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Glass-Transition Cooperativity Onset in a Series of Random Copolymers Poly(n-butyl methacrylate-stat-styrene)

S. Kahle、Jarosław Korus、E. Hempel 等 7 位作者1997-11-01Macromolecules

Dielectric spectroscopy, heat capacity spectroscopy (HCS), and differential scanning calorimetry (DSC) investigations in the αβ relaxation splitting region of a series of random copolymers of n -butyl methacrylate with styrene are reported. A separate onset of the α relaxation is dielectrically observed, about one fre…

Material Dynamics and PropertiesThermodynamic properties of mixturesPhotochemistry and Electron Transfer Studies

Theory for the reorientational dynamics in glass-forming liquids

Thomas Franosch、Matthias Fuchs、W. Götze 等 5 位作者1997-11-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

The mode-coupling theory for ideal liquid-glass transitions is extended so that the structural relaxation for the reorientational degrees of freedom of a linear molecule, which is immersed in a system of spherical particles, can be described. Closed equations of motion for the correlation functions formed with tensor…

Material Dynamics and PropertiesPlant and animal studiesGlass properties and applications

Cure Characterization in Bis(maleimide)/Diallylbisphenol A Resin by Fluorescence, FT-IR, and UV-Reflection Spectroscopy

John C. Phelan、Chong Sook Paik Sung1997-11-01Macromolecules

Curing bis(maleimide)/diallylbisphenol A (BMI/DABPA) results in the formation of a high-temperature thermoset resin. FT-IR, fluorescence, and UV-reflectance spectroscopy were used to investigate the cure behavior of this material under three different cure schedules. Fluorescence signals were quenched before curing du…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersPhotopolymerization techniques and applications

Three Dimensionally Diluted Magnetic Semiconductor Clusters Cd1-yMnyS with a Range of Sizes and Compositions: Dependence of Spectroscopic Properties on the Synthesis Mode

Laurent Lévy、Nicolas Feltin、D. Ingert 等 4 位作者1997-11-01The Journal of Physical Chemistry B

Absorption and photoluminescence spectroscopic measurements are presented for particles with sizes from 2 to 4 nm, composition from y = 0 to 0.3,where y is given by Cd 1 - y Mn y S, and different preparation modes. No monotonous variation of bandgap energy with increasing composition is observed. The depth of the mini…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsElectronic and Structural Properties of Oxides

Diamond surface-channel FET structure with 200 V breakdown voltage

P. Gluche、A. Aleksov、Andrei Vescan 等 5 位作者1997-11-01IEEE Electron Device Letters

An enhancement mode diamond FET using a hydrogen-terminated surface as hole conductive channel has been fabricated with 200 V gate to drain breakdown voltage. At the 8.5-μm gate length the maximum drain current was 22 mA/mm. 90 mA/mm maximum drain current was obtained at a gate length of 3.0 μm. Scaling to below 1 μm…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchAdvancements in Semiconductor Devices and Circuit Design

Food materials adhesion: A review

Marie‐Caroline Michalski、Stéphane Desobry、J. Hardy1997-11-01Critical Reviews in Food Science and Nutrition

This article reviews the various theories of adhesion mechanism and, more specifically, studies concerning foodstuffs adhesion to industrial equipment and packaging surfaces. Adhesion is governed by mechanical interlocking, wetting, electrostatic and chemical forces, and diffusion. Direct conclusions about the validit…

Surface Modification and SuperhydrophobicityAdhesion, Friction, and Surface InteractionsMaterial Properties and Processing

Characterization of Sol and Gel in Hevea Natural Rubber

Jitladda Tangpakdee、Yasukuki Tanaka1997-11-01Rubber Chemistry and Technology

Abstract The gel content of rubber from high-ammonia latex (HA-latex) decreased significantly after deproteinization with proteolytic enzyme. The addition of 1–2% ethanol in toluene solution reduced the gel content of rubbers from HA-latex, deproteinized HA-latex (HA-DP) and pale crepe. Transesterification of the rubb…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionPolysaccharides Composition and Applications

Modeling of Nickel/Metal Hydride Batteries

Blaine Paxton、John Newman1997-11-01Journal of The Electrochemical Society

A mathematical model of the discharge behavior of the nickel oxide/KOH/ battery system is presented. The model shows great sensitivity to the kinetic parameters of the nickel oxide active material. The thickness and porosity of the battery system's electrodes are optimized in terms of the specific energy and power of…

Catalytic Processes in Materials ScienceAdvanced Battery Technologies ResearchMolten salt chemistry and electrochemical processes

Morphological observations of Aulacoseira using scanning electron microscopy

Peter A. Siver、Hedy Kling1997-11-01Canadian Journal of Botany

Despite the fact that the genus Aulacoseira Thwaites is a common component of phytoplankton communities in many North American water bodies, there are relatively few taxonomic based surveys utilizing the scanning electron microscope (SEM). In addition, based on the current literature, some species are difficult to ide…

Paleontology and Stratigraphy of FossilsDiatoms and Algae ResearchAquatic Invertebrate Ecology and Behavior

Model Catalysts Fabricated Using Electron Beam Lithography and Pulsed Laser Deposition

Aaron S. Eppler、Günther Rupprechter、L. Guczi 等 4 位作者1997-11-01The Journal of Physical Chemistry B

Supported metal nanoparticles have been fabricated using electron beam lithography (EBL) and pulsed laser deposition (PLD). EBL produced ordered two-dimensional arrays with particle diameters of 40 ± 0.5 nm, uniform interparticle distances (230 ± 2 nm), and uniform height (20 ± 0.5 nm). Due to the narrow size distribu…

Catalytic Processes in Materials ScienceElectron and X-Ray Spectroscopy Techniquesnanoparticles nucleation surface interactions

Stacking faults in magnesium

N. Chetty、M. Weinert1997-11-01Physical review. B, Condensed matter

The energetics of various low-energy intrinsic, extrinsic, and twinlike stacking fault configurations in hexagonal-close-packed magnesium are determined from first-principles calculations. To zeroth-order, the ordering of the energies can be understood in terms of the number of fcc-like planes in the sequence of close…

Magnesium Alloys: Properties and ApplicationsBoron and Carbon Nanomaterials ResearchSuperconductivity in MgB2 and Alloys

Effects of Dispersion and Aggregation of Silica in the Reinforcement of Poly(methyl acrylate) Elastomers

Zhengcai Pu、James E. Mark、Jagdish M. Jethmalani 等 4 位作者1997-11-01Chemistry of Materials

Composites were prepared from methyl acrylate monomer and silica particles to which 3-(trimethoxysilyl)propyl methacrylate groups had been grafted. The silica particles were bonded onto poly(methyl acrylate) through participation of their methacrylate groups in the polymerization of the methyl acrylate to form an elas…

Advanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and PropertiesSilicone and Siloxane Chemistry

Introduction to Organic Laboratory Techniques: A Contemporary Approach

Donald L. Pavia、Gary M. Lampman、George S. Kriz1997-11-01Medical Entomology and Zoology

Introduction to organic laboratory techniques: a contemporary approach , Introduction to organic laboratory techniques: a contemporary approach , مرکز فناوری اطلاعات و اطلاع رسانی کشاورزی

Clay minerals and soil interactionsEngineering and Material Science ResearchChemical and Environmental Engineering Research

Physicochemical Foundations for Characterization of Adsorbents by Using High-Resolution Comparative Plots

Mietek Jaroniec、Katsumi Kaneko1997-11-01Langmuir

Theoretical foundations for the comparison of adsorption isotherms at the range of low surface coverages are presented in order to facilitate the use of this high-resolution comparative analysis for characterization of porous adsorbents. The well-known models of adsorption on heterogeneous and microporous solids were…

Adsorption and biosorption for pollutant removalPhase Equilibria and ThermodynamicsMesoporous Materials and Catalysis

International research and development trends and problems of HVDC cables with polymeric insulation

M.S. Khalil1997-11-01IEEE Electrical Insulation Magazine

This paper addresses the worldwide research and development of HVDC cables with polymeric insulation. The unique features of the dc insulation characteristics of polyethylene are presented and discussed. The problems of using polymeric insulation in HVDC applications are presented and analyzed.

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaHigh-Voltage Power Transmission Systems

Roles of phonon amplitude and low-energy optical phonons on superionic conduction

Kunio Wakamura1997-11-01Physical review. B, Condensed matter

From a simple equation of motion for a linear chain, the phonon amplitudes for mobile and cage ions are represented in terms of their ionic radius and atomic mass. Estimated values of the amplitude in superionic conductors are larger for the mobile ions than the cage ions. Based on this result, many binary and ternary…

High-pressure geophysics and materialsGlass properties and applicationsSolid-state spectroscopy and crystallography

Nonlinear distortion of short pulses radiated by plane and focused circular pistons

Michalakis A. Averkiou、Mark F. Hamilton1997-11-01The Journal of the Acoustical Society of America

Detailed measurements of finite-amplitude pulses radiated by plane and focused circular pistons in water are presented. Comparisons of time waveforms and frequency spectra, both on and off axis, are made with numerical calculations based on the nonlinear parabolic wave equation. Emphasis is on nonlinear distortion of…

Ultrasonics and Acoustic Wave PropagationCavitation Phenomena in PumpsUltrasound and Cavitation Phenomena

Enhanced Photoluminescence and Characterization of Mn-Doped ZnS Nanocrystallites Synthesized in Microemulsion

Li‐Hua Gan、Bin Liu、C. H. Chew 等 7 位作者1997-11-01Langmuir

ZnS:Mn luminescent nanomaterials were first prepared in an inverse microemulsion at room temperature as well as under a hydrothermal condition. Mn-doped ZnS nanoparticles obtained are distributed from 3 to 18 nm in diameter as determined by transmission electron microscopy. The crystalline nature of the materials is c…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Polymer Interdiffusion near an Attractive Solid Substrate

Eric K. Lin、Wen‐Li Wu、Sushil K. Satija1997-11-01Macromolecules

Neutron reflectometry is used to study interdiffusion in bilayers of hydrogenated and deuterated poly(methyl methacrylate) (PMMA) on silicon substrates where the polymer−substrate interaction energy is strongly attractive. The effect of the polymer−substrate interaction energy on the interdiffusion rate as a function…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies