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Ultrasensitive Detection of 1, 4-Bis(4-Vinylpyridyl)Phenylene in a Small Volume of Low Refractive Index Liquid by Surface-Enhanced Raman Scattering-Active Light Waveguide

Weiqing Xu、Shuping Xu、Zhicheng Lü 等 6 位作者2004-04-01Applied Spectroscopy

This paper reports a novel surface-enhanced Raman scattering (SERS)-active light waveguide method for ultrasensitive detection of a sample dissolved in a small volume of low refractive index liquid. The SERS-active light waveguide demonstrated in this study was constructed via the light-guiding silica capillary. The s…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy Techniques in Biomedical and Chemical ResearchBiosensors and Analytical Detection

Organic Dye-Doped Thin Films for Wavelength Conversion and Their Effects on the Photovoltaic Characteristics of CdS/CdTe Solar Cell

Byung‐Chul Hong、Katsuyasu Kawano2004-04-01Japanese Journal of Applied Physics

For the improvement of the conversion efficiency of CdS/CdTe solar cells by applying the wavelength conversion properties, the spectroscopic studies of the fluorescent laser dye Rhodamine 6G (Rh6G)-doped into polyvinylbutyral (PVB) and polymethylmethacrylate (PMMA) were carried out. It was found that all the photolumi…

TiO2 Photocatalysis and Solar CellsQuantum Dots Synthesis And PropertiesPhotochemistry and Electron Transfer Studies

Development of Solid Oxide Fuel Cells by Applying DC and RF Plasma Deposition Technologies

Günter Schiller、R. Henne、Michael Lang 等 4 位作者2004-04-01Fuel Cells

Abstract Based on advanced plasma deposition technology with both DC and RF plasmas DLR Stuttgart has developed a concept of a planar SOFC with consecutive deposition of all layers of a thin‐film cell onto a porous metallic substrate support. This concept is an alternative approach to conventionally used sintering tec…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsElectrophoretic Deposition in Materials Science

Shock-wave sintering of nanodiamonds

В. В. Даниленко2004-04-01Physics of the Solid State

A two-stage technology of compaction of ultrafine-dispersed diamonds (UDDs) is developed and successfully applied for ampoule-free sintering of dense UDD granules in lead under a pressure of up to 100 GPa. Standard strength tests of polycrystals (fractions 80/63, 125/80) thus obtained showed a wide spread in strength…

Metal and Thin Film MechanicsHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

Polycatenar, bent-core pyridines and their discotic complexes with silver(I)

D.M. Huck、H. Loc Nguyen、Bertrand Donnio 等 4 位作者2004-04-01Liquid Crystals

New, bent-core, polycatenar pyridine mesogens are described. Binding to silver(I) leads to complexes properly described as discotic.

Magnetism in coordination complexesMolecular spectroscopy and chiralityAxial and Atropisomeric Chirality Synthesis

Antibiotic Treatment of Silk to Produce Novel Infection-Resistant Biomaterials

Hyung‐Min Choi、Martin Bide、Matthew D. Phaneuf 等 5 位作者2004-04-01Textile Research Journal

Dye-like applications of antibiotics to silk produce infection-resistant materials for potential use in biomedical applications. Two antibiotics, doxycycline (doxy) and cipro floxacin (cipro), are applied under a variety of conditions to silk and to silk that has previously been hydrolyzed at 40°C for 20, 40, and 60 m…

Silk-based biomaterials and applicationsPhytochemical compounds biological activitiesBiochemical and Structural Characterization

Intramolecular C−H···π Interactions in Metal-Porphyrin Complexes

Goran A. Bogdanović、Vesna B. Medaković、Miloš Milčić 等 4 位作者2004-04-01International Journal of Molecular Sciences

Cambridge Structural Database (CSD) was screened in order to find intramolecular C−H···π interactions with a chelate ring of coordinated porphyrin. It was found 154 crystal structures with 244 intramolecular C−H···π interactions in transition metal complexes with derivatives of porphyrin. Comparison of interacting dis…

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryPorphyrin Metabolism and Disorders

Recent Advances to the Development of Low‐Temperature Solid Oxide Fuel Cells

Changrong Xia、Yin Lang、Guangyao Meng2004-04-01Fuel Cells

Abstract While existing solid oxide fuel cell (SOFC) technology has demonstrated much higher energy efficiency with minimal pollutant emission than the conventional technologies, the costs of the current SOFC systems are still prohibitive for broad commercialization. To be economically competitive, both the cost of ma…

Advancements in Solid Oxide Fuel CellsElectronic and Structural Properties of Oxides

The Effect of Neutron Flux on Radiation-Induced Embrittlement in Reactor Pressure Vessel Steels

R.E. Stoller2004-04-01Journal of ASTM International

Abstract The effect of neutron flux level is a longstanding concern for determining the applicability of test reactor data or high lead-factor surveillance data to the prediction of embrittlement in commercial reactor pressure vessels (RPV). However, as operating reactors reach higher fluences, the question of flux ef…

Fusion materials and technologiesNuclear Materials and PropertiesGraphite, nuclear technology, radiation studies

Self-organization in nanocomposites based on detonation nanodiamonds

А. P. Voznyakovskii2004-04-01Physics of the Solid State

The effect of modifying detonation nanodiamond additives on the stress-strain properties of polymer nanocomposites is investigated using polysiloxane polyblock copolymers as an example. It is shown that the formation of a physical network of supramolecular structures (due to self-organization initiated by force fields…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchLaser-Ablation Synthesis of Nanoparticles

Chemical mechanical modification of nanodiamond in an aqueous system

Yixiao Zhu、Xiaojuan Shen、B. C. Wang 等 5 位作者2004-04-01Physics of the Solid State

The effect of chemical-mechanical modification (CMM) on the ζ potential and size distribution of nanodiamonds was studied. Results show a significant change in the functional groups on its surface after CMM treatment by the anionic surface modifier DN-10. The amount of hydroxyl groups decreases, and two peaks connecte…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Influence of Intermediate-Range Order on Glass Formation

Hui Li2004-04-01The Journal of Physical Chemistry B

The subpeak was first observed in glassy Fe−Al ribbons. The origin of the subpeak is not due to the system size, but it is consequence of the occurrence of local atomic structural order. The usual stability of undercooled liquids against crystallization is explained by means of local atomic structural order. Direct ex…

Material Dynamics and PropertiesTheoretical and Computational PhysicsMetallic Glasses and Amorphous Alloys

TARKIANITE, (Cu, Fe)(Re, Mo)4S8, A NEW MINERAL SPECIES FROM THE HITURA MINE, NIVALA, FINLAND

K. Kojonen、A. C. Roberts、O-P. Isomäki 等 6 位作者2004-04-01The Canadian Mineralogist

Tarkianite, a new mineral species of ideal composition (Cu,Fe)(Re,Mo)4S8, was recently discovered in sulfide concentrate from the Hitura Ni–Cu–PGE mine, Nivala, western central Finland. It is associated with pyrrhotite, pentlandite, valleriite, chalcopyrite, cubanite, mackinawite, chromite, and the PGE minerals sperry…

Glass properties and applicationsCrystal Structures and PropertiesMineralogy and Gemology Studies

Hydrogenation of Styrene‐Butadiene Rubber Catalyzed by Ru(CHCHPh)Cl(CO)(PCy3)2

Qinmin Pan、Garry L. Rempel2004-04-01Macromolecular Rapid Communications

Abstract Summary: The hydrogenation of a copolymer of styrene and butadiene (SBR) catalyzed by Ru(CHCHPh)Cl(CO)(PCy 3 ) 2 was experimentally investigated within the temperature range of 120–160 °C, at P of 300–1 200 psi, and a catalyst concentration of 10–78 × 10 −6 M . Special attention was paid to minimizing the ca…

Organometallic Complex Synthesis and CatalysisPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Achromatic polarization switch using a film-compensated twisted nematic liquid crystal cell

Qiong‐Hua Wang、Thomas Wu、Xinyu Zhu 等 4 位作者2004-04-01Liquid Crystals

A broadband polarization switch consisting of an active twisted nematic liquid crystal cell and two passive uniaxial compensation films is analysed. The conjugate gradient method was used for optimizing the device parameters. Simulation results indicate that the polarization switch exhibits a broad bandwidth and high…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhase-change materials and chalcogenides

Detonation diamonds in Ukraine

Н. В. Новиков、Г. П. Богатырева、M. N. Voloshin2004-04-01Physics of the Solid State

Some information on the history of dynamic synthesis of diamond in Ukraine is considered. Basic characteristics of ASM5 0.1/0 and ASM1 0.1/0 nanodiamond powders produced by static synthesis are described. The characteristics and surface properties of nanodiamond powders produced by detonation synthesis in Ukraine are…

Diamond and Carbon-based Materials ResearchAdvanced materials and compositesMining and Gasification Technologies

Embden–Meyerhof–Parnas and Entner–Doudoroff pathways in Thermoproteus tenax: metabolic parallelism or specific adaptation?

Hatim Ahmed、Britta Tjaden、Reinhard Hensel 等 4 位作者2004-04-01Biochemical Society Transactions

Genome data as well as biochemical studies have indicated that--as a peculiarity within hyperthermophilic Archaea--Thermoproteus tenax uses three different pathways for glucose metabolism, a variant of the reversible EMP (Embden-Meyerhof-Parnas) pathway and two different modifications of the ED (Entner-Doudoroff) path…

Glycosylation and Glycoproteins ResearchMetabolism and Genetic DisordersEnzyme Structure and Function

Direct observation of the crossover from α-relaxation to Rouse dynamics in a polymer melt

Dieter Richter、M. Monkenbusch、Lutz Willner 等 6 位作者2004-04-01Europhysics Letters (EPL)

In this letter we report a large experimental effort exploring the dynamics of poly(vinyl ethylene) on length scales covering Rouse dynamics and below. The results establish the simultaneous existence of a generic sublinear diffusion regime which underlies the α-process in addition to the Rouse process. Both regimes a…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Corrosion Protection by Electropolymerised and Polymer Pigmented Coatings - A Review

S. Sathiyanarayanan、S. Muralidharan、G. Venkatachari 等 4 位作者2004-04-01Corrosion Reviews

The aqueous electropolymerisation process can be used for the production of primer coatings on metals. Recent studies have shown that such types of coatings are highly corrosion resistant. Further it is also shown that electropolymerisation coating with pigment is feasible. Besides, the use of polymers such as polyani…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Synergistic effects of carbon fillers on tensile and impact properties in nylon 6,6 and polycarbonate based resins

Jeremiah P. Konell、Julia A. King、İ. Miskioğlu2004-04-01Polymer Composites

Abstract Electrically and thermally conductive resins can be produced by adding conductive fillers to insulating polymers. Mechanical properties such as tensile modulus, ultimate tensile strength, strain at ultimate tensile strength, and notched Izod impact strength are also important and cannot be ignored. This resea…

Mechanical Behavior of CompositesPolymer crystallization and propertiesFiber-reinforced polymer composites