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Chitosan microparticles as injectable scaffolds for tissue engineering

Dunia M. García Cruz、Jorge L. Escobar Ivirico、Manuela M. Gomes 等 7 位作者2008-07-10Journal of Tissue Engineering and Regenerative Medicine

The use of chitosan microparticles as injectable carriers for cell transplantation represents a promising alternative to avoid the drawbacks of the implantation of other forms of three-dimensional (3D) scaffolds seeded with cells. In this study, a 3D construct is obtained in vitro by combining chitosan microparticles…

Hydrogels: synthesis, properties, applicationsElectrospun Nanofibers in Biomedical Applications3D Printing in Biomedical Research

Superconductivity in Thin Films of Boron-Doped Carbon Nanotubes

N. Murata、J. Haruyama、Jason Reppert 等 8 位作者2008-07-10Physical Review Letters

Superconductivity in carbon nanotubes (CNTs) is attracting considerable attention. However, its correlation with carrier doping has not been reported. We report on the Meissner effect found in thin films consisting of assembled boron (B)-doped single-walled CNTs (B-SWNTs). We find that only B-SWNT films consisting of…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Conformal invariance and shape-dependent conductance of graphene samples

Dmitry A. Abanin、Leonid Levitov2008-07-10Physical Review B

For a sample of an arbitrary shape, the dependence of its conductance on the longitudinal and Hall conductivity is identical to that of a rectangle. We use analytic results for a conducting rectangle, combined with the semicircle model for transport coefficients, to analyze the properties of the graphene monolayer and…

Graphene research and applicationsLow-power high-performance VLSI designQuantum and electron transport phenomena

A Simple and Low-Cost Method for the Preparation of Monodisperse Hollow Silica Spheres

Hua Zou、Shishan Wu、Qianping Ran 等 4 位作者2008-07-10The Journal of Physical Chemistry C

This paper presents a simple and low-cost method to prepare hollow silica spheres. This method is just based on a PVP-involved emulsion polymerization and subsequent sol−gel process. PVP first participated in the polymerization reaction as a stabilizer or surfactant and then played a coupling agent role in the latter…

Mesoporous Materials and CatalysisPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Zn Modification of the Reactivity of Pd(111) Toward Methanol and Formaldehyde

Eseoghene Jeroro、John M. Vohs2008-07-10Journal of the American Chemical Society

The adsorption and reaction of methanol and formaldehyde on two-dimensional PdZn alloys on a Pd(111) surface were studied as a function of the Zn content in the alloy in order to understand the role of Zn in Pd/ZnO catalysts for the steam reforming of methanol (SRM). Temperature programmed desorption (TPD) and high re…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Novel K2NiF4‐Type Materials for Solid Oxide Fuel Cells: Compatibility with Electrolytes in the Intermediate Temperature Range

Ruth Sayers、Jun Liu、B. Rustumji 等 4 位作者2008-07-10Fuel Cells

Abstract Many new materials have been identified as being of potential interest to solid oxide fuel cell developers. Recent work has suggested that materials of the La 2 NiO 4 composition possess sufficient activity to act as an effective cathode. Whilst there have been many studies of the transport properties of mate…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

A Core–Corona Hierarchical Manganese Oxide and its Formation by an Aqueous Soft Chemistry Mechanism

David Portehault、Sophie Cassaignon、Nadine Nassif 等 5 位作者2008-07-10Angewandte Chemie International Edition

No template and no organic medium are needed for the low-temperature, one-pot aqueous route to layered manganese oxides with a hierarchical core–corona architecture (see picture). Particle formation occurs by a two-step precipitation process with two different kinetics.

Supercapacitor Materials and FabricationCopper-based nanomaterials and applicationsLayered Double Hydroxides Synthesis and Applications

Preparation and characterization of water‐blown polyurethane foams from liquefied cornstalk polyol

Yongbin Yan、Hao Pang、Xiaoxu Yang 等 5 位作者2008-07-10Journal of Applied Polymer Science

Abstract Polyurethane foams were prepared from the liquefied cornstalk polyol, which was obtained by the liquefaction of cornstalk in the presence of polyhydric alcohols using sulfuric acid as catalyst. The advisable liquefaction reaction conditions were selected by investigating their influences on the properties of…

Corrosion Behavior and InhibitionPolymer composites and self-healingLignin and Wood Chemistry

Rheology of 1‐butyl‐3‐methylimidazolium chloride cellulose solutions. I. Shear rheology

Rhea J. Sammons、John R. Collier、Timothy G. Rials 等 4 位作者2008-07-10Journal of Applied Polymer Science

Abstract In this article, shear rheology of solutions of different concentrations obtained by dissolution of cellulose in the ionic liquid (IL) solvent 1‐butyl‐3‐methylimidazolium chloride ([Bmim]Cl) was studied by measuring the complex viscosity and dynamic moduli at different temperatures. The obtained viscosity cur…

Advanced Cellulose Research StudiesLignin and Wood ChemistryRheology and Fluid Dynamics Studies

Sintering Characteristic, Microstructure, and Dielectric Relaxor Behavior of (K 0.5 Na 0.5 )NbO 3 –(Bi 0.5 Na 0.5 )TiO 3 Lead‐Free Ceramics

Hongliang Du、Wancheng Zhou、Dongmei Zhu 等 7 位作者2008-07-10Journal of the American Ceramic Society

Highly dense lead‐free ceramics (1− x )(K 0.5 Na 0.5 )NbO 3 − x (Bi 0.5 Na 0.5 )TiO 3 [(1− x )KNN− x BNT] have been synthesized by pressureless sintering owing to the careful control of processing conditions. The densification of (1− x )KNN− x BNT ceramics improves with increasing addition of BNT. The translucence is…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Electromagnetic analysis of cylindrical cloaks of an arbitrary cross section

André Nicolet、Frédéric Zolla、Sébastien Guenneau2008-07-10Optics Letters

We extend the design of radially symmetric invisibility cloaks through transformation optics as proposed by Pendry et al. [Science 312, 1780 (2006)] to coated cylinders of an arbitrary cross section. The validity of our Fourier-based approach is confirmed by both analytical and numerical results for a cloak displaying…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Dynamics of Excited-State Conformational Relaxation and Electronic Delocalization in Conjugated Porphyrin Oligomers

Ming‐Hua Chang、Markus Hoffmann、Harry L. Anderson 等 4 位作者2008-07-10Journal of the American Chemical Society

We have investigated the influence of nuclear geometric relaxation on the extent of the excited-state electronic delocalization in conjugated zinc porphyrin oligomers using ultrafast transient photoluminescence spectroscopy. By use of metal-coordinating templates that force the oligomers into specific geometries in so…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Iridium‐Catalyzed Dehydrocoupling of Primary Amine–Borane Adducts: A Route to High Molecular Weight Polyaminoboranes, Boron–Nitrogen Analogues of Polyolefins

Anne Staubitz、Alejandro Presa Soto、Ian Manners2008-07-10Angewandte Chemie

B und N als Rückgrat: Lösliche lineare Polyaminoboran-Homopolymere und -Copolymere mit hohen Molekulargewichten wurden durch die iridiumkatalysierte Dehydrokupplung der leicht erhältlichen Amin-Boran-Addukte RNH2⋅BH3 synthetisiert (R=H, Me, nBu).

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionMuon and positron interactions and applications

Biomaterials and Biofunctionality in Layered Macromolecular Assemblies

Katsuhiko Ariga、Jonathan P. Hill、Qingmin Ji2008-07-10Macromolecular Bioscience

Recent research in the field of LbL assembly is summarized and categorized as fabrication, sensing, drug release/delivery, and cell technology. Special emphasis is given to topics such as cell-membrane-mimic assembly, fabrication of free-standing biomolecular structures including protein microtubes, detection of DNA a…

Advanced biosensing and bioanalysis techniquesPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

In Situ ATRP‐Mediated Hierarchical Formation of Giant Amphiphile Bionanoreactors

Benjamin Le Droumaguet、Kelly Velonia2008-07-10Angewandte Chemie International Edition

Functional giants: Amphiphilic bioconjugates can be synthesized in situ by grafting polystyrene from a protein (see scheme). The resulting giant amphiphiles display low polydispersities and the characteristic aggregation properties of amphiphilic biomacromolecules. A second, catalytically active guest protein can also…

Supramolecular Self-Assembly in MaterialsClick Chemistry and ApplicationsDendrimers and Hyperbranched Polymers

Mechanistic Consequences of Composition in Acid Catalysis by Polyoxometalate Keggin Clusters

Josef Macht、Michael J. Janik、Matthew Neurock 等 4 位作者2008-07-10Journal of the American Chemical Society

The kinetics and mechanism of ether and alkanol cleavage reactions on Brønsted acid catalysts based on polyoxometalate (POM) clusters are described in terms of the identity and dynamics of elementary steps and the stability of the transition states involved. Measured rates and theoretical calculations show that the en…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Synthesis and Characterization of Short Saccaharum Cilliare Fibre Reinforced Polymer Composites

A. S. Singha、Vijay Kumar Thakur2008-07-10Journal of Chemistry

This paper deals with the synthesis of short Saccaharum Cilliare fibre (SC) reinforced Urea‐Formaldehyde (UF) matrix based polymer composites. Present work reveals that mechanical properties such as: tensile strength, compressive strength, flexural strength and wear resistance of the UF matrix increase up to 30% fibre…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research Studies

The Medium‐Chain Dehydrogenase/Reductase Engineering Database: A systematic analysis of a diverse protein family to understand sequence–structure–function relationship

Michael Knoll、Jürgen Pleiss2008-07-10Protein Science

The Medium-Chain Dehydrogenase/Reductase Engineering Database (MDRED, http://www.mdred.uni-stuttgart.de) has been established to serve as an analysis tool for a systematic investigation of sequence-structure-function relationships. It includes sequence and structure information of 2684 and 42 medium-chain dehydrogenas…

Protein Structure and DynamicsEnzyme Structure and FunctionBiochemical and Molecular Research

Radiological Risk Assessment and Environmental Analysis

作者信息未提供2008-07-10Oxford University Press eBooks

This book is an update and major revision to Radiological Assessment: A Textbook on Environmental Dose Analysis published by the U.S. Nuclear Regulatory Commission in 1983. It focuses on risk to the public because decision makers typically use that endpoint to allocate resources and resolve issues. Chapters in the boo…

Radioactive contamination and transferGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Study on the long‐term thermal‐oxidative aging behavior of polyamide 6

Ying Shu、Lin Ye、Tao Yang2008-07-10Journal of Applied Polymer Science

Abstract The long‐term thermal‐oxidative aging behavior of polyamide 6 (PA6) was studied by comparison with the stabilized sample in this work. The variation of mechanical properties of the pure and the stabilized samples of PA6 with aging time at 110°C, 130°C, and 150°C were investigated, respectively. The aging mech…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties