Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Abstract The PANI/CeO 2 composites were synthesized using in situ deposition technique by placing fine graded CeO 2 in polymerization mixture of aniline. This is the single step polymerization process for the direct synthesis of emeraldine salt phase of polymer. Low frequency dielectric studies were carried out on pre…
Abstract A complex of Eu 3+ , benzoate (BA), acrylate (AA), and 1,10‐phenanthroline (Phen) was synthesized in this work. The structure of Eu(BA) 2 (AA)(Phen) was characterized with elemental analysis, FTIR, and UV spectroscopy. Copolymers containing rare earth complex were prepared via the copolymerization of Eu 3+ (B…
The Ti-doped SnO2(110) surface has been investigated by using first-principles method with a slab model. The geometrical optimizations and band-structure calculations have been performed for four possible doping models. Our results indicate that the substitution of Ti for sixfold-coordinated Sn atom at the top layer i…
Epitaxial perovskite Pb(Zn1∕3Nb2∕3)O3 (PZN)-based ferroelectric thin films were prepared through a chemical solution approach, in which the solution precursors were appropriately modified with polyethylene glycol (PEG). The addition of PEG in the solution dramatically promoted the perovskite phase while suppressed the…
Abstract This study compared a series of experimental propylene/ethylene copolymers synthesized by a transition metal‐based, postmetallocene catalyst (xP/E) with homogeneous propylene/ethylene copolymers synthesized by conventional metallocene catalysts (mP/E). The properties varied from thermoplastic to elastomeric o…
The present work is devoted to a study of the shear-induced parallel-to-perpendicular orientation transition in the lamellar system by the large-scale nonequilibrium molecular-dynamics (NEMD) simulation. An effective generic model-A2B2 tetramer for amphiphilies is used. The NEMD simulation produces unambiguous evidenc…
The iron-incorporated mesoporous silica material Fe-HMS was successfully synthesized at ambient temperature by using dodecylamine as the template agent, and it was characterized by XRD, SEM, FT-IR, UV-vis, ESR and N(2) adsorption measurements. Its catalytic performance was studied for phenol hydroxylation with H(2)O(2…
Abstract The impact behaviors of nanoclay‐filled nylon 6 (nano‐nylon 6) blended with poly(acrylonitrile–butadiene–styrene) terpolymers (ABS) prepared through a twin screw mixing process were investigated here using metallocene polyethylene grafted maleic anhydride (POE‐ g ‐MA) as a compatibilizer to enhance the interf…
Abstract In this work, composites of an EVA polymer matrix and short sisal fiber were characterized. The physical‐morphological as well as chemical interactions between EVA and sisal were investigated. When the samples were prepared in the presence of dicumyl peroxide, the results suggest that crosslinking of EVA as w…
Abstract The formation mechanism of precipitated calcium carbonate from aqueous solution under industrial conditions (high supersaturation) was investigated in a semi‐batch and in a continuous mixing nozzle process. The influence of potassium hydroxide and magnesium chloride on crystal modification and particle size w…
Piezoelectric fibres are finding increasing application in a variety of piezoelectric composites, including active fibre composites (AFCs). This paper describes the manufacture and characterization of lead zirconate titanate (PZT) fibres manufactured by viscous plastic processing (VPP). The manufacturing method will b…
Neutron scattering results are presented for spin-wave excitations of three ferromagnetic metallic A1-xA'xMnO3 manganites (where A and A' are rare- and alkaline-earth-metal ions), which when combined with previous work elucidate the systematics of the interactions as a function of carrier concentration x, on-site diso…
Abstract In this work, we synthesized poly(methyl methacrylate) (PMMA)/expanded graphite (EG) nanocomposites by a new polymerization method. The volume electrical conductivity of the nanocomposite prepared by this way is very high (when the content of EG is about 8 wt %, the conductivity could reach 60 S/cm). The stru…
This paper introduces a process to synthesize well aligned carbon nanotubes (CNTs) from ethanol flames by using a uniform electric field generated from a DC power supply. It has been found that (1) comparing with the other processes a small electric field is enough to align CNTs; (2) the synthesis process becomes more…
Abstract The sorption of ethylene and 1‐hexene and their mixture in three poly(ethylene‐ co ‐1‐hexene) samples is measured gravimetrically at temperatures 70, 90, and 150°C and pressures 0–30 bar. Gravimetric sorption measurements are supplemented with microscopic observations of swelling of polyethylene particles cau…
With the density-functional theory and nudged elastic band method, the adsorption and dissociation of the hydrogen molecule on the boron nitride (BN) nanotubes with and without defects are studied theoretically. Hydrogen molecule physically adsorbs on the surface of the BN layer and nanotubes. The dissociation of the…
Abstract Graft copolymerization of methyl methacrylate (MMA) onto Antheraea pernyi silk fibers, initiated by benzoyl peroxide in the supercritical CO 2 was investigated. The grafting degree was determined as a function of impregnating pressure, impregnating time, monomer concentration, initiator concentration, and rea…
Abstract New poly(azomethine urethane)s were synthesized in the conventional literature manner by reacting a new bisphenol‐containing azomethine group, N , N ′‐bis(4‐hydroxyl‐3‐methoxy benzylidine)‐2,6‐diaminopyridine (I) with various diisocyanates, such as hexamethylene diisocyanate (HDI) (a), methylene‐4,4′‐diphenyl…
Abstract Novel anion exchange materials was prepared from cellulose fabrics (cotton‐ and rayon‐cloths) by binding polyallylamine to aldehyde groups introduced by partial oxidation of cellulose via sodium periodate treatment. Degree of oxidation (D.O.) was controlled to 2–8% by the amount of oxidant. Polyallylamine (MW…
Nanographite having open edges has a nonbonding $\ensuremath{\pi}$-electron state of edge origin (edge state), which causes unconventional electronic and magnetic features. Bromine-adsorption effect on the electronic and magnetic properties of nanoporus carbon consisting of a flexible three-dimensional random nanograp…