Materials Literature
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Films of transparent semiconductors are widely studied and developed because of high potential applications in electronics in last decade. Our work concerns the properties of NiO films fabricated by RF magnetron sputtering. Electrical and optical parameters of the films were characterized using Hall and transmittance…
Imaging is essential in accurately detecting, staging, and treating primary liver cancer (hepatocellular carcinoma [HCC]), one of the most prevalent and lethal malignancies. We developed a novel multifunctional nanoparticle (NP) specifically targeting glypican-3 (GPC3), a proteoglycan implicated in promotion of cell g…
We report on synthesis of single crystals of BaFe2Se3 and study of their crystal and magnetic structures by means of synchrotron single crystal X-ray and neutron powder diffraction. The crystal structure has orthorhombic symmetry and consists of double chains of FeSe4 edge connected tetrahedra intercalated by barium.…
Abstract Complex hierarchical structures composed of simple nanoscale building blocks form the basis of most biological materials. Here, we demonstrate how analogies between seemingly different fields enable the understanding of general principles by which functional properties in hierarchical systems emerge, similar…
Special features of the crystal field splitting of d-levels in the transition metal compounds with small or negative charge-transfer gaps Delta(CT) are considered. We show that in this case the Coulomb term and the covalent contribution to the t(2g)-e(g) splitting have different signs. In order to check theoretical pr…
The solar cell industry has grown quickly in recent years due to strong interest in renewable energy and the problem of global climate change .Cost is an important factor in the success of any solar technology. Today's solar cells are simply not enough efficient and are too expensive to manufacture for large-scale ele…
An initial-boundary-value problem for the sixth order Cahn-Hilliard type equation in 3-D is studied. The problem describes phase transition dynamics in ternary oil-water-surfactant systems. It is based on the Landau-Ginzburg theory proposed for such systems by G. Gompper et al. We prove that the problem under consider…
We investigate the structure, chemical bonding, electronic properties, and magnetic behavior of a three-dimensional graphitic network in aba and aaa stacking with intercalated transition metal atoms (Mn, Fe, Co, Ni, and Cu). Using density functional theory, we find induced spin-polarization of the C atoms both when th…
Freestanding layer-by-layer (LbL) films of anionic carboxymethylated cellulose nanofibrils (NFC) and a cationic branched polyelectrolyte, polyethyleneimine (PEI) have been prepared and characterized in terms of their structural and mechanical properties. The consecutive build-up of PEI and NFC on a hydroxylated and tr…
We present the facile preparation results of noble metal nanostructures induced by graphene via rapid coreduction by Ti(3+) at room temperature. Such a reduction of graphene oxide (GO) can be readily performed in solutions or on various substrates within seconds. High quality noble metal nanocrystals can be prepared b…
Two-dimensional polyaniline (PANI) nanosheets have been prepared inductively by electropolymerization of aniline monomer in an aqueous electrolyte containing sulfonated PANI-functionalized graphenes (SPANI-Gs). The SPANI-G aqueous solution is used directly as the electrolyte for electropolymerization of aniline. The f…
The performance of solid oxide fuel cells (SOFCs) was significantly enhanced through surface modification of yttria-stabilized zirconia (YSZ) electrolyte by doped ceria interlayers. Ultra-thin yttria-doped-ceria (YDC) layers were fabricated by atomic layer deposition (ALD). The doping concentrations of Y2O3 were finel…
Single-crystal-to-single-crystal (SCSC) transformations have recently been found in some molecular magnets, which involve rearrangement or dynamic movement of molecular components of the crystals. Various stimuli such as guest removal, guest exchange, ligand exchange as well as redox reactions may induce SCSC transfor…
We analyze the transverse-electric wave propagation through lossless trilayer stacks containing single-negative (SNG) materials in which only one of the two material constants, permittivity (epsilon) or permeability (mu), is negative.We consider the following combinations: ENG/MNG/ENG, ENG/DPS/MNG, DPS/ENG/DPS, and EN…
Surface chemistry can become pronounced in determining the optical properties of colloidal metal nanoparticles as the nanoparticles become so small (diameters <20 nm) that the surface atoms, which can undergo chemical interactions with the environment, represent a significant fraction of the total number of atoms alth…
An environmentally friendly and controllable P(VDF-co-CTFE) hydrogenation route involving the transition-metal complex mediated radical chain transfer reaction is successfully developed to synthesize P(VDF-co-CTFE-co-TrFE). The typical transition metal catalysts of ATRP reaction could be applied in this process.
We have re-investigated the structural identity of the famous gold-phosphine-halide Au:PR3:X compound having 55–69 gold atoms and core size of 1.4 nm (similar to “Schmid gold” or Nanogold®) from the viewpoint of the Superatom-Complex (SAC) model for ligand protected metal clusters, and in consideration of the ligand-a…
This article presents the first example of ultra-small (3-4 nm) magneto-luminescent cyano-bridged coordination polymer nanoparticles Ln0.33(3+)Gdx3+/[Mo(CN)8]3- (Ln=Eu (x=0.34), Tb (x=0.35)) enwrapped by a natural biocompatible polymer chitosan. The aqueous colloidal solutions of these nanoparticles present a luminesc…
In this work we present a novel water soluble spiropyran photoswitch that can be photonically activated inside live cells from a form that has no significant effect on the cellular survival to a form that induces a dramatic toxic response.
Stable superhydrophobic meshes with a biomimetic hierarchical structure were fabricated via simple electropolymerization and chemical polymerization processes. Because the multi-scale hierarchical structure provides a stable superhydrophobic state by maintaining a Cassie state, these meshes have high static and dynami…