Materials Literature
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The effects of ZnO crystal defects and the ubiquitous defect fluorescence on the electronic properties of nanocrystal thin-films were determined. Films were prepared from particles prepared in DMSO with controllable defect fluorescence. Particles were determined to range in size from 5 to 12 nm on average, with little…
Abstract Iron‐mediated atom transfer radical polymerization using activators generated by electron transfer directly from the secondary fluorine atoms on the poly(vinylidene fluoride) (PVDF) backbone, using methyl methacrylate (MMA) and poly (ethylene glycol) methyl ether methacrylate (PEGMA) as the monomers, FeCl 3 ·…
Abstract Well‐defined multiarm star copolymers, hyperbranched poly(glycidol)‐ b ‐poly(ε‐caprolactone), with an average of 100–110 arms per molecule and a molecular weight of arms of 3000 g/mol (PGOH‐ b ‐PCL 30 ) and 1000 g/mol (PGOH‐ b ‐PCL 10 ) were synthesized by cationic ring‐opening polymerization of ε‐caprolacton…
Understanding the mechanism underlying the interactions between inorganic nanostructures and biological systems is crucial for several rapidly growing fields that rely on nano-bio interactions. In particular, the further development of cell-targeted drug delivery using metallic nanoparticles (NP) requires new tools fo…
Spangolite, Cu(6)Al(SO(4))(OH)(12)Cl·3H(2)O, is a hydrated layered copper sulfate mineral. The Cu(2+) ions of each layer form a systematically depleted triangular lattice which approximates a maple leaf lattice. We present details of the crystal structure, which suggest that in spangolite this lattice actually compris…
Kleine Tumoren sichtbar gemacht: Eine einfache Synthese, die ohne toxische Chemikalien auskommt, liefert stark magnetische einkristalline Eisen/Eisenoxid-Kern/Schale-Nanopartikel. Die Nanopartikel wirken als hoch effektive Kontrastmittel in der Kernspintomographie und ermöglichen den Nachweis von 1–3 mm kleinen Tumore…
This work aims at shading fundamental insights into mechanisms that dictate the composition and microstructure of polypropylene/poly(ethylene-co-propylene) (PP/EPR) in-reactor alloys produced by the multizone circulating reactor (MZCR) technology, a novel one for polyolefin production. For this purpose, this technolog…
The first heterobimetallic alkyl(trimethylstannoxy)zinc clusters with the formula [Me 3 SnOZnR] 4 (R = Me 1, Et 2 ) are facile accessible by the Brønsted acid−base reaction of trimethyltin hydroxide with the respective zinc dialkyls ZnR 2 (R = Me, Et). The resulting products 1 and 2 can be isolated as white solids in…
Fluorescent magnetic nanoparticles exhibit great application prospects in biomedical engineering. Herein, we reported the effects of hydrophilic silica-coated CdTe quantum dots and magnetic nanoparticles (FMNPs) on human embryonic kidney 293 (HEK293) cells and mice with the aim of investigating their biocompatibility.…
Large area fabrication of metal alloy nanoparticles with tunable surface plasmon resonances on low-cost substrates is reported. A UV excimer laser was used to anneal 5 nm thick Ag Au bilayer films deposited with different composition ratios to create alloy nanoparticles. These engineered surfaces are used to investiga…
Light, transformation, release! Self-assembly of a simple amphiphile with an azobenzene unit produced an organic nanotube with 20 nm inner diameter. The trans-to-cis photoisomerization of the azobenzene unit within the solid bilayer membranes of the nanotube induced the transformation to cylindrical nanofibers (see gr…
A novel mixed micelle made of Tween 80 and soybean phospholipids (S80) was prepared and used as the delivery system for paclitaxel (PTX), with the purpose of improving the stability, therapeutic index, and security of PTX in comparison with Taxol® injection. The micelle size, morphological features, dilution stability…
2 mol% Dy 3+ ‐doped NaYF 4 microcrystals with different morphologies and crystalline phases have been synthesized through a hydrothermal method without assistance of any surfactant, catalyst, or template by controlling reaction temperatures, reaction time, and molar ratios of reactants. For comparison, the samples wer…
Sol and gel state behavior, in aqueous salt free dispersions, of clays Laponite (L) and Na montmorillonite (MMT) was studied at various mixing ratios (L:MMT = r = 1:0.5, 1:1, and 1:2). In the sol state, the zeta potential and gelation concentration of L-MMT obeyed the universal relation, X(L-MMT) = (rX(L) + X(MMT))/(1…
Unraveling the complex interaction between catalysts and reactants under operando conditions is a key step toward gaining fundamental insight in catalysis. We report the evolution of the structure and chemical composition of size-selected micellar Pt nanoparticles (∼1 nm) supported on nanocrystalline γ-Al(2)O(3) durin…
A method that does not employ hot-injection techniques has been developed for the size-tunable synthesis of high-quality CdSe quantum dots (QDs) with zinc blende structure. In this environmentally benign synthetic route, which uses less toxic precursors, solvents, and capping ligands, CdSe QDs that absorb visible ligh…
Using scanning tunneling microscopy (STM), we have imaged local charge density fluctuations in monolayer graphene. By placing a small gold nanoparticle on the end of the STM tip, a charge sensor is created. By raster scanning the tip over the surface and using Coulomb blockade spectroscopy, we map the local potential…
Spin-dependent transport in hydrogenated two-dimensional graphene is explored theoretically. Adsorbed atomic hydrogen impurities can either induce a local antiferromagnetic, ferromagnetic, or nonmagnetic state depending on their density and relative distribution. To describe the various magnetic possibilities of hydro…
Quantum chemical calculations were carried out to study the reaction of Al atom in the ground electronic state with H(2)O molecule. Examination of the potential energy surface revealed that the Al + H(2)O → AlO + H(2) reaction must be treated as a complex process involving two steps: Al + H(2)O → AlOH + H and AlOH + H…
Magnetoelectric (ME) composites that simultaneously exhibit ferroelectricity and ferromagnetism have recently gained significant attention as evident by the increasing number of publications. These research activities are direct results of the fact that multiferroic magnetoelectrics offer significant technological pro…