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Binding of Glucose to the d-Galactose/d-Glucose–Binding Protein from Escherichia coli Restores the Native Protein Secondary Structure and Thermostability That Are Lost upon Calcium Depletion

Sabato D’Auria、Alessio Ausili、Anna Marabotti 等 9 位作者2006-02-01The Journal of Biochemistry

The effect of the depletion of calcium on the structure and thermal stability of the D-galactose/D-glucose-binding protein (GGBP) from Escherichia coli was studied by fluorescence spectroscopy and Fourier-transform infrared spectroscopy. The calcium-depleted protein (GGBP-Ca) was also studied in the presence of glucos…

Protein Structure and DynamicsEnzyme Structure and FunctionGABA and Rice Research

Synthesis and Characterization of Luminescent Conjugated Polymer−Silica Composite Spheres

Renu Ravindranath、Parayil Kumaran Ajikumar、Nurmawati Bte Muhammad Hanafiah 等 5 位作者2006-02-01Chemistry of Materials

A novel poly( p -phenylene) derivative ( C 12 PPPC 11 OH ) was synthesized and used as a template for silica polymerization under ambient conditions in the absence of added catalysts. A few polymers of analogous molecular structures were also simultaneously used in control experiments to derive a molecular mechanism f…

Conducting polymers and applicationsLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors

Unique Formation of a Pentanuclear Lanthanum(III) Thiolate Oxide Cluster via Control of Hydrolysis

Hong‐Xi Li、Mei-Ling Cheng、Zhi-Gang Ren 等 6 位作者2006-02-01Inorganic Chemistry

The reaction of [(TMS)2N]3La(mu-Cl)Li(THF)3 (1) and HSPh produced a bimetallic complex [{(TMS)2N}2La(THF)]2(mu-SPh)(mu-Cl)] (2). Compound [{(TMS)2N}2La5O(SPh)10LiCl2(THF)6] (3) was prepared by control of the hydrolysis of 2 and LiCl or 1 and HSPh with the proper amount of water. 1 was treated first with 1/6 equiv of H…

Radioactive element chemistry and processingLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

Polyethylene Organo-Clay Nanocomposites: The Role of the Interface Chemistry on the Extent of Clay Intercalation/Exfoliation

Michaël Mainil、Michaël Alexandre、Fabien Monteverde 等 4 位作者2006-02-01Journal of Nanoscience and Nanotechnology

High density polyethylene (HDPE)/clay nanocomposites have been prepared using three different functionalized polyethylene compatibilizers: an ethylene/vinyl acetate copolymer, a polyethylene grafted with maleic anhydride functions and a (styrene-b-ethylene/butylene-b-styrene) block copolymer. The nanocomposites were p…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesTribology and Wear Analysis

Melting behaviors, crystallization kinetics, and spherulitic morphologies of poly(butylene succinate) and its copolyester modified with rosin maleopimaric acid anhydride

Xiaoqing Liu、Chuncheng Li、Dong Zhang 等 4 位作者2006-02-01Journal of Polymer Science Part B Polymer Physics

Abstract This article investigated the melting behaviors, crystallization kinetics, and spherulitic morphologies of poly(butylene succinate) (PBS) and its copolyester (PBSR) modified with rosin maleopimaric acid anhydride, using wide‐angle X‐ray diffraction, differential scanning calorimeter (DSC), and polarized optic…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Mechanical and Rheological Behavior of Unvulcanized and Dynamically Vulcanized i‐PP/EPDM Blends

Э. В. Прут、Tatiana Medintseva、V.Ye Dreval'2006-02-01Macromolecular Symposia

Abstract The mechanical and rheological behavior of dynamically vulcanized PP/EPDM blends is examined and compared with those of unvulcanized blends. The effect of blend ratio and dynamic vulcanization of EPDM rubber on tensile properties and flow are investigated. The mechanical properties of the blends are strongly…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesTransport Systems and Technology

Electronic properties of H-terminated diamond in electrolyte solutions

Christoph E. Nebel、Bohuslav Rezek、Dongchan Shin 等 5 位作者2006-02-01Journal of Applied Physics

The electronic properties of hydrogen-terminated single-crystalline chemical-vapor deposited diamond in electrolyte solutions between pH 2 and 12 have been characterized by cyclic voltammetry experiments and pH-sensitive measurements using ion-sensitive field-effect transistor structures. The data show the formation o…

Diamond and Carbon-based Materials ResearchAnalytical Chemistry and SensorsElectronic and Structural Properties of Oxides

NEW PHYSICAL EFFECTS IN METAL DEUTERIDES

Peter L. Hagelstein、Michael C. H. McKubre、David J. Nagel 等 5 位作者2006-02-01OpenAlex

The experimental evidence for anomalies in metal deuterides, including excess heat and nuclear emissions, suggests the existence of new physical effects. 1.

Advanced Chemical Physics StudiesCrystallography and molecular interactionsHydrogen Storage and Materials

Cracking in ferroelectric ceramic actuators caused by domain switching

Kyoung Moon Jeong、Hyeon Gyu Beom2006-02-01International Journal of Applied Electromagnetics and Mechanics

Cracking near the edge of an internal electrode embedded in ferroelectric ceramic actuators is analyzed. The boundary of the domain switching zone near the edge of the internal electrode in a ceramic multilayer actuator is determined based on the nonlinear electric theory. Under small-scale conditions, the stress inte…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisNumerical methods in engineering

Permanente plasmapolymere Trennschichten

Klaus‐D. Vissing、Holger Klyszcz‐Nasko2006-02-01Vakuum in Forschung und Praxis

Abstract Beschichtungen mit Trennaktivität zeichnen sich dadurch aus, dass das O/Si‐Verhältnis ca. 1:1 und das Kohlenstoff‐Siliziumverhältnis ca. 2:1 beträgt. Hieraus lässt sich folgern, dass für die Trennwirkung eine Struktur verantwortlich ist, die dem PDMS ähnlich ist und für die dreidimensionale Vernetzung ein erh…

Copper Interconnects and ReliabilitySynthesis and properties of polymersSilicone and Siloxane Chemistry

Elastomeric Compounds with Silica. Lower Hysteresis in the Presence of Functionalised Isoprene Oligomers

Maurizio Galimberti、G. Melillo、Francesca Baione 等 7 位作者2006-02-01Macromolecular Symposia

Abstract Silica as reinforcing filler brings about a low hysteresis in elastomeric compounds. Aim of this work was to promote a better silica‐elastomer interaction by using, as minor ingredients of a compound, isoprene oligomers having a functional group as the chain end. The effect of the functionality was investigat…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Mass Attenuation of Gamma Photons in Special Lead Glass that Can be Used in Radiation Shielding Windows

Firas Mohammed Ali Fathi2006-02-01Mağallaẗ ʻulūm al-rāfidayn

Three samples of special lead glass are suggested for radiation protection and radiation shielding. Each one of these samles consist of seven oxides (Lead Oxide, Silicon Oxide, Barium Oxide, Sodium Oxide, Calcium Oxide, Aluminum Oxide and Cerium Oxide) with different weight ratio for each sample. The mass attenuation…

Luminescence Properties of Advanced MaterialsRadiation Shielding Materials AnalysisNuclear materials and radiation effects

EPR studies of phase transitions in perchlorates [M2+(ClO4)2 · 6H2O] at high pressures

A. A. Prokhorov、G. N. Neĭlo、A. D. Prokhorov 等 4 位作者2006-02-01Physics of the Solid State

The EPR spectra of the Mn 2+ ion in crystals of the perchlorate hexahydrates Zn(ClO 4 ) 2 · 6H 2 O, Mg(ClO 4 ) 2 · 6H 2 O, and Cd(ClO 4 ) 2 · 6H 2 O were studied in the temperature range 77–320 K under hydrostatic pressure. It is shown that the octahedron of six molecules H 2 O surrounding this paramagnetic ion is con…

Crystallography and molecular interactionsSolid-state spectroscopy and crystallographyChemical Thermodynamics and Molecular Structure

Pitting on the 20Kh13 steel in chloride solutions

А. Д. Давыдов、В. С. Шалдаев、G.R. Engelgardt2006-02-01Russian Journal of Electrochemistry

The dependences of the pitting potential, determined by potentiodynamic method, on the NaCl solution concentration, pH, and temperature are found. The repassivation potential and the induction time for the pitting under different conditions are determined. The corrosion potential and kinetic parameters of the steel di…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMaterial Properties and Failure Mechanisms

MECHANISM AND SIMULATION OF UNIFORM NANOWIRES OF POROUS SILICON GROWTH ON p-Si SUBSTRATE

Syed Minhaz Hossain、Jayoti Das、Sansa Dutta 等 4 位作者2006-02-01International Journal of Nanoscience

An extension of Beale's and Lehman's model for the formation of porous silicon (PS) layer on p-type substrate is proposed with a view to explain the experimental conditions necessary for obtaining either uniform vertical pores or nonuniform pore branching. A uniformity parameter is defined and correlated with the meas…

Thin-Film Transistor TechnologiesSilicon and Solar Cell TechnologiesSilicon Nanostructures and Photoluminescence

Stress relaxation during superelastic behavior of TiNi shape memory alloy

E. A. Pieczyska、S.P. Gadaj、Wojciech Nowacki 等 4 位作者2006-02-01International Journal of Applied Electromagnetics and Mechanics

Martensitic and reverse transformations in TiNi shape memory alloy subjected to tension test at room temperature are investigated using a thermovision camera. Stress relaxation stages during the loading and unloading branches are induced, respectively. A very large stress drop, caused by the phase transformation, is o…

Shape Memory Alloy TransformationsTitanium Alloys Microstructure and Properties

Compatibility of Nickel-Based Alloys with Supercritical Water Applications: Aging Effects on Corrosion Resistance and Mechanical Properties

Yuzo Daigo、Yutaka Watanabe、Katsuo Sugahara 等 4 位作者2006-02-01CORROSION

Corrosion-resistant Ni-based alloys are thought to be strong candidates as a structural material for chemical processes using supercritical water (SCW). In recent years, Cr was considered as the most important alloying element to improve corrosion resistance in SCW. However, high Cr content can cause a phase transform…

Advanced materials and compositesAdvanced Materials Characterization TechniquesMetallurgical and Alloy Processes

High‐Temperature Oxidation of a Cu–Ni Based Cermet: Kinetic and Microstructural Study

Fabien Rioult、Michèle Pijolat、Françoise Valdivieso 等 4 位作者2006-02-01Journal of the American Ceramic Society

The oxidation of a cermet composed of nickel ferrite (Ni x Fe 3− x O 4 ), nickel oxide (Ni y Fe 1− y O), and Ni–Cu alloy (Cu z Ni 1− z ) (with x =0.8, y =0.84, and z =0.44) has been studied by thermogravimetry, at 960°C, under controlled oxygen partial pressure. The rate of oxidation increases with the oxygen partial…

Magnetic Properties and Synthesis of FerritesMetallurgical Processes and ThermodynamicsCopper-based nanomaterials and applications

Layer‐by‐Layer Self‐Assembly of Ceramic Particles for Coating Complex Shape Substrates

Hongwei Qiu、Woo Y. Lee、Svetlana A. Sukhishvili2006-02-01Journal of the American Ceramic Society

Key parameters for controlling the layer‐by‐layer self‐assembly of ceramic particles were studied using a model system, which consisted of an Si substrate, 100 and 500 nm silica spheres, and a polycation/polyanion combination that provided binding between the substrate and silica particles, as well as between the sili…

Polymer Surface Interaction StudiesPickering emulsions and particle stabilizationElectrophoretic Deposition in Materials Science

Discostellataxa (Bacillariophyta) from the Río Limay basin (northwestern Patagonia, Argentina)

José María Guerrero、Ricardo O. Echenique2006-02-01European Journal of Phycology

Discostella stelligera and allied similar taxa are mainly identified by the presence of marginal fultoportulae located at the end of the striae, and not on the interstriae, as occurs in the genus Cyclotella, from which they have recently been removed. In this paper, valve morphology and ultrastructure of D. stelligera…

Diatoms and Algae Research