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Vertically oriented few-layer graphene as an electron field-emitter

Sanjay K. Behura、Indrajit Mukhopadhyay、Akira Hirose 等 5 位作者2013-05-30physica status solidi (a)

Field emission from flat graphene sheets is a challenge due to fewer emission sites. Here, we have synthesized free-standing vertically oriented few-layer graphene (FLG) films directly on dielectric substrates by hot-filament chemical vapor deposition (HFCVD) without any catalyst or special substrate treatment. The fa…

Carbon Nanotubes in CompositesGraphene research and applicationsQuantum and electron transport phenomena

Comparison of chemical vapor deposition diamond-, diamond-like carbon- and TiAlN-coated microdrills in graphite machining

Xuelin Lei、Liang Wang、Bin Shen 等 5 位作者2013-05-30Proceedings of the Institution of Mechanical Engineers Part B Journal of Engineering Manufacture

In this study, continuous microcrystalline diamond layer with grain size of 0.8–2 µm, nanocrystalline diamond layer with grain size less than 100 nm, diamond-like carbon layer with no apparent grains and TiAlN layer with small particles on the top surface are successfully deposited on cemented tungsten carbide-cobalt…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchLubricants and Their Additives

Low percolation threshold and high electrical conductivity in melt‐blended polycarbonate/multiwall carbon nanotube nanocomposites in the presence of poly(ε‐caprolactone)

Sandip Maiti、Supratim Suin、Nilesh K. Shrivastava 等 4 位作者2013-05-30Polymer Engineering and Science

This study focuses on the electrical properties of polycarbonate (PC)/poly(ε‐caprolactone) (PCL)‐multiwall carbon nanotube (MWCNT) nanocomposites. MWCNTs were incorporated into thermoplastic PC matrix by simple melt blending using biodegradable PCL based concentrates with MWCNT loadings (3.5 wt%). Because of the lower…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesConducting polymers and applications

High Pressure Compression-Molding of α-Cellulose and Effects of Operating Conditions

Thibaud Pintiaux、David Viet、Virginie Vandenbossche 等 5 位作者2013-05-30Materials

Commercial α-cellulose was compression-molded to produce 1A dog-bone specimens under various operating conditions without any additive. The resulting agromaterials exhibited a smooth, plastic-like surface, and constituted a suitable target as replacement for plastic materials. Tensile and three-points bending tests we…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesMaterial Properties and Processing

Nonisothermal DSC Study of Epoxy Resins Cured with Hydrolyzed Specified Risk Material

Nayef El‐Thaher、Tizazu H. Mekonnen、Paolo Mussone 等 5 位作者2013-05-30Industrial & Engineering Chemistry Research

The effects of salt, molecular weight and viscosity, and mass ratio on the apparent activation energy of the cross-linking reaction of epoxy resins and protein hydrolysate were studied by nonisothermal differential scanning calorimetry. The Kissinger equation, the model-free isoconversional method, and the autocatalyt…

Polymer crystallization and propertiesEpoxy Resin Curing ProcessesThermal and Kinetic Analysis

Epiphytic Diatoms along Environmental Gradients in Western European Shallow Lakes

Saúl Blanco、Cristina Cejudo‐Figueiras、Irene Álvarez‐Blanco 等 12 位作者2013-05-30CLEAN - Soil Air Water

Diatom‐based assays have been successfully associated worldwide with the tropic status of lakes. Several studies have demonstrated a correlation between epiphytic diatoms and nutrient load in shallow lakes and wetlands. We examine the relative importance of environmental factors in explaining the structure of epiphyti…

Aquatic Ecosystems and Phytoplankton DynamicsFreshwater macroinvertebrate diversity and ecologyDiatoms and Algae Research

Hierarchically Self-Assembled Photonic Materials from Liquid Crystalline Random Brush Copolymers

Prashant Deshmukh、Suk‐kyun Ahn、Manesh Gopinadhan 等 5 位作者2013-05-30Macromolecules

Here we report a general methodology to attain novel hierarchical nanostructures using new polymer scaffolds that self-assemble to form cholesteric 1D photonic mesophases existing in conjunction with microphase segregated domains. To achieve this, a series of liquid-crystalline random brush copolymers (LCRBC) consisti…

Liquid Crystal Research AdvancementsAdvanced Polymer Synthesis and CharacterizationSurfactants and Colloidal Systems

Properties of wood plastic composite panels made from waste sanding dusts and nanoclay

Mehrab Madhoushi、Arash Chavooshi、Alireza Ashori 等 5 位作者2013-05-30Journal of Composite Materials

This article presents the application of waste sanding dusts in order to evaluate its suitability as reinforcement for thermoplastics as an alternative to wood fibers. The effects of sanding dust loading and nanoclay content on the physical and mechanical properties were also studied. Overall trend showed that with ad…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesTribology and Wear Analysis

Atomistic scale fracture behaviours in hierarchically nanotwinned metals

Fuping Yuan、Xiaolei Wu2013-05-30The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

In the present study, a series of large-scale molecular dynamics simulations have been performed to investigate the atomistic scale fracture behaviours along the boundaries of primary twins in Cu with hierarchically nanotwinned structures (HTS), and compare their fracture behaviours with those in monolithic twins. The…

Microstructure and mechanical propertiesAluminum Alloys Composites PropertiesHigh-Velocity Impact and Material Behavior

A transflective and viewing angle controllable blue-phase liquid crystal display

Peng Li、Yubao Sun、Qiong‐Hua Wang2013-05-30Liquid Crystals

A polymer-stabilised blue-phase liquid crystal display (PSBP-LCD) with double-side in-plane switching (DS-IPS) electrode structure is proposed. This structure shows the transflective characteristics because the bottom electrodes are made by aluminium material. For transflective displays, it exhibits a well-matched vol…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsSemiconductor Lasers and Optical Devices

Powellite‐Rich Glass‐Ceramics: A Spectroscopic Study by EPR and Raman Spectroscopy

Tatiana Taurines、Delphine Neff、B. Boizot2013-05-30Journal of the American Ceramic Society

The aim of this study was to better understand the incorporation of rare‐earth elements in glass‐ceramics of nuclear interest. We synthesized glass‐ceramics from glasses in the system SiO 2 – B 2 O 3 – Na 2 O – CaO – Al 2 O 3 – MoO 3 – Gd 2 O 3 by various heat treatments. Gadolinium is used both as a spectroscopic pro…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsNuclear materials and radiation effects

Advanced surface characterization of silver nanocluster segregation in Ag–TiCN bioactive coatings by RBS, GDOES, and ARXPS

R. Escobar Galindo、N.K. Manninen、C. Palacio 等 4 位作者2013-05-30Analytical and Bioanalytical Chemistry

Surface modification by means of wear protective and antibacterial coatings represents, nowadays, a crucial challenge in the biomaterials field in order to enhance the lifetime of bio-devices. It is possible to tailor the properties of the material by using an appropriate combination of high wear resistance (e.g., nit…

Nanoparticles: synthesis and applicationsIon-surface interactions and analysisLaser-Ablation Synthesis of Nanoparticles

Water Dispersal and Functionalization of Hydrophobic Iron Oxide Nanoparticles with Lipid-Modified Poly(amidoamine) Dendrimers

Adriano Boni、Lorenzo Albertazzi、Claudia Innocenti 等 5 位作者2013-05-30Langmuir

A novel and facile method for water dispersal of hydrophobic iron oxide nanoparticles based on the amphiphilic PAMAM-C12 dendrimer is described. Stable and highly concentrated water dispersions of multifunctional magnetic nanoparticles were obtained with this single-step approach, and showed interesting relaxometric p…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryDendrimers and Hyperbranched Polymers

Effect of Support Structure and Composition on the Catalytic Activity of Pt Nanoclusters for Methane Dehydrogenation

Zhuo Cheng、Cynthia S. Lo2013-05-30Industrial & Engineering Chemistry Research

Methane adsorption and dehydrogenation on nanometer-sized Pt clusters, supported by reduced ceria (110), was investigated using density functional theory with Hubbard corrections. Two Pt nanocluster shapes, hemispherical and tetrahedral, are considered. Both stoichiometric and reduced ceria do facilitate methane adsor…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Hydrogen Adsorption and Oxidation on Pt Film: An in Situ Real-Time Attenuated Total Reflection Infrared (ATR-IR) Spectroscopic Study

Yanyan Dong、Gengshen Hu、Xin Hu 等 6 位作者2013-05-30The Journal of Physical Chemistry C

The adsorption and oxidation of hydrogen on Pt film has been studied by means of in situ real-time attenuated total reflection infrared spectroscopy. Strong hydrogen signal was obtained, which is usually very weak or hard to be detected. By applying the curve-fitting analysis to the spectra, it is concluded that three…

Catalytic Processes in Materials ScienceHydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen Reduction

Optimization of Synthesis Parameters for Mesoporous Shell Formation on Magnetic Nanocores and Their Application as Nanocarriers for Docetaxel Cancer Drug

Ahmed Mohamed El‐Toni、Mohamed Abbas Ibrahim、Joselito P. Labis 等 5 位作者2013-05-30International Journal of Molecular Sciences

In this work, Fe3O4@SiO2 nanoparticles were coated with mesoporous silica shell by S-N+I- pathway by using anionic surfactant (S-) and co-structure directing agent (N+). The role of co-structure directing agent (CSDA) is to assist the electrostatic interaction between negatively charged silica layers and the negativel…

Nanoparticle-Based Drug DeliveryMesoporous Materials and CatalysisIron oxide chemistry and applications

Thermal degradation kinetics of PET/SWCNTs nanocomposites prepared by the in situ polymerization

R. Pilawka、Sandra Paszkiewicz、Z. Rosłaniec2013-05-30Journal of Thermal Analysis and Calorimetry

The decomposition and thermal behavior of poly(ethylene terephthalate) (PET)/carbon nanotubes (CNTs) nanocomposites were studied using thermogravimetric (TG) analysis in air atmosphere. A series of PET/single-walled CNTs (SWCNTs) materials of varying nanoparticles concentration were prepared using the in situ polymeri…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesThermal and Kinetic Analysis

Considerations for the design of polymeric biodegradable products

André Costa Vieira、Rui Miranda Guedes、Volnei Tita2013-05-30Journal of Polymer Engineering

Abstract Several biodegradable polymers are used in many products with short life cycles. The performance of a product is mostly conditioned by the materials selection and dimensioning. Strength, maximum strain and toughness will decrease along its degradation, and it should be enough for the predicted use. Biodegrada…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsAdditive Manufacturing and 3D Printing Technologies

Elastic Bounds of Bioinspired Nanocomposites

H. J. Lei、Zuoqi Zhang、Fei Han 等 6 位作者2013-05-30Journal of Applied Mechanics

Biological materials in nature serve as a valuable source of inspiration for developing novel synthetic materials with extraordinary properties or functions. Much effort to date has been directed toward fabricating and understanding bio-inspired nanocomposites with internal architectures mimicking those of nacre and c…

Bone Tissue Engineering MaterialsPaleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and Inhibition

Thiol-Reactive Molecule with Dual-Emission-Enhancement Property for Specific Prestaining of Cysteine Containing Proteins in SDS-PAGE

Yong Yu、Jie Li、Sijie Chen 等 7 位作者2013-05-30ACS Applied Materials & Interfaces

1-[4-(Bromomethyl)phenyl]-1,2,2-triphenylethene (2) was synthesized and evaluated for specific fluorescent prestaining of proteins containing cysteine (Cys) in SDS-PAGE. The molecule showed classic aggregation-induced emission (AIE) property in protein labeling and its quantum efficiency was further enhanced upon reac…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsClick Chemistry and Applications