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In VitroToxicity Evaluation of Engineered Cadmium-Coated Silica Nanoparticles on Human Pulmonary Cells

Uliana De Simone、Luigi Manzo、Antonella Profumo 等 4 位作者2013-01-01Journal of Toxicology

Cytotoxicity of cadmium-containing silica nanoparticles Cd-SiO2NPs (0.05-100 µg/mL) versus SiO2NPs and CdCl2 was evaluated by an in vitro test battery in A549 by assessing (i) mitochondrial function, (ii) membrane integrity/cell morphology, (iii) cell growth/proliferation, (iv) apoptotic pathway, (v) oxidative stress,…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsGraphene and Nanomaterials Applications

Incorporation of chromophores into dendrigraft polybutadiene: effect of dendrigraft matrix on the fluorescent properties

Yu Zhang、Kaihua Shen、Fang Guo 等 7 位作者2013-01-01RSC Advances

This paper demonstrated fluorescence behaviour of two novel coumarin-containing dendrigraft polybutadienes (PB-Cou) with linear-comb (LC-PB-Cou) and star-comb (SC-PB-Cou) architectures. LC-PB-Cou and SC-PB-Cou with 12–13 mol% coumarin content were synthesized via the combination of anionic polymerization and “click” c…

RNA Interference and Gene DeliverySynthetic Organic Chemistry MethodsDendrimers and Hyperbranched Polymers

Modification of Sn/S cages with bis-functionalized ferrocenyl units

Zhiliang You、Dieter Fenske、Stefanie Dehnen2013-01-01Dalton Transactions

Bis-functionalized ferrocenyl units have been attached to organo-functionalized [(R(F)Sn)4S6] double-decker clusters as criss-cross-type intramolecular straps. Two different ways of linking result in different crystal structures and different electrochemical stabilities of the resulting compounds.

Molecular Junctions and NanostructuresPolyoxometalates: Synthesis and ApplicationsOrganometallic Compounds Synthesis and Characterization

Topology optimization of robust superhydrophobic surfaces

Andrea Cavalli、Peter Bøggild、Fridolin Okkels2013-01-01Soft Matter

In this paper we apply topology optimization to micro-structured superhydrophobic surfaces for the first time. It has been experimentally observed that a droplet suspended on a brush of micrometric posts shows a high static contact angle and low roll-off angle. To keep the fluid from penetrating the space between the…

Surface Modification and SuperhydrophobicityAdvanced Multi-Objective Optimization AlgorithmsHeat Transfer and Optimization

Supercapacitance of Single‐Walled Carbon Nanotubes‐Polypyrrole Composites

Matei Raicopol、Alina Prună、Luisa Pilan2013-01-01Journal of Chemistry

The composites based on carbon nanotubes (CNTs) and conducting polymers (CPs) are promising materials for supercapacitor devices due to their unique nanostructure that combines the large pseudocapacitance of the CPs with the fast charging/discharging double‐layer capacitance and excellent mechanical properties of the…

Supercapacitor Materials and FabricationElectrochemical sensors and biosensorsConducting polymers and applications

Controlled synthesis of ultrathin ZnO nanowires using micellar gold nanoparticles as catalyst templates

Hong Yin、Qiushi Wang、Sebastian Geburt 等 13 位作者2013-01-01Nanoscale

We demonstrate a simple and effective approach to control the diameter of ultrathin ZnO nanowires with high aspect ratios and high densities over large areas. Diblock copolymer-based nanoparticle arrays exhibiting a high degree of hexagonal order and offering easy control of particle size (typically 1-10 nm) and inter…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsNanowire Synthesis and Applications

Purification of amoxicillin trihydrate by impurity-coformer complexation in solution

Kay Huai Ying Hsi、Anthony Joseph Concepcion、Meghan Kenny 等 5 位作者2013-01-01CrystEngComm

In this work, we demonstrated the purification of amoxicillin trihydrate (AMCT) by the formation of 4-hydroxyphenylglycine (4HPG)-coformer complex in solution. Without advanced knowledge of cocrystal formation of 4HPG, a workflow was established to choose the optimal coformer and the amount of coformer to add for a sp…

Protein purification and stabilityEnzyme Structure and FunctionCrystallization and Solubility Studies

Electric field in SPS: geometry and pulsed current effects

Salvatore Grasso、Yoshio Sakka2013-01-01Journal of the Ceramic Society of Japan

Electrical heating of the graphite die and punch assembly is a unique feature of the spark plasma sintering (SPS) process. The high currents needed to heat the die, despite its low resistance, can produce an electric field across the ceramic specimens that may be enough to induce field assisted sintering. Despite the…

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsAdvanced materials and composites

Single-walled carbon nanotubes as anisotropic relaxation probes for magnetic resonance imaging

Arisbel Cerpa、Mariana Köber、Daniel Calle 等 9 位作者2013-01-01MedChemComm

We report on the preparation and characterization of magnetically oriented single-walled carbon nanotube arrangements as novel nanoprobes to enhance anisotropically water relaxation as detected by magnetic resonance imaging methods. SWCNT suspensions immobilized in agarose gels showed evident magnetic anisotropy with…

Carbon Nanotubes in CompositesAdvanced NMR Techniques and ApplicationsNMR spectroscopy and applications

Magnetic and Photocatalytic Behaviors of Ca Mn Co-Doped BiFeO<sub>3</sub> Nanofibres

Yannan Feng、Huan‐Chün Wang、Yang Shen 等 5 位作者2013-01-01Modern Research in Catalysis

Ca and Mn co-doped BiFeO3 ultrafine nanofibres were prepared with the purpose of improving magnetic and photocatalytic performances of the one-dimensional multiferroic material. Impurity phase introduced by both Bi fluctuation and Mn substitution can be suppressed by Ca doping and a space group transition from R3c to…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Light-responsive microstructures capable of pyrene monomer fluorescence switching

Mina Han、Yumi Okui、Tomohiro Hirade2013-01-01Journal of Materials Chemistry C

We synthesized an amphiphilic fluorescent compound (PyAzEG) having a pyrene fluorophore directly attached to twisted ortho-alkylated azobenzene (i) to suppress pyrene excimer formation and (ii) to facilitate pyrene monomer fluorescence switching. PyAzEG molecules in a dilute solution underwent azobenzene-based trans ↔…

Luminescence and Fluorescent MaterialsPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

Numerical self-consistent field theory of multicomponent polymer blends in the Gibbs ensemble

Zoltán Mester、Nathaniel A. Lynd、Glenn H. Fredrickson2013-01-01Soft Matter

A new computational technique is presented for the investigation of multicomponent polymer phase behavior based on a Gibbs ensemble formulation of self-consistent field theory. Calculations in the Gibbs ensemble allow the simulation of two or more coexisting phases in the absence of an interface by enabling the exchan…

Material Dynamics and PropertiesTheoretical and Computational PhysicsBlock Copolymer Self-Assembly

Fabrication of a Human Recombinant Collagen-Based Corneal Substitute Using Carbodiimide Chemistry

Mohammad Mirazul Islam、May Griffith、Kimberley Merrett2013-01-01Methods in molecular biology

Human recombinant collagen can be cross-linked with a variety of chemical cross-linking agents. Cross-linking methods can be tuned to confer collagen-based scaffolds with specific physical properties, improved antigenicity and thermal stability without impeding the ability of the material to integrate into the surroun…

Electrospun Nanofibers in Biomedical ApplicationsCorneal Surgery and TreatmentsSilk-based biomaterials and applications

&beta;-Phase Instability in Binary Ti&ndash;<i>x</i>Nb Biomaterial Single Crystals

Pan Wang、Mitsuharu Todai、Takayoshi Nakano2013-01-01MATERIALS TRANSACTIONS

The ω-phase transformation and β-phase stability in Ti–xNb (28 ≤ x ≤ 40 at%) single crystals were investigated using electrical resistivity measurements, transmission electron microscopy (TEM) observations, and specific heat measurements. The crystal for x = 28 exhibits distinct anomalous negative temperature dependen…

Metal and Thin Film MechanicsTitanium Alloys Microstructure and PropertiesMXene and MAX Phase Materials

Structure and Dielectric Properties of Na1/2Bi1/2TiO3-BaTiO3Solid Solutions

M. Dunce、E. Birks、M. Antonova 等 6 位作者2013-01-01Ferroelectrics

Dielectric properties, polarization and x-ray diffraction are studied for (1-x)Na1/2Bi1/2TiO3-xBaTiO3 solid solutions in a concentration range above the morphotropic phase boundary. It is showed that all the studied compositions have tetragonal structure with maximal tetragonality slightly above the morphotropic phase…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Gas-phase Photocatalytic Partial Oxidation of Cyclohexane to Cyclohexanol and Cyclohexanone on Au/TiO2 Photocatalysts

Diana Sannino、Vincenzo Vaiano、Paolo Ciambelli 等 6 位作者2013-01-01Journal of Advanced Oxidation Technologies

Abstract The heterogeneous photocatalytic partial oxidation of cyclohexane in gas-phase as an alternative green process for fine chemicals synthesis was successfully achieved on Au/TiO

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

X-ray diffraction, Mossbauer spectroscopy, and magnetoelectric effect studies of (BiFeO3)x-(BaTiO3)1-x solid solutions

Karol Kowal、E. Jartych、P. Guzdek 等 7 位作者2013-01-01Nukleonika

Bismuth ferrite, BiFeO3, is the most investigated multiferroic material in which ferroelectricity coexists with an antiferromagnetic order at room temperature. The crystalline structure of BiFeO3 is well recognized for monocrystals as well as for polycrystalline materials or thin films. BiFeO3 is reported to have a rh…

Multiferroics and related materials

EFFECT OF IONIC CROSSLINKING ON DENSITY OF HYDROGEL CHITOSAN MEMBRANES

Magdalena Gierszewska、Jadwiga Ostrowska-Czubenki、Anita Kwiatkowska2013-01-01OpenAlex

Ionically crosslinked chitosan membranes were prepared and their density was determined using modified pycnometer method. High‑molecular compound: sodium alginate (NaAlg) and low‑molecular compounds: pentasodium tripolyphosphate (TPP) and trisodium citrate (CIT) were used as ionic crosslinkers of chitosan. As a refere…

Electrochemical sensors and biosensorsNanocomposite Films for Food PackagingAnalytical Chemistry and Sensors