Materials Literature
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The substrate-induced oxidation upon prolonged annealing in UHV of ultrathin films of Ni and Cr vapor deposited on yttria-stabilized zirconia YSZ(100) was studied by X-ray photoelectron spectroscopy (XPS) to obtain information about the oxidation mechanism, determine the available quantity of reactive oxygen in YSZ, a…
The isothermal decomposition of austenite into ferrite is investigated using a two-dimensional cellular automaton (CA) algorithm. This CA model provides a simple solution for the difficult moving boundary problem that governs the ferrite grain growth. In this model, the growth of ferrite grains is controlled by both t…
The domain structures of Bi 4− x La x Ti 3 O 12 (BLT) ceramics (where x = 0, 0.5, 0.75, and 1.0) have been investigated by transmission electron microscopy. The morphology of the 90° domain walls were found to be curved due to a decrease of the spontaneous strain energy after doping with La. Movement of the 90° domain…
Cd1-xMnxS quantum dots (QDs) with diameter d less than or equal to 4.5 nm and with manganese concentrations from x = 0.001 to 0.15 have been prepared using aqueous solution precipitation. Absorption and fluorescence spectra at room temperature have been recorded. No monotonic variation of the band gap energy with incr…
Experiment unambiguously shows substitutional nickel is present in as-grown synthetic diamond where Ni is present in the solvent–catalyst. There is less convincing evidence for the presence of an interstitial species. We present the results of first-principles calculations of the properties of substitutional and inter…
<div class="htmlview paragraph">Impact of oil-derived ash on the pressure drop of continuous regeneration-type diesel particulate filter (CR-DPF) was investigated through 600hrs running test at maximum power point on a 6.9L diesel engine, which meets the Japanese long-term emission regulations enacted in 1998, u…
We report on experimental studies of the phase state and the character of phase transitions in the quasi-one-dimensional organic compound $(\mathrm{TMTSF}{)}_{2}{\mathrm{PF}}_{6}$ in the close vicinity of the borders between the metal (M), antiferromagnetic (AF) insulator, and superconducting (SC) states. In order to…
Abstract The divergent dendronization of an ϵ‐caprolactone‐based polymer has been performed to provide access to dendronized polymers with sufficient biocompatibility and degradability for use as drug‐delivery scaffolds. The synthesis was performed through the tin(II) 2‐ethylhexanoate‐catalyzed polymerization of a γ‐f…
The wet air regeneration of some 4-chloro-2-methylphenoxyacetic acid (MCPA) exhausted activated carbons (ACs) has been investigated. The wet oxidation process of MCPA in the absence of ACs suggests the development of a a radical mechanism. Oxygen partial pressure has been shown not to affect the process, while pH exer…
Abstract As an experimental necessity, past flame spread studies have relied on fast burning cellulosic papers. For the longer duration tests planned for the International Space Station a 50% fiberglass, 50% cotton composite fabric is better suited for the novel fuel feeding system in the compact hardware design of a…
Part I of this article describes a series of tests of localized, penetrating impact on sandwich panels. The sandwich panel size was 500 500 mm 2 with a thickness of 46 mm. Three types of panel configuration were tested. Penetration was carried out in quasi-static conditions and at approximately 70 and 93 m/s. Impactor…
Diblock copolymers containing recognition units designed to participate in specific three-point hydrogen bonding were adsorbed onto modified gold surfaces. Self-assembled monolayers (SAMs) containing complementary recognition units were used to direct the adsorption process. The polymer-modified surfaces obtained were…
Thermal diffusivity of the composites of camphor sulphonic acid (CSA) doped polyaniline (PANI) and its composites with cobalt phthalocyanine (CoPc) has been measured using open cell photoacoustic technique. Analysis of the data shows that the effective thermal diffusivity value can be tuned by varying the relative vol…
Sequentially spectrophotometric titrations by sodium hydroxide of meso-tetraphenylporphyrin derivatives bearing one, two, three, or four p-hydroxyl groups result in new types of spectra. The strong new bands appear in the visible region with splitting or broadening of the Soret band and its significant loss of oscilla…
High-pressure electrical conductivity experiments have been performed on the Mott insulator $\mathrm{MnO}$ to a maximum pressure of $106\phantom{\rule{0.3em}{0ex}}\mathrm{GPa}$. We observe a steady decrease in resistivity to $90\phantom{\rule{0.3em}{0ex}}\mathrm{GPa}$, followed by a large, rapid decrease by a factor o…
Infrared transmission and Raman scattering have been used to study Raman active phonons and crystal-field excitations in Yb 3+ -doped yttrium, lutetium and scandium orthosilicate crystals (Y 2 SiO 5 (YSO), Lu 2 SiO 5 (LSO) and Sc 2 SiO 5 (SSO)), which belong to the same C 2h 6 crystallographic space group. Energy leve…
Flavodoxins are involved in a variety of electron transfer reactions that are essential for life. Although FMN-binding proteins are well characterized in prokaryotic organisms, information is scarce for eukaryotic flavodoxins. We describe the 2.0-A resolution crystal structure of the Saccharomyces cerevisiae YLR011w g…
The pressure-induced phase transition in silicon carbide is studied using a constant-pressure ab initio technique. The reversible transition between the zinc-blende structure and the rock-salt structure is successfully reproduced through the simulation. The transformation mechanism at the atomistic level is characteri…
Ultrathin nickel oxide films were grown on the Ag(001) surface by evaporation of Ni in an O 2 atmosphere. The growth mechanism, composition, and structure of the NiO layers formed in the early stages of deposition have been investigated by LEIS, XPS, XPD, and LEED. We found that at O 2 pressures in the 10 -7 − 10 -6 m…
A triad consisting of a carotenoid (C), a dimesitylporphyrin (P), and a tris(heptafluoropropyl)porphyrin (P F ), C−P−P F, has been synthesized and found to undergo rapid singlet−singlet energy transfer between the porphyrin moieties so that their excited states are in equilibrium. Photoinduced electron transfer from t…