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Effects of Si source and high gravity on combustion synthesis of Ti 3 SiC 2 in air

G H Liu、J T Li2012-03-08Advances in Applied Ceramics Structural Functional and Bioceramics

Combustion synthesis of Ti3SiC2 was carried out in air with Si3N4, SiC, and Si as Si sources respectively, and the effect of Si source on the phase composition of the products was investigated. With Si3N4 as Si source, the major product was TiCxN1−x and no Ti3SiC2 was synthesised. When SiC and Si were used, Ti3SiC2 wa…

2D Materials and ApplicationsAluminum Alloys Composites PropertiesMXene and MAX Phase Materials

Mechano-Chemical Preparation and Application of Mulberry-Like CaCo3/SiO2Composite Particles in Superhydrophobic Films

Xiufang Wen、Ying Liu、Zijie Xu 等 8 位作者2012-03-08Soft Materials

This study focuses on preparation of mulberry-like CaCO3/SiO2 composite particles with a mechanochemical method and their application in superhydrophobic films. Silicon dioxide nanoparticles were adhered to calcium carbonate microparticles to form mulberry-like composite particles through vigorous stirring, which prev…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsFluid Dynamics and Thin Films

Thermal degradation of BaAl2Si2O8:Eu2+ phosphor excited by near ultraviolet light

Mingxing Ma、Dachuan Zhu、Cong Zhao 等 7 位作者2012-03-08Chinese Science Bulletin

Eu 2+ doped BaAl 2 Si 2 O 8 phosphor was synthesized by one-step calcination of precursors that were prepared by chemical co-precipitation. The thermal degradation properties of BaAl 2 Si 2 O 8 :Eu 2+ were investigated by photoluminescence, lifetime and chromaticity coordinate measurements. BaAl 2 Si 2 O 8 :Eu 2+ is e…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsRadiation Detection and Scintillator Technologies

MULTIPHASE EQUILIBRIUM, PHASE STABILITY AND PHASE TRANSFORMATION IN NANOCRYSTALLINE ALLOY SYSTEMS

Wenwu Xu、Xiaoyan Song、Z. X. Zhang2012-03-08NANO

A nanoscale thermodynamic approach is developed to quantify the multiphase equilibrium in nanocrystalline alloy systems. The nanoscale multiphase equilibrium calculations indicate that the activities and mole numbers of phases in alloy systems change diversely as a function of the nanograin size at constant temperatur…

Microstructure and mechanical propertiesIntermetallics and Advanced Alloy PropertiesMetallurgical and Alloy Processes

Ytterbia (2·25 mol.-%) stabilised zirconia (Yb-TZP) manufactured from coated nanopowder

Frank Kern、Rainer Gadow2012-03-08Advances in Applied Ceramics Structural Functional and Bioceramics

Rare earth stabilised tetragonal zirconia polycrystals (TZPs) with stabilisers other than yttria and ceria are scarcely examined as structural ceramics. Unstabilised pyrogenic zirconia nanopowder was coated with 2·25 mol.-% of ytterbium oxide via the nitrate route. Yb-TZP ceramics were consolidated by hot pressing in…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

Nanocomposites of ZnS and poly-(dimethyl)-block-(phenyl)siloxane as a new high-refractive-index polymer media

N. V. Sergienko、Dmitri Godovsky、B. G. Zavin 等 5 位作者2012-03-08Nanoscale Research Letters

In the present paper, we describe a new and original method to obtain transparent, siloxane-based composites, with high refractive index (up to 1.68). The method is based on the decomposition of Zn-siloxane, mixed with a poly-(dimethyl)-block-(phenyl)siloxane matrix in different ratios. It was found that after treatme…

TiO2 Photocatalysis and Solar CellsSilicon Nanostructures and PhotoluminescenceSynthesis and properties of polymers

Electrodeposition of copper on aligned multi-walled carbon nanotubes

M. Schneider、Mathias Weiser、Susanne Dörfler 等 6 位作者2012-03-08Surface Engineering

In this work, the electrochemical deposition of copper on aligned multi-walled carbon nanotubes (MWCNTs) from an aqueous electrolyte is described. The addition of sodium dodecyl sulphate has been applied to enhance wettability of the hydrophobic MWCNT surface. The transfer of the MWCNT–copper composite film from nicke…

Carbon Nanotubes in CompositesSupercapacitor Materials and FabricationConducting polymers and applications

Control of in-plane uniaxial anisotropy of Fe72Si14B14 magnetostrictive thin film using a thermal expansion coefficient

Jaewon Shin、Sung Hoon Kim、Yasuaki Suwa 等 5 位作者2012-03-08Journal of Applied Physics

This paper introduces an in-plane uniaxial anisotropy control method of Fe72Si14B14 magnetostrictive thin-film for high sensitivity of MI sensor. The anisotropy can be controlled by inverse-magnetostriction and inducing a bias stress using the difference of thermal expansion coefficient in bimetal structure. We can co…

Magnetic properties of thin filmsMetallic Glasses and Amorphous AlloysMagnetic Properties and Applications

Phonon Properties and Low Thermal Conductivity of Phase Change Material with Superlattice-Like Structure

Pengyu Long、Hao Tong、Xiangshui Miao2012-03-08Applied Physics Express

Based on the Parlinsk–Li–Kawasoe method and density function theory, the phonon properties of some phase change memory materials are calculated. Thermal conductivities are acquired from our calculation, and they are in reasonable agreement with our experimental measurements. Phonon dispersion curve, mismatch between p…

Transition Metal Oxide NanomaterialsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

SUPERCRITICAL SOLVOTHERMAL SYNTHESIS AND NEAR-INFRARED ABSORBING PROPERTIES OF CsxWO3

Chongshen Guo、Shu Yin、Yunfang Huang 等 6 位作者2012-03-08Functional Materials Letters

Cs x WO 3 nanoparticles in the range of 20–50 nm have been successfully synthesized by the supercritical solvothermal approach, where after dissolving WCl 6 and CsOH in a mixed solution of water, ethanol and oleic acid, the solution was heated at 300°C. The products were characterized by X-ray diffraction, TEM, HR-TEM…

Luminescence Properties of Advanced MaterialsTransition Metal Oxide NanomaterialsGa2O3 and related materials

Influence of magnesia doping on structure and electrical conductivity of pyrochlore type GdSmZr 2 O 7

Z-G Liu、J-H Ouyang、K-N Sun 等 4 位作者2012-03-08Advances in Applied Ceramics Structural Functional and Bioceramics

Polycrystalline ceramic samples of magnesia doped GdSm1–xMgxZr2O7–x/2 have been prepared by conventional solid state reaction method using high purity oxides. The influence of magnesia dopant content on densification, microstructure and electrical properties of GdSm1–xMgxZr2O7–x/2 ceramics are investigated. Magnesia d…

Advancements in Solid Oxide Fuel CellsNuclear Materials and PropertiesNuclear materials and radiation effects

A Series of [Mn6] Complexes with Terminal Functional Groups

Małgorzata Hołyńska、Stefanie Dehnen2012-03-08Zeitschrift für anorganische und allgemeine Chemie

Abstract A series of [Mn 6 O 2 ( R 1 OH) 4 (sao) 6 ( R 2 COO) 2 ] complexes with terminal functional groups ( 1 : R 1 = CH 3 , R 2 = HO‐C 6 H 4 , 2 : R 1 = C 2 H 5 , R 2 = H 2 N‐C 6 H 4 , 3 : R 1 = CH 3 , R 2 = Cl‐C 6 H 4 , 4 : R 1 = CH 3 , R 2 = CH 3 S‐C 6 H 4 , 5 : R 1 = CH 3 , R 2 = I‐C 6 H 4 , 6 : R 1 = CH 3 , R 2…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Dynamics of confined water reconstructed from inelastic x-ray scattering measurements of bulk response functions

Robert H. Coridan、Nathan W. Schmidt、Ghee Hwee Lai 等 5 位作者2012-03-08Physical Review E

Nanoconfined water and surface-structured water impacts a broad range of fields. For water confined between hydrophilic surfaces, measurements and simulations have shown conflicting results ranging from "liquidlike" to "solidlike" behavior, from bulklike water viscosity to viscosity orders of magnitude higher. Here, w…

High-pressure geophysics and materialsMaterial Dynamics and PropertiesSpectroscopy and Quantum Chemical Studies

Current carrying friction and wear characteristics of Ti 3 AlC 2 by novel method of infiltration sintering

Qi Xiao、Zhenlin Lv2012-03-08Advances in Applied Ceramics Structural Functional and Bioceramics

High purity Ti3AlC2 samples were prepared by an infiltration sintering method. The current carrying friction and wear characteristics of high pure bulk Ti3AlC2 dry sliding against a GCr15 bearing steel disc were experimentally investigated on a pin-on-disk type tester at several sliding speeds from 20 to 60 m s−1, dif…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesMXene and MAX Phase Materials

Iron doped titania thin films prepared by spin coating

Auppatham Nakaruk、C.Y. Lin、Pramod Koshy 等 4 位作者2012-03-08Advances in Applied Ceramics Structural Functional and Bioceramics

Thin films of titania (TiO2) doped with 1–5 wt-%Fe were spin coated on glass slides and then annealed at 500°C for 2 h. Results revealed that all of the films were ∼500 nm in thickness and consisted of anatase. Increasing the dopant levels revealed the following trends: the major (101) anatase peak shifted to larger l…

TiO2 Photocatalysis and Solar CellsZnO doping and propertiesSemiconductor materials and devices

Structure–Activity Relationship Study of Collagen‐Derived Anti‐Angiogenic Biomimetic Peptides

Elena Roşca、Jacob E. Koskimaki、Niranjan B. Pandey 等 5 位作者2012-03-08Chemical Biology & Drug Design

Structure-activity relationship (SAR) studies are essential in the generation of peptides with enhanced activity and efficacy as therapeutic agents. In this study, we report a Structure-activity relationship study for a family of mimetic peptides derived from type IV collagen with potent anti-angiogenic properties. Th…

Protease and Inhibitor MechanismsChemical Synthesis and AnalysisSilk-based biomaterials and applications

Synthesis of Emulsion-Templated Acrylic-Based Porous Polymers: From Brittle to Elastomeric

Yeliz Tunç、Nesrin Hasırcı、Kezban Ulubayram2012-03-08Soft Materials

High internal phase emulsion polymers (PolyHIPEs) are novel materials that have high porosity and interconnected open-cell structure and are used in various applications such as supports for catalytic systems, media for separation of similar molecules, and scaffolds for tissue engineering. In this study, 90% porous ac…

Hydrogels: synthesis, properties, applicationsAdvanced Polymer Synthesis and CharacterizationPickering emulsions and particle stabilization

MgFeGe as an isoelectronic and isostructural analog of the superconductor LiFeAs

Xiaofeng Liu、Satoru Matsuishi、Satoru Fujitsu 等 4 位作者2012-03-08Physical Review B

MgFeGe with a CeFeSi-type structure was synthesized by high-pressure method, and its electrical transport, magnetic properties, and electronic structure were investigated. It is found that MgFeGe has the smallest $c$/$a$ (1.65) ratio and the shortest in-plane Fe-Fe distance (2.75 \AA{}) among CeFeSi-type and ThCr${}_{…

Rare-earth and actinide compoundsIron-based superconductors researchSuperconductivity in MgB2 and Alloys

SYNTHESIS, STRUCTURE, AND LUMINESCENCE PROPERTIES OF ZnSnO3 NANOWIRES

Soyeon An、Changhyun Jin、Hyun‐Su Kim 等 6 位作者2012-03-08NANO

ZnSnO 3 nanowires were synthesized on Si substrates by thermal evaporation of a mixture of ZnO, SnO 2 and graphite powders. The nanowires were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and photoluminescence spectroscopy. The ZnSnO 3 nanowires varied from 10 to…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Influence of incremental rate of anodising current on roughness and electrochemical corrosion of oxide film on titanium alloy Ti–10V–2Fe–3Al

J H Liu、Gaolin Wu、Mei Yu 等 6 位作者2012-03-08Surface Engineering

In this study, the influence of incremental rate of anodising current V IR on the crystal structure, surface roughness and corrosion resistance of anodic oxide films on Ti–10V–2Fe–3Al was studied using Raman spectroscopy, atomic force microscopy (AFM), electrochemical impedance spectroscopy (EIS) and potentiodynamic p…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability