020 A, Z=4, R=0,077. Discussion de l'arrangement de base des atomes et de la distribution des cations determines par l'affinement d'occupation de site et par l'analyse des liaisons de valence. Comparaison avec les resultats obtenus auparavant
A computational technique is proposed for the analysis of optical absorption spectra for a variety of materials in terms of the well established power law for the optical absorption coefficient. Values of the power index n and optical energy gap E 0 can be obtained from a linear plot using the standard method of numer…
Fabrication and characterisation of photoelectrochemical solar cells employing flux-grown copper tungstate single crystals have been accomplished. Mott-Schottky plots have been drawn to provide a useful estimation of the properties of CuWO 4 from the measurements, and thus the nature and the values of the parameters N…
A synthetic five-part molecular device has been prepared that uses a multistep electron transfer strategy similar to that of photosynthetic organisms to capture light energy and convert it to chemical potential in the form of long-lived charge separation. It consists of two covalently linked porphyrin moieties, one co…
Introduction Molecules have been found to exist in a rich variety of astrophysical environments, including stellar atmospheres, comets, planetary atmospheres, and the dense and diffuse clouds in the interstellar medium. An understanding of molecular structure, spectroscopy, and photoabsorption processes is thus of cri…
The structural bovine eye lens protein alpha-crystallin was dissociated in 7 M urea and its four subunits, A1, A2, B1, and B2, were separated by means of ion-exchange chromatography. Homopolymeric reaggregates of these subunits were prepared by removal of the denaturant via dialysis. It was found that subunits were ex…
We have previously shown [Goto, Y., Calciano, L. J., & Fink, A. L. (1990) Proc. Natl. Acad. Sci. U.S.A. 87, 573-577] that beta-lactamase, cytochrome c, and apomyoglobin are maximally unfolded at pH 2 under conditions of low ionic strength, but a further decrease in pH, by increasing the concentration of HCl, refolds t…