Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Vanadium oxide was deposited on mesoporous titania by the molecular designed dispersion method to investigate the potential properties of these catalysts. Mesoporous titania was synthesized following the evaporation-induced self-assembly (EISA) method with a subsequent treatment with ammonia to increase the thermal st…
A development is presented that allows the simulation of reciprocal-space maps (RSMs) of epitaxic thin films exhibiting fluctuations in the size and shape of the crystalline domains over which diffraction is coherent (crystallites). Three different crystallite shapes are studied, namely parallelepipeds, trigonal prism…
It has been shown by several groups that the mechanical and electrical behavior of composites changes quite substantially, and often beneficially, when the filler particle size is less than 100 nm in diameter. There is also good reason to believe that the interface between the embedded particulates and the polymer mat…
For brittle cleavage under Load Mode I, a model for single crystals is presented which derives the critical stress in terms of the cleavage energy and the uniaxial elastic modulus. The model parameters are determined by fitting to results of ab initio density functional calculations. The crucial concept for establishi…
CO adsorption on NO(2)-predosed Au[111] reveals an unexpected attractive coadsorbate interaction, associated with an unprecedented blueshift of the CO stretch frequency, a sizeable attenuation of the infrared NO(2) symmetric stretch band, and a (sq.rt(7) x sq.rt(7))R19 degrees structure characterized by scanning tunne…
X-ray diffraction patterns of NiPc in powder form show that it has a β-form with monoclinic structure. The thermal evaporation of NiPc led to α-polycrystalline films orientated preferentially to the (001) plane with an amorphous background. After annealing at 573 K for 2 h, a mixture of α- and β-phases was formed, whi…
Abstract Summary: Polyaniline composite film with nano‐structure was prepared through a chemical oxidation method by adding carbon nanotubes (CNTs) as nano‐fiber seeds. Spin‐coating or casting method was employed on the interdigital electrodes of carbon and the composite film was formed with an in‐situ polymerization…
Specific heat of stoichiometric ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Sr}}_{x}{\mathrm{MnO}}_{3}$ samples with large ($x=1.0$, 0.9, 0.7, 0.55, 0.45) and low $(x=0.0)$ strontium contents was measured from 3 to 393 K, on heating and on cooling, in zero magnetic field and in the field of 7 T. The temperatures and the…
We have investigated the structural and dynamic properties of liquid nickel by means of large-scale molecular-dynamics simulations, using an effective-pair potential derived from the second-order pseudopotential perturbation theory. The model of interactions is assessed on the single-atom as well as collective dynamic…
We present a simple model to describe the induction of magnetic behavior on gold clusters upon chemisorption of one organic molecule with different chemical linkers. In particular, we address the problem of stability of the lowest lying singlet and show that for some linkers there exists a spin symmetry-breaking that…
Resistance to partial discharge (PD) was investigated for four kinds of epoxy nanocomposites, an epoxy resin without fillers, and an epoxy resin with SiO/sub 2/ micro-filler. The nano-fillers used were TiO/sub 2/, two different particle sizes of SiO/sub 2/, and layered silicate. Filler content was 5 wt % in all nano-…
We describe photoinduced formation of blue fluorescent aggregates of azobenzene derivatives, whose isolated molecules in solution are not fluorescent at ambient temperature, with different alkyl chain lengths. In contrast to nonfluorescent C0 (4-hydroxyazobenzene), C10 and C24 with long alkyl chains started being blue…
Reversible interparticle self-organization is reported for gold nanoparticles functionalized with an oligo(p-phenylene vinylene) moiety in butanol. The aggregates show a clear melting temperature at 80 degrees C, and atomic force microscopy and transmission electron microscopy indicate a fractal-like organization of t…
This paper examines ferronematic switching in a homeotropic cell in the presence of a magnetic field normal to the cell plane. At low fields we find thresholdless switching of the nematic director, consistent with experimental data. At higher fields, there are three regimes, depending on the strength of the director-f…
Syntheses, electronic structures in the ground state, unique photoexcited states, and spin alignment are reported for novel biradical 1, which was designed as an ideal model compound to investigate photoinduced spin alignment in the excited state. Electron spin resonance (ESR), time-resolved ESR (TRESR), and laser-exc…
The synthesis of novel diblock copolymers consisting of a semifluorinated block of poly(1 H,1 H,2 H,2 H -perfluorooctyl methacrylate) (PFOMA) and a hydrocarbon block of polycaprolactone (PFOMA- b -PCL) was achieved by the combination of enzymatic ring-opening polymerization (eROP) and atom transfer radical polymerizat…
The paper discusses the mechanisms by which inorganic fillers in silicone rubber dielectrics enhance the properties of thermal conductivity, relative permittivity, and electrical conductivity making them useful in outdoor high voltage insulation applications. The addition of alumina tri-hydrate or silica fillers to si…
Fixtured sintering of up to 5 hours at 1223 to 1323 K is successfully used to diminish the dimensional change of NiTi memory alloys produced from mixtures of elemental Ni and Ti powders packed and pressed at room temperature under 400, 500, and 600 MPa pressure. The improvements obtained can help near-net-shape techno…
A nanocomposite material, composed of nano-sized MgO-filler added to a low-density polyethylene (LDPE), was subjected to electrical property investigations under DC voltage application. The volume resistivity of LDPE, under 40-80 kV/mm DC field at 90 /spl deg/C, increases by the power of 10 due to the addition of only…
Abstract Summary: In this work, epoxy resin/CaCO 3 nanocomposites were prepared by in situ and inclusion polymerization. Nanoparticles with a size of 30–40 nm were dispersed efficiently in bisphenol‐A alkaline solution before polymerization and the dispersion could be kept in the resultant composite by a reaction that…