Materials Literature
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In this study, noncovalent functionalization of single-walled carbon nanotubes (SWCNTs) with phospholipid-polyethylene glycols (Pl-PEGs) was performed to improve the solubility of SWCNTs in aqueous solution. Two kinds of PEG derivatives, ie, Pl-PEG 2000 and Pl-PEG 5000, were used for the PEGylation process. An experim…
Magnetic and crystal structures of superconducting X(y)Fe(2-x)Se₂ (X = Rb and K with T(c) = 31.5 and 29.5 K) have been studied by neutron powder diffraction at room temperature. Both crystals show an ordered iron vacancy pattern and the crystal structure is well described by the I4/m space group with the lattice const…
Single-crystalline Er-doped ZnO nanorod arrays (NRAs) on Ag island films with appropriate annealing show a promising enhancement of 1540 nm emission for optical communication. The enhanced 1540 nm emission of Er-doped ZnO NRAs is attributed to the enhancement of the deep level emission of ZnO host. In an effort to enh…
Three different thickness dense TiO2 (150 nm, 300 nm and 450 nm respectively) films were deposited on ITO substrates by dc reactive magnetron sputtering technique. These dense TiO2 films were used as the blocking layers. After that, TiO2 nanorod films were deposited on these dense TiO2 films by same technique. Both th…
The structural and magnetic properties of the CoNb2O6 compound have been investigated with a particular interest in their low-dimensional magnetic behavior which is characterized by the presence of weakly interacting ferromagnetic chains. We investigate this cobalt niobate by combining magnetic measurements; x-ray and…
This paper performs first-principles calculations to study the structural, mechanical and electronic properties of the spinels ZnAl 2 O 4 , ZnGa 2 O 4 and ZnCr 2 O 4 , using density functional theory with the plane-wave pseudopotential method. Our calculations are in good agreement with previous theoretical calculatio…
Specific features of the thermal behavior of Bi m + 1 Fe m −3 Ti 3 O 3 m + 3 layered perovskite-like compounds (where m takes integer and some fractional values between 3 and 9) were considered, and the temperature limits of stability of these compounds were determined. The phase diagram of the Bi 4 Ti 3 O 12 -BiFeO 3…
Dodecylbenzenesulfonate (DBS) modified Ni R Ti layered double hydroxides (LDHs) with different Ni/Ti molar ratios were prepared as hydrophobic organics sorbent by one-step co-precipitation method. The basal spacing of DBS−Ni R Ti ( d 003 = 2.99−3.54 nm) is significantly increased compared with cyanate-intecalated Ni 5…
Mass production of tires, as well as the difficult storage or elimination is a real environmental problem. Various methods for recycling tires are currently used, such as mechanical grinding, which puts vulcanized rubber, steel, and fibers apart. The rubber may be used in several industrial applications such as floori…
A simple and cost effective chemical technique has been utilized to grow cadmium sulphide (CdS) nanoparticles at room temperature. The sample is characterized with XRD (X-ray diffractometer), SEM (Scanning electron microscope), TEM (Transmission electron microscope) and UV-VIS spectrophotometer. The particle size esti…
This work analysed the effect of chloride deposition on the susceptibility to atmospherically induced stress corrosion cracking (AISCC) of stainless steel type AISI 316L used to manufacture containers for radioactive intermediate level waste in the UK. Using U-bend specimens contaminated with MgCl2, a threshold deposi…
Zn1 − xCoxFe2O4 (x = 0−1 in a step of 0.2) nanoparticles with different range of particle size including 5–10 nm and 200–250 nm have been prepared by sol–gel process. Mössbauer spectra at room temperature indicated that, with increasing cobalt content, there is a transition from paramagnetic to magnetically ordered-fe…
Graphene has been attracting a strong interest as a transparent electrode as well as a THz nanoelectronic device owing to its unique properties. To date, large-area graphene growth has been realized by chemical vapor deposition (CVD) with a catalyst metal. To avoid the transfer of segregated graphene, we have examined…
Abstract Mesoporous materials with pore diameters in the range 2–50 nm forming tubular or fibrous structures are of great interest due to their unique properties. Because they are commonly used as sorbents and catalyst carriers, knowledge of their surface area and porosity is critical. A modified intercalation/deinter…
Two three-dimensional 2p-3d-4f heterometallic frameworks featuring a nanosized Ln(6)Cu(24)Na(12) (Ln = Gd, Dy) cluster as a node have been obtained under microwave irradiation conditions through the reaction of H(2)ANMA (H(2)ANMA = L-alanine-N-monoacetic acid), Cu(NO(3))(2), and Ln(NO(3))(3) (Ln = Gd for 1, Dy for 2)…
Structural and magnetic properties of bulk nanostructural Mn100−xBix (x = 40, 45, 52) permanent magnets prepared by spark plasma sintering technique were studied. The effect of the Mn/Bi ratio on the MnBi low temperature phase (LTP) formation and its magnetic properties were investigated. An increase of the bismuth am…
Abstract Clay processes, mineral reactions, and element budgets in oceans continue to be important topics for scientific investigation, particularly with respect to understanding better the roles of chemistry, formation mechanism, and input from hydrothermal fluids, seawater, and non-hydrothermal mineral phases.To tha…
The temperature dependence of the effective magnetic anisotropy constant, K(T), of MnFe2O4 nanoparticles is obtained based on superconducting quantum interference device magnetometry measurements. The variation of the blocking temperature, TB, as a function of particle radius, r, is first determined by associating the…
An analytic approach to the theory of optical defect modes in chiral liquid crystals (CLCs) is developed. The analytic study is facilitated by the choice of the problem parameters. Specifically, an isotropic layer (with the dielectric susceptibility equal to the average CLC dielectric susceptibility) sandwiched betwee…
Deformation mechanisms of carbon nanotube (CNT) fibres under tensile loading are studied by means of in situ Raman spectroscopy to detect the CNT deformation and stress distributions in the fibres. The G' band in the Raman spectrum responds distinctly to the tensile stress in Raman shift, width and intensity. The G' b…