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Effects of Concentration of Some Lanthanide(III) Complexes of 1,7‐Bis(carboxymethyl)‐1,4,7,10‐tetraazacyclododecane on Bis(p‐nitrophenyl)phosphate Hydrolysis

C. Allen Chang、Bo Wu、Chih‐Hsiang Hsiao2009-02-23European Journal of Inorganic Chemistry

Abstract A detailed study of the effects of the concentration of some lanthanide(III) complexes [LnDO2A + ; DO2A = 1,7‐bis(carboxymethyl)‐1,4,7,10‐tetraazacyclododecane] on the hydrolysis of the phosphodiester bond of the compound BNPP [sodium bis(4‐nitrophenyl)phosphate] is reported at 25 °C and pH 7.90 (Ln = Eu), 9.…

Magnetism in coordination complexesRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Photoluminescence Characteristics of Nanocrystalline ZnGa2O4Phosphors Obtained at Different Sintering Temperatures

Jae-Hyeok Cha、Kyunghwan Kim、Yong Seo Park 等 5 位作者2009-02-23Molecular Crystals and Liquid Crystals

A nano-sized ZnGa2O4 phosphor was synthesized via a precipitation method (at a low temperature) and then sintered at various temperatures. X-ray diffraction (XRD) analysis confirmed that single-crystalline ZnGa2O4 particles were formed. A pure ZnGa2O4 phase was obtained at a sintering temperature of 1000°C. Theaverage…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsMicrowave Dielectric Ceramics Synthesis

Internal field engineering in CdZnO/MgZnO quantum well structures

Seoung-Hwan Park、Doyeol Ahn2009-02-23Applied Physics Letters

Electronic and optical properties of CdZnO/MgZnO quantum well (QW) structures with the depolarization of an internal field are investigated by using the non-Markovian gain model. The Mg composition is selected to give zero internal field for a given Cd composition. The Mg content to give zero internal field is found t…

Semiconductor Quantum Structures and DevicesZnO doping and propertiesSemiconductor materials and devices

Preparation and Characterization of Transparent Conductive Nb-Doped ZnO Films by Radio-Frequency Sputtering

Feng Cao、Yiding Wang、Liu Da-Li 等 7 位作者2009-02-23Chinese Physics Letters

Niobium-doped ZnO (NZO) transparent conductive films are deposited on glass substrates by rf sputtering at 300° C. Effects of sputtering power on the structural, morphologic, electrical, and optical properties of NZO films are investigated by x-ray diffraction (XRD), field emission scanning electron microscopy (FESEM)…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Preparation and flammability of EPDM/PP/Mg(OH)2 dynamic vulcanizates

Hongdian Lu、Wei Yang、Shun Zhou 等 6 位作者2009-02-23Polymers for Advanced Technologies

Abstract Magnesium hydroxide (MH) flame retardant dynamic vulcanized ethylene‐propylene‐diene terpolymer (EPDM)/polypropylene (PP) thermoplastic vulcanizates (TPVs) were prepared by a twin‐screw extruder. Influences of MH on their morphology, mechanical properties, flammability, and crystallization behavior have been…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesSynthesis and properties of polymers

Preparation of ZnO Nanospheres and Their Applications in Dye-Sensitized Solar Cells

Yongzhe Zhang、Lihui Wu、Yanping Liu 等 6 位作者2009-02-23Chinese Physics Letters

ZnO nanospheres are synthesized by a two-step self-assembly method. X-ray diffraction pattern and Raman scattering spectra measurements show that all the samples present a typical wurtzite structure. A regular sphere shape is inspected by field emission scanning electron microscope and transmission electron microscope…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesZnO doping and properties

Effect of a Heteroatom on Bonding Patterns and Triradical Stabilization Energies of 2,4,6-Tridehydropyridine versus 1,3,5-Tridehydrobenzene

Prashant Uday Manohar、Lucas Koziol、Anna I. Krylov2009-02-23The Journal of Physical Chemistry A

Electronic structure of 2,4,6-tridehydropyridine and isoelectronic 1,3,5-tridehydrobenzene is characterized by the equation-of-motion spin-flip coupled-cluster calculations with single and double substitutions and including perturbative triple corrections. Equilibrium geometries of the three lowest electronic states,…

Polymer crystallization and propertiesSynthesis and properties of polymersThermal and Kinetic Analysis

Strong and stable photoluminescence from the semiconducting inner tubes within double walled carbon nanotubes

Daisuke Shimamoto、Hiroyuki Muramatsu、Takuya Hayashi 等 9 位作者2009-02-23Applied Physics Letters

We examined the optical features of single wall carbon nanotubes (SWNTs) and the inner tubes within double walled carbon nanotubes (DWNTs) having the same (n,m) chirality. The brighter and more stable photoluminescence signals as well as the larger absorbance were observed for the semiconducting inner tubes within DWN…

Carbon Nanotubes in CompositesGraphene research and applicationsMechanical and Optical Resonators

Block Copolymer Micelles as Nanocontainers for Controlled Release of Proteins from Biocompatible Oil Phases

Andrew C. Miller、Anna Bershteyn、Wuisiew Tan 等 6 位作者2009-02-23Biomacromolecules

Biocompatible oils are used in a variety of medical applications ranging from vaccine adjuvants to vehicles for oral drug delivery. To enable such nonpolar organic phases to serve as reservoirs for delivery of hydrophilic compounds, we explored the ability of block copolymer micelles in organic solvents to sequester p…

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Impact of Reduction on the Properties of Metal Bisdithiolenes: Multinuclear Solid-State NMR and Structural Studies on Pt(tfd)2 and Its Reduced Forms

Joel A. Tang、E. Kogut、Danielle Norton 等 7 位作者2009-02-23The Journal of Physical Chemistry B

Transition-metal dithiolene complexes have interesting structures and fascinating redox properties, making them promising candidates for a number of applications, including superconductors, photonic devices, chemical sensors, and catalysts. However, not enough is known about the molecular electronic origins of these p…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchAdvanced NMR Techniques and Applications

Strong coupling of magnetic and dielectric properties in the a-axis-oriented orthorhombic HoMnO3 films

T. C. Han、J. G. Lin2009-02-23Applied Physics Letters

High quality orthorhombic (OT) HoMnO3 (HMO) thin films with a-axis perpendicular to the film surface are grown on SrTiO3(110) substrates with the method of pulsed laser deposition. The structural, magnetic, and dielectric properties of OT-HMO films are measured. The temperature-dependent magnetization clearly displays…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Photoinduced anisotropy and polarization holography in a stilbene-containing fluorinated polyimide

Tingchao He、Changshun Wang、Pan Xu 等 5 位作者2009-02-23Optics Letters

A stilbene-containing fluorinated polyimide with high optical and thermal stability was prepared. The photoinduced anisotropy in this polyimide was investigated by measuring its dichroism and photoinduced birefringence. A large photoinduced birefringence (Deltan approximately 10(-2)) was achieved in the polymer. Stabl…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotorefractive and Nonlinear Optics

Tetragonally Packed Cylinder Structure of Comb−Coil Block Copolymer Bearing Heteroarm Star Architecture

Wei-Shan Chiang、Chia-Hung Lin、Chao-Lin Yeh 等 8 位作者2009-02-23Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVNoteTetragonally Packed Cylinder Structure of Comb−Coil Block Copolymer Bearing Heteroarm Star ArchitectureWei-Shan Chiang†, Chia-Hung Lin‡, Chao-Lin Yeh†, Bhanu Nandan†⊥, Pei-Nan Hsu†, Chiu-Wei Lin†, Hsin-Lung Chen*†, and Wen-Chang Chen*‡§View Author Information Department of Chemical…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Characterization of metallocene ethylene‐1‐octene copolymers with high comonomer content cross‐linked by dicumyl peroxide or β‐radiation

Jean‐François Nicolas、Jorge A. Ressia、Enrique M. Vallés 等 5 位作者2009-02-23Journal of Applied Polymer Science

Abstract Two metallocene ethylene‐1‐octene copolymers differing in comonomer content were cross‐linked either by dicumyl peroxide (DCP) or β‐radiation with doses ranging from 0.5 to 4% DCP and 25 to 200 kGy, respectively. The effect of cross‐linking on the crystalline morphology was analyzed by differential scanning c…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Prospects in Lyophilization of Bovine Pericardium

Adolfo A. Leirner、Virgílio Tattini、Ronaldo N.M. Pitombo2009-02-23Artificial Organs

Almost 30 years after the introduction of heart valve prostheses patients worldwide are benefiting from the implant of these devices. Among the various types of heart valves, the ones made of treated bovine pericardium have become a frequently used replacement of the heart's native valve. Lyophilization, also known as…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Properties and Structure of P2O5-V2O5-ZnO/B2O3Glasses

Wookyung Sung、Juyeon Won、Jungki Lee 等 4 位作者2009-02-23Molecular Crystals and Liquid Crystals

Glasses in the P2O5-V2O5-ZnO/B2O3 (PVZ/B) system, were investigated on the thermal properties such as glass transition temperature, dilatometer softening point and coefficient of thermal expansion, and chemical properties (aqueous durability) in order to determine their applicability as barrier-ribs in plasma display…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsTransition Metal Oxide Nanomaterials

Photochromic composites based on porous stretched polyethylene filled by nematic liquid crystal mixtures

Alexey Bobrovsky、Valéry Shibaev、G. K. Elyashevich 等 7 位作者2009-02-23Polymers for Advanced Technologies

Abstract A number of the novel photochromic polyethylene (PE)‐based liquid crystal composites were prepared and studied. The oriented stretched porous polyethylene films were used as the polymer matrices. Commercial liquid crystals doped with new photochromic compounds were introduced into PE films and photo‐optical p…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPhotochromic and Fluorescence Chemistry

Shape and size-controlled fabrication of ZnO nanostructures using novel templates

Rozita Habibi、Jafar Towfighi、Alimorad Rashidi2009-02-23Journal of Experimental Nanoscience

A simple wet chemical method was developed to control the size and shape of the Zinc oxide (ZnO) nanostructures in the presence of new, efficient, and low-cost templates like ameline, sorbitol, and polyethylene glycol (PEG, Mw = 200) at low temperature within a few minutes. Nanorods and nanoparticles have been achieve…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

Mesomorphic behaviour and TSDC measurements ofortho-metallated palladium(II) and platinum(II) complexes with S,O-donor co-ligands

Viorel Cı̂rcu、Doina Mănăilă-Maximean、Constantin Roşu 等 6 位作者2009-02-23Liquid Crystals

A series of ortho-metallated Pd and Pt complexes containing an imine ligand carrying three alkoxy chains and N-benzoylthiourea derivatives as co-ligands were prepared and their liquid crystalline properties investigated. Their structures were assigned based on elemental analysis, IR and 1H NMR spectroscopy, whereas th…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesSynthesis and Properties of Aromatic Compounds

An investigation into the properties of cotton/spandex and polyester/spandex knitted fabrics

N. Gokarneshan、K. Thangamani2009-02-23Journal of the Textile Institute

Very little work has been done in the area of spandex-blend weft knits. This paper presents the findings of knits produced from cotton/spandex- and polyester/spandex-blend knits produced from core spun yarns. The dimensional properties of cotton/spandex knits compare well with those of cotton knits. The behaviour of t…

Mechanical Behavior of CompositesDyeing and Modifying Textile FibersTextile materials and evaluations