Materials Literature
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In this paper, we have investigated the temperature dependence of dielectric properties (relative dielectric permeabilities and dielectric tangents of losses) for woven fabrics of hemp, jute, flax, cotton, polyester (PES), cotton-PES mixture, and wool. The measurements have been carried out at a temperature range from…
A short review of the modern state of lithium use in experimental facilities and fusion devices is presented. This paper is intended to be used by the engineers and researchers involved in activities on thermonuclear fusion.
The reaction of ReCl(5) with 3 equiv of a benzene-1,2-dithiolate derivative in CH(3)CN produced, after the addition of [C(8)H(16)N]Br ([C(8)H(16)N](+) is 5-azonia-spiro[4,4]nonane), brownish-green crystals of [C(8)H(16)N][Re(tms)(3)] (1c) and [C(8)H(16)N][Re(Cl(2)-bdt)(3)] (2c), where (tms)(2-) represents 3,6-bis(trim…
The magnetic properties and magnetocaloric effects of the Gd6Co2Si3 alloy are investigated. Gd6Co2Si3 undergoes a reversible second-order magnetic transition with a Curie temperature at room temperature (TC=295 K). A broad distribution of the magnetic entropy change ΔSm peak is observed, and the full width at half max…
The optical conductivity of graphene is studied in detail. It is shown how crossover from nonlinear to linear behaviour of the current density occurs when the frequency of the external electric field is increased. We also study electron-hole pair creation in bilayer graphene and show that its rate in a static electric…
We present an investigation of different thin-film evaporated ferromagnetic materials for their suitability as electrodes in individual single-wall and multi-wall carbon nanotube-based spin devices. Various electrode shapes made from permalloy (Ni81Fe19), the diluted ferromagnet PdFe, and PdFe/Fe bilayers are studied…
Interaction of NH(3)BH(3) and Li(2)NH (or Li(3)N) in THF leads to the formation of NH(3) and LiNH(2)BH(3), which further react with each other and produce ca. 10 wt.% hydrogen at 45 degrees C.
The interfacial chemistry of the impregnation step involved in the synthesis of cobalt catalysts supported on titania was investigated with regard to the mode of interfacial deposition of the aqua complex [Co(H(2)O)(6)](2+) on the "titania/electrolyte solution" interface, the structure of the inner-sphere complexes fo…
Most experiments on neutron or heavy-ion cascade-produced irradiation of pure metals and metallic alloys demonstrate unlimited void growth as well as development of the dislocation structure. In contrast, the theory of radiation damage predicts saturation of void size at sufficiently high irradiation doses and, accord…
Stable fluorescence: Ultra small and stable nano-zinc oxides are formed from imidazolium ionic liquid crystal precursors. This new luminescent system achieves stable blue and green fluorescence at room temperature by using different alkyl precursors (see figure).
Quadratic response functions are derived and implemented for a vibrational configuration interaction state. Combined electronic and vibrational quadratic response functions are derived using Born-Oppenheimer vibronic product wave functions. Computational tractable expressions are derived for determining the total quad…
For some porphyrinoids, such as orangarin and amethyrin, the main route of macrocyclic pi-circulation is different from the main macrocyclic conjugation pathway predicted by porphyrin chemists. Our analytical theory of ring-current diamagnetism allows us to predict the main macrocyclic conjugation pathway from the rin…
Experimental conditions allowing consequent selection of a dominating photoluminescence mechanism in 6H-SiC nanocrystals at room temperature are reported. Electrostatic screening of surface states involved in radiative transitions can be efficiently achieved by polar ethanol molecules. This leads to a preponderant rad…
Abstract Poly(3‐alkylthiophene)s represent a family of conjugated polymers that are soluble and processable, but still retaining the good electrical conductivity of the insoluble parent polymer thiophene ring backbone. Poly(3‐hexylthiophene) (P3HT) is reported to be a best candidate in the family for solar cell applic…
In this paper, two new series of main-chain and side-chain second-order nonlinear optical (NLO) polyurethanes have been successfully prepared, in which isolation groups with different sizes were introduced to adjust the NLO property of the resultant polymers, according to the concept of "suitable isolation groups". Th…
We demonstrate that the sequence of reactants plays a key factor in the final size of Au nanocrystals. The growth mechanism markedly differs with seed size and/or internal crystallinity. Conversely to what could be expected when the multiple-twinned particle (MTP) seeds are rather large (3.5 nm) they control the nanoc…
This paper offers a theoretical explanation of the coupling effect phenomenon between mechanical loading and chemical reactions based on linear nonequilibrium thermodynamics and also discusses the classical method of obtaining restrictions on the phenomenological coefficients. The question whether static or dynamic lo…
Transparent SrBi2B2O7 glasses were prepared via melt-quenching technique and characterized using differential scanning calorimetry and x-ray powder diffraction. The ac conductivities of the glasses were studied as a function of frequency (100 Hz–10 MHz) at different temperatures. The frequency dependence of conductivi…
Surface-initiated atom transfer radical polymerization (SI-ATRP) can be used to produce conformal coatings of controlled thickness on virtually any surface, providing to it specific physico-chemical and biological properties. Here we have tackled the problem of modulating cell adhesion on typical culture substrates; t…
Abstract It has been found that composites of chitosan (CS) and Ag nanoparticles can exhibit excellent antibacterial activities. However, the weak mechanical performances of these composite materials limit their wide application. Grafting of vinyl monomers onto CS is one of the most effective methods to improve the pe…