Materials Literature
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Nanotube-containing membranes prepared by the template method show promise for use as highly selective filters for membrane-based chemical and biological separations. Most of the work to date has been done on gold nanotubes prepared by electroless deposition of Au within the pores of polymeric filtration membranes. Th…
Studies were carried out to produce biodegradable films from cassava starch. Two alternatives were investigated. In the first, films were obtained by starch gelatinization followed by thermopressing and glycerol was used at different concentrations as a plasticizer. In the second, starch acetate films were obtained by…
Abstract This paper prepares the ground for the continuum analysis of shear band evolution using a Cosserat/micropolar constitutive equation derived from micromechanical considerations. The nature of the constitutive response offers two key advantages over other existing models. Firstly, its non‐local character obviat…
Methanococcus jannaschii MJ0936 is a hypothetical protein of unknown function with over 50 homologs found in many bacteria and Archaea. To help define the molecular (biochemical and biophysical) function of MJ0936, we determined its crystal structure at 2.4-A resolution and performed a series of biochemical screens fo…
The temperature-dependence of the cation distribution in synthetic spinel (MgAl 2 O 4 ) was investigated using in situ time-of-flight neutron powder diffraction at ISIS, the pulsed-neutron source at the Rutherford Appleton Laboratory. Neutron diffraction patterns of stoichiometric MgAl 2 O 4 were collected on heating…
Abstract Shear and extensional rheological measurements were conducted in conjunction with laser light scattering (LLS) on ethylene‐vinyl acetate copolymer (EVA) nanocomposites. The materials were prepared by melt‐mixing EVA and commercially acquired layered silicates. Wide Angle X‐Ray Scattering (WAXS) was used to as…
A lack of understanding about the selenite adsorption behavior on hydroxyaluminum (HyA)‐ and hydroxyaluminosilicate (HAS)‐interlayered phyllosilicates led us to conduct the present study. The kinetics of selenite adsorption on montmorillonite (Mt), HyA(OH/Al = 2.0)‐Mt, HAS1(OH/Al = 2.0; Si/Al = 0.24)‐Mt, and HAS2(OH/A…
BACKGROUND: Investigations were performed to determine whether poly-N-acetyl glucosamine (p-GlcNAc) induces hemostasis by the activation of platelets. METHODS: Platelets were isolated from human blood, fixed in the presence poly-N-acetyl glucosamine fibers, and visualized with scanning electron microscopy. Platelet ac…
Water-soluble poly(alkyl aryl ether) dendrimers have been explored for their use as hosts of organic substrates in aqueous media. Prototypical photoreactions, namely, photo-Fries reaction of (a) 1-naphthyl benzoate and (b) 1-naphthyl phenyl ester and alpha-cleavage reaction of (a) dibenzyl ketones and (b) benzoin alky…
We report on the controlled chemical grafting of well-defined polymer chains onto individual montmorillonite-type clay nanoplatelets and the direct visualization of the formed hybrid material at the nanoscale level. Our approach is based on the use of a surfactant mixture that contains varying proportions of hydroxyl-…
The structural, electrical, and magnetic properties of Fe3Si/GaAs(001) hybrid structures with high crystalline and interfacial perfection are studied. The Fe3Si/GaAs(001) hybrid structures are fabricated by molecular beam epitaxy at 200 °C. The composition of the films, which can be regarded as a Heusler alloy, is tun…
We describe the properties and potential applications of an electronic material that consists of an interconnected random network of single-walled carbon nanotubes. This material possesses useful electronic properties, and it can be patterned into devices with high yield using conventional microfabrication technology.…
Abstract In this paper, we describe the synthesis and characterization of poly(9,9′‐dioctylfluorene)–poly(ethylene oxide) (PF‐PEO) block copolymers with different block ratio and molecular architectures (diblock or triblock copolymers). Tapping‐mode atomic force microscopy is used to investigate the relationship betwe…
Nanoscale fabrication methods provide a unique approach to synthesize nanoscale materials. Laser-assisted embossing was used to generate close-packed arrays of hemispherical nanowells with zeptoliter (zL) volumes. The volumes of the nanowells were controlled by changing the fluence of the laser, by applying variable p…
By depositing PVD coatings on already conventionally galvanized steel sheets novel zinc alloy coatings have been developed. One of the biggest advantages of PVD coatings lies in the broad choice of coating materials as there are no constraints due to chemical reactions between the substrate and the coating. This leads…
Abstract The synthesis, crystal structure, and magnetic properties of quaternary oxides Ba3Ln2MO9 (Ln = Y, Sm–Gd, Dy–Lu for M = Mo; Ln = Y, Sm–Lu for M = W) are reported. Their powder X-ray diffraction measurements and Rietveld analysis showed that they have a “disordered” perovskite structure, i.e., BaLn2/3M1/3O3 exc…
The coercivity of cellular Sm-Co based permanent magnets is investigated by model calculations. The grain boundaries responsible for the pinning coercivity are modeled as planar inhomogeneities with arbitrary cross-sectional geometry. The calculation yields a physically transparent integral equation for the pinning en…
Multi-layer hydrogen storage thin films with Mg and MmNi3.5(CoAlMn)1.5 (here Mm denotes La-rich mischmetal) as alternative layers were prepared by direct current magnetron sputtering. Transmission electron microscopy investigation shows that the microstructure of the MmNi3.5(CoAlMn)1.5 and Mg layers are significantly…
Abstract Models based on kinetic, thermodynamic and rheological equations have been developed to compute dispersion extent, batch temperature and relative batch viscosity at discrete intervals during a mix cycle in an internal mixer. The calculated relative bulk viscosity can be linked empirically to a measured variab…
Abstract This review covers the various polymeric materials now used to produce outsoles and midsoles for footwear. Thermoset rubbers are considered to be the best material in terms of performance, but many new materials are challenging in the marketplace, due to their ease of production and lighter weight. While the…