Materials Literature
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The thermoelectric transport properties of Lu-doped Yb 14 MnSb 11 Zintl compounds have been investigated. The electrical conductivity increased and the Seebeck coefficient decreased with increasing Lu doping content, due to an increased carrier concentration. The carrier mobility behavior was in good accordance with t…
Strong white electroluminescence (EL) from SiN-based devices containing Si nanodots with a density of more than 4.6×1012/cm2 was investigated. The white EL illustrates enhanced light emission with increasing applied voltage and can be divided into two components, a dominant peak at ∼710 nm and weak one at ∼550 nm, whi…
A temperature-sensitive polymer/carbon nanotube interface with switchable bioelectrocatalytic capability was fabricated by self-assembly of poly(N-isopropylacrylamide)-grafted multiwalled carbon nanotubes (MWNT-g-PNIPAm) onto the PNIPAm-modified substrate. Electron microscopy and electrochemical measurements revealed…
Abstract A series of dyes bearing polymethine chromophore units in boron dipyrromethene (BODIPY) α‐positions were prepared by condensation of 3,5‐dimethyl boron dipyrromethene with various hemicyanines. One or two methyl groups of the starting material can react, yielding the corresponding mono‐ and disubstituted deri…
This study proposes a novel method using Jiles-Atherton model parameters to identify small fault current results from winding turn-to-turn short circuit in power transformer inrush current. The waveform symmetry and hysteresis curve shapes of inrush current with fault current are different from inrush current without…
PURPOSE: To assess the feasibility of loading iron oxide nanoparticles in endothelial microparticles (EMPs), thereby enabling their noninvasive monitoring with magnetic resonance (MR) imaging in mice. MATERIALS AND METHODS: Experiments were approved by the French Ministry of Agriculture. Endothelial cells, first label…
Freeze-dried wheat gluten foams were evaluated with respect to their thermal and fire-retardant properties, which are important for insulation applications. The thermal properties were assessed by differential scanning calorimetry, the laser flash method and a hot plate method. The unplasticised foam showed a similar…
Centimeter-sized Te-doped GaSe ingots were grown from the charge compositions of GaSe with nominals 0.05, 0.1, 0.5, 1, and 3 mass% Te, which were identified as ε-GaSe:Te (0.01, 0.07, 0.38, 0.67, and 2.07 mass%) single crystals. The evolution of the absorption peaks of the phonon modes E'(2) (≈ 0.584 THz) and E"(2) (1.…
We present an ab initio analysis for the ground-state properties of a correlated organic compound $\kappa$-(BEDT-TTF)2Cu(NCS)2. First, we derive an effective two-dimensional low-energy model from first principles, having short-ranged transfers and short-ranged Coulomb and exchange interactions. Then, we perform many-v…
Nanoporous iron metal foams were synthesized by an improved sol-gel autocombustion method in this report. It has been confirmed to be pure phase iron by X-ray diffraction measurements. The nanoporous characteristics were illustrated through scanning electron microscope and transmission electron microscope images. Very…
The reaction of new dinuclear gold(I) organometallic complexes containing mesityl ligands and bridging bidentate phosphanes [Au(2)(mes)(2)(μ-LL)] (LL=dppe: 1,2-bis(diphenylphosphano)ethane 1a, and water-soluble dppy: 1,2-bis(di-3-pyridylphosphano)ethane 1b) with Ag(+) and Cu(+) lead to the formation of a family of het…
Morphologies à la carte: A kinetic control strategy has been utilized to fabricate bimetallic nanoparticles. Using cubic Pd nanocrystals as seeds and a syringe pump that enables precise control over precursor injection rate, it is possible to synthesize Pd–Ag bimetallic nanoparticles with tailored shapes (see picture:…
Multiwalled carbon nanotubes (MWCNTs) have a great potential in wide applications but faces limitation in term of dispersion feasibility. The aggregation of MWCNTs floss has restricted its usage and thus, acid treatment is expected to promote the MWCNTs reaggregation. The functionalization process of MWCNTs involves o…
The acoustic vibrations of gold nanorods coated with palladium were investigated as a function of Pd amount using ultrafast pump-probe spectroscopy. Both the extensional and breathing vibrational modes of the nanorods were coherently excited and detected. This permits precise determination of their periods, which were…
Poly(2-aminothiazole) derivatives were synthesized by chemical oxidative polymerization method using 2-aminothiazole (2AT), 2-aminobenzothiazole (2ABT) and 6-ethoxy-2-aminobenzothiazole (EtO-2ABT) as the monomers. Structural characterizations were carried out by Fourier Transform Infrared (FT-IR), nuclear magnetic res…
Modeling interfacial properties is a major challenge for mesoscopic simulation methods. Many-body dissipative particle dynamics (MDPD) is then a promising method to model heterogeneous systems at long time and length scales. However no rule exists to obtain a set of MDPD parameters capable to reproduce the thermodynam…
Dynamisch oleophobe Oberflächen mit Filmen aus Poly(dimethylsiloxan)(PDMS)-Bürsten mit niedrigem Molekulargewicht wurden hergestellt. Trotz der statisch oleophilen Natur dieser nicht aufgerauten und nicht perfluorierten Oberflächen werden sehr kleine Kippwinkel (TAs) erreicht, die Tropfen unpolarer Flüssigkeiten in Be…
We introduce a novel bottom-up approach to fabricate by self assembly a metamaterial from metallic nanoparticles in a two-step process. In the first step, a metamaterial made of densely packed silver nanoparticles is required. The material dispersion with increasing nanoparticle densities, from dispersed to randomly p…
We propose a general nucleation and growth model that can explain the mechanism of the formation of CoPt(3)/Au, FePt/Au, and Pt/Au nanodumbbells. Thus, we found that the nucleation event occurs as a result of reduction of Au(+) ions by partially oxidized surface Pt atoms. In cases when Au(3+) is used as a gold precurs…
Temperature dependencies of cyclization and cycloreversion processes of a photochromic diarylethene derivative, 1,2-bis(2-methyl-3-benzothienyl)perfluorocyclopentene (BT), were investigated by steady-state spectroscopy and femtosecond laser photolysis methods. Steady-state measurements revealed that the cyclization re…