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Photovoltaic Hybrid Films with Polythiophene Growing on Monoclinic WO3 Semiconductor Substrates

Zhouyong Yang、Xiuyuan Ni2012-02-15Langmuir

A new photovoltaic film consisting of monoclinic WO(3) semiconductor and conjugated polythiophene (PT) is prepared via an in situ polymerization which is initiated by photoexcited WO(3). It is observed that PT grows on the WO(3) substrate along with reaction time, leading to uniform and high quality PT-WO(3) composite…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

A model for the effective thermal conductivity of metal-nonmetal particulate composites

José Ordoñez-Miranda、Ronggui Yang、J. J. Alvarado‐Gil2012-02-15Journal of Applied Physics

The effective thermal conductivity of particulate composites with oriented spheroidal metallic particles embedded in a dielectric matrix is analyzed under the framework of the two-temperature model of heat conduction. The obtained analytical results show that the effective thermal conductivity depends strongly on (1)…

Thermal properties of materialsComposite Material MechanicsThermal Radiation and Cooling Technologies

Selective Guest Exchange in Encapsulation Complexes Using Light of Different Wavelenghts

Henry Dube、Julius Rebek2012-02-15Angewandte Chemie

Eine Frage des Lichts: Mit Licht zweier Wellenlängen und Erwärmen kann die Assoziation zweier spezifischer Einschlusskomplexe in Lösung kontrolliert werden. Der Gastmolekülaustausch lässt sich abhängig von der Wellenlänge nacheinander oder parallel durchführen, und es sind drei Kombinationen von Einschlusskomplexen zu…

Radical Photochemical ReactionsPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Functional Polymers Bearing Reactive Azetidinium Groups: Synthesis and Characterization

Subrata Chattopadhyay、Helmut Keul、Martin Möller2012-02-15Macromolecular Chemistry and Physics

Abstract Functional polymers with azetidinium groups in the backbone are synthesized via the reaction of aminotelechelic polymers, containing primary and secondary amino groups, with epichlorohydrin. During the reaction, the secondary amino groups are transformed into azetidinium groups and the primary amino groups ar…

Synthetic Organic Chemistry MethodsSynthesis and properties of polymersSynthesis of β-Lactam Compounds

Surface Diels–Alder Reactions as an Effective Method to Synthesize Functional Carbon Materials

Helena Kaper、Agnès Grandjean、Claudia Weidenthaler 等 5 位作者2012-02-15Chemistry - A European Journal

The post-synthesis chemical modification of various porous carbon materials with unsaturated organic compounds is reported. By this method, amine, alcohol, carboxylate, and sulfonic acid functional groups can be easily incorporated into the materials. Different carbonaceous materials with surface areas ranging from 24…

Mesoporous Materials and CatalysisAnalytical Chemistry and ChromatographyCovalent Organic Framework Applications

Experimental Characterization of Chiral Uniaxial Bianisotropic Composites at Microwave Frequencies

Farhad Bayatpur、Alireza V. Amirkhizi、Sia Nemat‐Nasser2012-02-15IEEE Transactions on Microwave Theory and Techniques

This paper presents an experimental procedure for retrieving the effective constitutive parameters of chiral materials. Unlike past research that primarily deals with isotropic materials, this study considers a lossy uniaxial bianisotropic slab with a nonzero chirality along its axial direction. First, plane-wave scat…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Effects of Tourmaline Particles on Structure and Properties of Polypropylene Filtration Melt-Blown Nonwoven Electrets

Bin Yu、Jian Han、XIANGBING HE 等 5 位作者2012-02-15Journal of Macromolecular Science Part B

BIN YUab, JIAN HANab, XIANGBING HEb, GUOPING XUb & XINGBO DINGb a The Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Zhejiang Sci-Tech University , Ministry of Education , Hangzhou , China b School of Materials and Textiles, Zhejiang Sci-Tech University , Hangzhou , China Polypropylene (PP)…

Polymer crystallization and propertiesConducting polymers and applicationsTextile materials and evaluations

Multisite models to determine the distribution of kink sites adjacent to low-energy edges

Michael A. Lovette、Michael F. Doherty2012-02-15Physical Review E

Kink sites play a critical role in crystal growth. The incorporation of a growth unit into a kink site (1) maintains the free energy of the edge constant and (2) creates another site with the same properties. These properties allow growth through successive incorporation events to proceed in a self-sustaining manner s…

Spectroscopy and Quantum Chemical StudiesCrystallization and Solubility Studiesnanoparticles nucleation surface interactions

Fractography Analysis of Naturally Woven Coconut Sheath Reinforced Polyester Composite: A Novel Reinforcement

J.T. Winowlin Jappes、I. Siva、N. Rajini2012-02-15Polymer-Plastics Technology and Engineering

In this work, naturally woven coconut sheath, a new type of reinforcement was used. Composite Laminates were prepared in a compression molding press. Tensile, flexural and impact tests were conducted as per ASTM standards, and results were compared with the glass fibre composite. Fractured specimens were analyzed with…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced CompositesElectrospun Nanofibers in Biomedical Applications

Tuning the electronic and magnetic properties of carbon-doped ZnO nanosheets: First-principles prediction

Fu‐bao Zheng、Changwen Zhang、Pei‐ji Wang 等 4 位作者2012-02-15Journal of Applied Physics

Using the full-potential linearized augmented plane wave (FLAPW) method, we study the electronic and magnetic properties of C-doped graphene-like ZnO nanosheets (NSs). The results show that in a specimen with isolated C-doping, there is a spontaneous polarization with a magnetic moment 2.0μB/C. In two C-doped systems…

ZnO doping and propertiesMultiferroics and related materialsAdvanced Condensed Matter Physics

ZnO/anthracene based inorganic/organic nanowire heterostructure: Photoresponse and photoluminescence studies

Soumen Dhara、P. K. Giri2012-02-15Journal of Applied Physics

The effects of surface modification of vertically aligned ZnO nanowires (NWs) with anthracene for the improved photocurrent, photoresponse, and UV photoluminescence have been investigated in this work. The formation of ZnO/anthracene based inorganic/organic NWs heterostructure by surface capping with anthracene soluti…

ZnO doping and propertiesPerovskite Materials and ApplicationsGa2O3 and related materials

Effect of various pulp properties on the solubility of cellulose in sodium hydroxide solutions

Martin Kihlman、Fredrik Aldaeus、Fadia Chedid 等 4 位作者2012-02-15Holzforschung

Abstract The dissolution of pulps with varying characteristic properties, for example cellulose chain length or content of hemicellulose, has been investigated in two alkaline solvent systems [sodium hydroxide (NaOH)/urea/thiourea (8:8:6.5 by wt.) and NaOH/zince oxide (ZnO) (9:0.5 by wt.)]. One standard paper pulp, tw…

Advanced Cellulose Research StudiesLignin and Wood ChemistryMaterial Properties and Processing

The role of a silane coupling agent in carbon nanotube/polypropylene composites

Fei Xin、Lin Li2012-02-15Journal of Composite Materials

The carbon nanotube (CNT)/polypropylene(PP) composites have been prepared with the aid of a silane coupling agent (ZFDA, Dow Corning® Z‐6173) and then characterized by electron microscopic, electrical, mechanical, and thermal measurements in order to understand the role of the silane coupling agent in CNT/PP composite…

Carbon Nanotubes in CompositesConducting polymers and applicationsSmart Materials for Construction

Vibration analysis of circular double-layered graphene sheets

Toshiaki Natsuki、Jin-Xing Shi、Qing‐Qing Ni2012-02-15Journal of Applied Physics

This paper presents a study on the natural vibration of circular double-layer graphene sheets (DLGSs) using circular plate theory. The circular DLGSs are assumed to be coupled together through the carbon–carbon van der Waals (vdW) force between their two layers. An analytical solution of coupled governing equations is…

Carbon Nanotubes in CompositesNonlocal and gradient elasticity in micro/nano structuresAdvanced Materials and Mechanics

Formation of fullerene superlattices by interlayer bonding in twisted bilayer graphene

André R. Muniz、Dimitrios Maroudas2012-02-15Journal of Applied Physics

Based on first-principles density functional theory calculations, we report a novel class of carbon nanostructures consisting of superlattice arrangements of caged fullerene configurations of various sizes embedded within planes of twisted bilayer graphene. Formation of these structures is the outcome of interlayer C-…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Energy transfer in CaYAlO4: Ce3+, Pr3+ for sensitization of quantum-cutting with the Pr3+-Yb3+ couple

Antoine Guille、A. Pereira、G Breton 等 5 位作者2012-02-15Journal of Applied Physics

Silicon based solar cells show a poor yield in the UV-blue range of the solar spectrum. The thermalization of the charge carriers is one major loss mechanism, which could be overcome by depositing a quantum-cutting material in front of the solar cell. This phenomenon has recently been demonstrated in materials doped w…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSilicon Nanostructures and Photoluminescence

Stress-strain dependence for soy-protein nanofiber mats

S. Khansari、Suman Sinha‐Ray、Alexander L. Yarin 等 4 位作者2012-02-15Journal of Applied Physics

Soy protein/nylon 6 monolithic and core-shell nanofibers were solution-blown and collected on a rotating drum as fiber mats. Tensile tests of rectangular strips of these mats revealed their stress-strain dependences. These dependences were linear at low strains which correspond to their elastic behavior. Then, a plast…

Natural Fiber Reinforced CompositesElectrospun Nanofibers in Biomedical ApplicationsFiber-reinforced polymer composites

Multi-layered bird beaks: a finite-element approach towards the role of keratin in stress dissipation

Joris Soons、Anthony Herrel、Annelies Genbrugge 等 6 位作者2012-02-15Journal of The Royal Society Interface

Bird beaks are layered structures, which contain a bony core and an outer keratin layer. The elastic moduli of this bone and keratin were obtained in a previous study. However, the mechanical role and interaction of both materials in stress dissipation during seed crushing remain unknown. In this paper, a multi-layere…

Cellular Mechanics and InteractionsSkin and Cellular Biology ResearchSilk-based biomaterials and applications

SiGe superlattice nanocrystal infrared and Raman spectra: A density functional theory study

Mudar Ahmed Abdulsattar2012-02-15Journal of Applied Physics

Infrared and Raman vibrational spectrum are calculated using ab initio density functional theory for SiGe superlattice nanocrystal of approximately 1.6 nm length. After obtaining the optimum positions of atoms via geometrical optimization using density functional theory, coupled perturbed Hartree-Fock equations are so…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Evaluation of Cross-Linked Chitosan as Filler on Mechanical Properties of Chitosan-Based Bio-Composites

Nurhidayatullaili Muhd Julkapli、Hazizan Md Akil、Zulkifli Ahmad2012-02-15Polymer-Plastics Technology and Engineering

The cross-linked chitosan (XCs) was applied as a filler for chitosan (Cs) matrix. The composites film was prepared by solution casting at 0 to 12 wt/v% content of XCs filler and characterized under tensile analysis. The tensile strength (TS) and Young Modulus (YM) increased lineraly with the content of XCs filler (2 t…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications