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Solvent-dependent fluorescence and circular dichroism properties of poly(quinoxaline-2,3-diyl)s bearing pyrene pendants

Yuuya Nagata、Tsuyoshi Nishikawa、Michinori Suginome2012-01-01Chemical Communications

Poly(quinoxaline-2,3-diyl)s bearing pyrene pendants exhibited solvent-dependent changes of the fluorescence color (blue and green) and the screw-sense selectivity (left-handed and racemic) in chloroform and 1,1,1-trichloroethane, respectively.

Molecular Sensors and Ion DetectionConducting polymers and applicationsLuminescence and Fluorescent Materials

Assembly of an undeca-nuclear nickel substituted POM through polycarboxylate ligand

Yunyun Zheng、Ru Wen、Xiang‐Jian Kong 等 6 位作者2012-01-01Dalton Transactions

An undeca-nuclear nickel substituted POM, namely [Ni(H(2)O)(6)][Ni(11)(PW(9)O(34))(2)(IDA)(3)(en)(2)(Hen)(2)(OH)(6)]·(H(2)O)(7)·(H(2)en)(2) (1) (en = 1,2-ethylenediamine, H(2)IDA = iminodiacetic acid), was synthesized through hydrothermal reaction of Na(6)PW(9)O(34), en, H(2)IDA and NiCl(2)·6H(2)O. Single-crystal stru…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Raman Spectra of PbFe0.5Nb0.5O3Multiferroic Single Crystals and Ceramics

N S Druzhinina、Yu. I. Yuzyuk、I. P. Raevski 等 6 位作者2012-01-01Ferroelectrics

Room temperature Raman spectra of both PbFe0.5Nb0.5O3 (PFN) single crystal and ceramics were found to contain 14 bands, namely 64, 130, 200, 265, 427, 488, 560, 703, 785, 861, 971, 1123, 1236, and 1383 cm−1. For the first time distinct anomalies in the temperature dependences of frequency and/or full width at half max…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Effects of Thermal Annealing and Film Thickness on the Structural and Morphological Properties of Titanium Dioxide Films

S. Çörekçí、K. Kızılkaya、T. Asar 等 6 位作者2012-01-01Acta Physica Polonica A

Titanium dioxide (TiO 2 ) thin films having different thicknesses of 220, 260, and 300 nm were deposited onto well-cleaned n-type silicon substrates by reactive DC magnetron sputtering and annealed in the range of 200-1000 C in steps of 200 C. The effects of thermal annealing and thickness variation on the crystalline…

TiO2 Photocatalysis and Solar CellsZnO doping and propertiesGas Sensing Nanomaterials and Sensors

Language Teaching Materials as Mediators For ICC Development: a Challenge for Materials Developers

Carlos Rico Troncoso2012-01-01DOAJ (DOAJ: Directory of Open Access Journals)

Los materiales de lengua y en particular los libros de texto son para los aprendices una fuente de exposición a la lengua y a la cultura. En los contextos multiculturales, estos se convierten en potentes herramientas que posibilitan los encuentros interculturales entre los individuos que poseen diferentes formaciones…

Material Selection and Properties

Unprecedented Phenomena with Tempering of Ti-4Fe-7Al Alloy

Yoshito Takemoto、Masahiro Ochi、Takehide Senuma 等 6 位作者2012-01-01Journal of the Japan Institute of Metals and Materials

Unprecedented phenomena were discovered by tempering the Ti-4Fe-7Al alloy quenched from the β (bcc) field. The alloy became very hard when it was tempered at 450℃ for several minutes, and severely rugged surface was generated. The inverse shape recovery phenomenon was also discovered when a quenched specimen that had…

Microstructure and Mechanical Properties of SteelsIntermetallics and Advanced Alloy PropertiesTitanium Alloys Microstructure and Properties

Hot Corrosion Behavior of Double-ceramic-layer LaTi2Al9O19/YSZ Thermal Barrier Coatings

Xie、Xiaoyun、Guo 等 8 位作者2012-01-01Acta Scientiarum Naturalium Universitatis Sunyatseni

LaTi2Al9O19 (LTA ) 作为新有点热的障碍涂层(TBC ) 展出有希望的潜力材料,由于它的优秀高温度的能力和低热电导率。在这份报纸, LTA/yttria 稳定了氧化锆(YSZ ) TBC 被大气的血浆喷洒生产。热腐蚀行为和涂层的相关失败机制被调查。LTA 的分解不甚至在 1 458 个热腐蚀周期以后发生在 1 373 K,揭示在 Na2SO4 和 NaCl 的熔融的盐的好化学稳定性。然而,熔融的盐渗透到契约上衣,引起在熔融的盐和契约上衣的热腐蚀的热地成年的氧化物(TGO ) 溶解。作为结果, TBC 裂开发生在氧化物层以内。在结论,陶器的材料 LTA 和 YSZ 表明在 Na2SO4 和 NaCl 的熔融的盐的好化…

Advanced ceramic materials synthesisCatalytic Processes in Materials ScienceRecycling and utilization of industrial and municipal waste in materials production

Efficient second harmonic generation in a metamaterial with two resonant modes coupled through two varactor diodes

Toshihiro Nakanishi、Yasuhiro Tamayama、Masao Kitano2012-01-01Institutional Repositories DataBase (IRDB)

We present an effective method to generate second harmonic (SH) waves using nonlinear metamaterial composed of coupled split ring resonators (CSRRs) with varactor (variable capacitance) diodes. The CSRR structure has two resonant modes: a symmetric mode that resonates at the fundamental frequency and an anti-symmetric…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Dynamics of charged gibbsite platelets in the isotropic phase

D. Kleshchanok、M. Heinen、G. Nägele 等 6 位作者2012-01-01Utrecht University Repository (Utrecht University)

We report on depolarized and non-depolarized dynamic light scattering, static light scattering, and steady shear viscosity measurements on interacting charge-stabilized gibbsite platelets suspended in dimethyl sulfoxide (DMSO). The average collective and (long-time) translational self-diffusion coefficients, and the r…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Instantaneous biosynthesis of silver nanoparticles (AgNPs) by selected macro fungi

Stephanie Chan2012-01-01eSpace (Curtin University)

Silver nanoparticles (AgNPs) have been reported to be useful in various medical and life sciences related application. It has received considerable attention in order to develop an efficient methodology for its synthesis. Conventional chemical synthesis is said to be harmful when used in medical related applications.…

Nanoparticles: synthesis and applicationsNanotechnology research and applications

Structure and Photoluminescence Properties of Ca9Al(PO4)7: Ce3+, Mn2+Phosphors

Qian Wang、Zhipeng Ci、Ge Zhu 等 7 位作者2012-01-01ECS Journal of Solid State Science and Technology

A series of single-phased color-tunable phosphors Ca 9 Al(PO 4 ) 7 : xCe 3+ , yMn 2+ (0≤x≤0.03, 0≤y≤0.07) (CAP: xCe 3+ , yMn 2+ ) were synthesized by solid state reaction. The obtained phosphors exhibit a broad excitation band ranging from 250 to 350 nm and two emission bands centered at about 350 and 645 nm upon 315…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsRadiation Detection and Scintillator Technologies

Surface Modifications for Controlled and Optimized Cell Immobilization by Adsorption: Applications in Fibrous Bed Bioreactors Containing Recombinant Cells

Peter M. Kilonzo2012-01-01Journal of Microbial & Biochemical Technology

The effects of surface properties of S. cerevisiae strains 468/pGAC9 and 468 on adhesion to polyethylenimine (PEI) and/glutaraldehyde (GA) pretreated cotton (CT), polyester (PE), polyester + cotton (PECT), nylon (NL), polyurethane foam (PUF), and cellulose re-enforced polyurethane (CPU) fibers were investigated. Proce…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications3D Printing in Biomedical Research

Recent Trend in Next Generation Power Electronics R&D

Hiroshi Yamaguchi2012-01-01IEEJ Transactions on Power and Energy

The energy management technology has been occupying the attention due to the requests for the high-efficiency energy use. Especially, the electric power management is the key issue in order to achieve the high-efficiency energy generation, transmission, distribution, and consumption. Therefore, the progress in power e…

Liquid Crystal Research AdvancementsNatural Compound Pharmacology Studies

Nonacyclic Ladder Silsesquioxanes and Spectral Features of Ladder Polysilsesquioxanes

Masafumi Unno、Tomoe Matsumoto、Hideyuki Matsumoto2012-01-01International Journal of Polymer Science

Laddersiloxanes, that is, ladder silsesquioxanes with defined structures, could be obtained by stepwise synthesis starting from cyclic silanols. These compounds were shown to have high thermal stability. As an extension of the previous work, the first nonacyclic ladder silsesquioxanes were synthesized by the reaction…

Advanced ceramic materials synthesisSynthesis and properties of polymersSilicone and Siloxane Chemistry

Development of a new magnetocaloric material used in a magnetic refrigeration device

F. Guillou、Ulrich Legait、Afef Kedous‐Lebouc 等 4 位作者2012-01-01EPJ Web of Conferences

Testing directly a magnetocaloric material in a magnetic refrigeration (MR) system is the best way to judge of its applicative potentialities. In this spirit, an oxide expected to show promising magnetocaloric properties around room temperature (Pr0.65Sr0.35MnO3) was produced in large scale and shaped in order to buil…

Advanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materialsMagnetic Properties of Alloys

Hydrogen bonded supramolecular polymers in protic solvents: role of multitopicity

Marion Tharcis、Thomas Breiner、Joël Belleney 等 5 位作者2012-01-01Polymer Chemistry

We describe the synthesis of macromolecular amphiphiles of various molar masses containing well-defined hydrophobic groups incorporating urea moieties. All compounds have the same proportion of associative hydrophobic groups and solubilising POE chains. However, a strong influence of both the number of associative gro…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesSupramolecular Self-Assembly in Materials

Electrochemically driven delivery to cells from vesicles embedded in polyelectrolyte multilayers

Norma Graf、Alexander Tanno、Alexander Dochter 等 6 位作者2012-01-01Soft Matter

Calcein was delivered from a functional coating into viable cells on top of it, upon the application of an electrochemical stimulus. The dye was loaded in liposomes stably embedded in a sandwich of polyelectrolyte multilayers. The covering multilayer was optimized with respect to its chemical composition to be resista…

Quantum Dots Synthesis And PropertiesPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

Ordered Mesoporous Carbon/MoO2 Nanocomposites as Stable Supercapacitor Electrodes

Yuanyuan Zhou、C. W. Lee、Sung‐Kun Kim 等 4 位作者2012-01-01ECS Electrochemistry Letters

Novel ordered mesoporous carbon/MoO 2 nanocomposites were prepared using one-step tri-constituent co-assembly method. From various structural and physical analysis, ordered mesoporous structure with homogeneous dispersion of MoO 2 in nanoscale was observed in as-prepared composites containing from 9 to 38 wt% MoO 2 ,…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationCatalysis and Hydrodesulfurization Studies

Morphogenesis of polyoxometalate cluster-based materials to microtubular network architectures

Antoine G. Boulay、Geoffrey J. T. Cooper、Leroy Cronin2012-01-01Chemical Communications

Pressed pellets of polyoxometalate (POM)-based materials are shown to undergo morphogenesis to produce microtubular network architectures without the need for a large single crystal precursor. The compression of the POM material into a pellet lowers the solubility sufficiently to allow tube initiation and growth from…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis