Materials Literature
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Novel series of laterally 1‐substitued (H, Cl, CH3, CN, NO2) naphthalene‐2,7‐diol based liquid crystals were synthesized and their mesomorphic properties identified using DSC studies, texture observation, X‐ray investigations and electro‐optical measurements. Depending on the chain length and type of lateral substitut…
Plastic deformation in cubic metals is relatively simple due to the high crystallographic symmetry of the underlying structure. Typically, one unique slip mode can provide arbitrary deformation. This is not true in lower symmetry hexagonal metals, where prismatic and basal slip (the usual favored modes) are insufficie…
Modification of chitosan (CHI) with maleic acid (MA) via maleic anhydride (MAn) was investigated in acetic acid solution, in the presence of cerium ammonium nitrate (CAN) as the initiator. The effects of reaction time, temperature, and CAN and MA concentrations on the grafting percentage were studied. The products wer…
The synthesis and phase behaviour of a new series of unsymmetrically substituted hexaalkoxytriphenylene‐based liquid crystals are reported. One of the hexyloxy chains in hexahexyloxytriphenylene (HAT6) is replaced by either a shorter or a longer chain, HAT‐(OC6H13)5(OC n H2n+1). Compounds with chain lengths n of 2–14,…
We present a theoretical model which describes the polarization-modulated and layer-undulated structure of the B7 phase and gives the phase transition from the synclinic ferroelectric smectic-C(S)P(F) phase to the B7 phase as observed experimentally. The system is driven into the modulated phase due to the coupling be…
The electronic structures and the magnetic properties of dilute magnetic semiconductors (DMSs) based on transparent semiconducting oxide CuAlO 2 are calculated by using the Korringa–Kohn–Rostoker method combined with the coherent potential approximation within the local density approximation. We see from the results t…
Abstract Tissue engineering entails the in vitro or in vivo generation of replacement tissues from cells with the aid of supporting scaffolds and stimulating biomolecules, in order to provide biological substitutes for restoration and maintenance of human tissue functions. In this review, we summarize the main classes…
This article reports on the design and performance analysis of a solar thermoelectric power generation plant (STEPG). The system considers both truncated compound parabolic collectors (CPCs) with a flat receiver and conventional flat-plate collectors, thermoelectric (TE) cooling and power generator modules and appropr…
A compression test system was developed for measuring the strength of a single particle with a cross-sectional dimension of less than 1μm. The test system used a small diamond plate that has a flat platen to compress the particle on a diamond substrate. To avoid compressing multiple particles and to avoid direct conta…
High-energy synchrotron-radiation (SR) powder diffraction experiments have been carried out to investigate the relationship between the crystal structure of the paraelectric phase in PbZr 1- x Ti x O 3 (PZT) and phase transition. The Rietveld refinement adopting the split-atom method reveals that the Pb atom in PZT, e…
A detailed 57Fe Mössbauer study of the Mg(0.8)Fe(0.2-y)Co(y)Al2O4 (y = 0, 0.05, 0.1, 0.15, 0.2) solid solutions and of the CNT-Fe/Co-MgAl2O4 nanocomposite powders prepared by reduction in H2-CH4 has allowed characterization of the different iron phases involved in the catalytic process of carbon nanotube (CNT) formati…
The Raman spectrum of isotactic polypropylene (iPP) has been found to exhibit vibrational peaks in the region of 750 to 880 cm(-1) that are sensitive to the degree of crystallinity. These features are broadly assigned to various modes of methyl group rocking, rho(CH2), and there have been various attempts to assess cr…
The syntheses of derivatives of isosorbide and cinnamic acid are described. These chiral compounds are photoisomerizable. The Z‐isomers could also be obtained after irradiation of these E‐isomeric cinnamic derivatives. The Z‐isomers were found to have a much lower helical twisting power than the E‐isomers. These compo…
Thin films of diblock copolymers with cylindrical microdomains oriented normal to the film plane are employed as planar optical waveguides in the Kretschmann configuration (see Figure). Their waveguiding properties were investigated by optical waveguide spectroscopy. The dielectric constants and the film thickness of…
The gyromagnetic factors g ∥ , g ⊥ and the hyperfine structure constants A ∥ and A ⊥ of the tetragonal Cu 2+ center in KTaO 3 are theoretically studied in this work. Based on the analyses of the electron paramagnetic resonance results of this center, it is found that the impurity Cu 2+ occupies the octahedral Ta 5+ si…
Propionate is a very abundant carbon source in soil, and many microorganisms are able to use this as the sole carbon source. Nevertheless, propionate not only serves as a carbon source for filamentous fungi but also acts as a preservative when added to glucose containing media. To solve this contradiction between carb…
Hyperbranched polymers (HBPs) formed by a self-condensing vinyl polymerization (SCVP) of copolymerization of AB* monomers slowly added into trifunctional C 3 * cores under various feed rates were investigated by a kinetic model. The dependences of average molecular weight, polydispersity, degree of branching, and numb…
The mass transfer of naphthalene vapor to water droplets in air was studied in the presence of ozone (O3) in the gas phase. A falling droplet reactor with water droplets of diameters 55, 91, and 182 microm was used for the study. O3 reacted with naphthalene at the air-water interface, thereby decreasing the mass trans…
The electronic properties of ${({\mathrm{Li}}_{2}\mathrm{O})}_{x}{({\mathrm{B}}_{2}{\mathrm{O}}_{3})}_{1\ensuremath{-}x}$ ($x=0.0$, 0.25, 0.33, 0.5, 0.75, and 1.0) compounds were studied by periodic quantum-chemical calculations at density functional theory level using localized atomic basis functions. A good agreemen…
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