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Highly conjugated π-electron donors for organic metals: synthesis and redox chemistry of new 1,3-dithiole and 1,3-selenathiole derivatives

Adrian J. Moore、Martin R. Bryce1991-01-01Journal of the Chemical Society Perkin Transactions 1

The bis(1,3-dithiolium) dication salts 8a–c have been synthesised in three steps (31–51% overall yields) starting from 1,4-bis(bromomethyl)naphthalene, 9,10-bis(chloromethyl)anthracene and 4,4′-bis(chloromethyl)biphenyl, respectively. The bis(halogenomethyl) compounds 5 were converted into the dipiperidiniumbis(dithio…

Organic and Molecular Conductors ResearchN-Heterocyclic Carbenes in Organic and Inorganic ChemistryOrganic Chemistry Cycloaddition Reactions

Energy Deposition in Small Cylindrical Targets by Monoenergetic Electrons

H. Nikjoo、D.T. Goodhead、D.E. Charlton 等 4 位作者1991-01-01International Journal of Radiation Biology

Calculations of energy deposition in cylindrical target volumes of diameter and height 1-100 nm, including those similar to the dimensions of biological molecules and structures such as DNA, nucleosomes and chromatin fibre, have been made. The calculations used the Monte Carlo track structure program MOCA8B for electr…

Radiation Therapy and DosimetryX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Structure and properties of partially neutralized poly(acrylic acid) gels

F. Schosseler、F. Ilmain、S. J. Candau1991-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure and properties of partially neutralized poly(acrylic acid) gelsF. Schosseler, F. Ilmain, and S. J. CandauCite this: Macromolecules 1991, 24, 1, 225–234Publication Date (Print):January 1, 1991Publication History Published online1 May 2002Published inissue 1 January…

Hydrogels: synthesis, properties, applicationsbiodegradable polymer synthesis and propertiesSurfactants and Colloidal Systems

Raman Spectroscopy Study of the Tetragonal-to-monoclinic Transition in Zirconium Oxide Scales and Determination of Overall Oxygen Diffusion by Nuclear Microanalysis of O18

J. Godlewski、JP Gros、M. Lambertin 等 5 位作者1991-01-01OpenAlex

Two allotropic forms of zirconium oxide, monoclinic and tetragonal, have been identified in the scales formed on zirconium alloys. The transition from tetragonal to monoclinic has been followed by X-ray measurements and Raman laser spectroscopy. Information on the average content of the tetragonal phase was obtained b…

Fusion materials and technologiesHigh Temperature Alloys and CreepNuclear Materials and Properties

Reliability of optical fibers exposed to hydrogen: prediction of long-term loss increases

P. J. Lemaire1991-01-01Optical Engineering

Hydrogen-induced loss increases are known to occur in optical fibers, due both to the presence of molecular H<sub>2</sub> and to the reaction of hydrogen with defects in the fibers. To predict the long-term loss increases expected for fibers under normal conditions, it is necessary to rely on accelerated aging experim…

Advanced Fiber Optic SensorsHigh voltage insulation and dielectric phenomenaPower Transformer Diagnostics and Insulation

Ferroresonance in power systems: Fundamental solutions

José R. Martí、A.C. Soudack1991-01-01IEE Proceedings C Generation Transmission and Distribution

Ferroresonance can occur in power transformers or reactors fed through capacitive coupling from neighbouring phases or lines. Ritz&apos;s method of harmonic balance is used to formulate an analytical solution to the problem of fundamental frequency ferroresonance. A two-term polynomial of order 11 is used to accuratel…

Magnetic Properties and ApplicationsPower Transformer Diagnostics and InsulationNon-Destructive Testing Techniques

OBJECTIVE MEASUREMENT OF FABRIC MECHANICAL PROPERTY AND QUALITY:

Sueo Kawabata、Masako Niwa1991-01-01International Journal of Clothing Science and Technology

Textiles as clothing material must fit the human body and senses. This fitting is an important performance of the textiles besides the utility performance of textiles such as fabric strength. For many years, the performance concerning this fitness has been evaluated subjectively by hand judgement. The fabric property…

Optical measurement and interference techniquesTextile materials and evaluationsIndustrial Vision Systems and Defect Detection

Redox-switched molecular aggregates: the first example of vesicle formation from hydrophobic ferrocene derivatives

Julio C. Medina、Isabelle Gay、Zhihong Chen 等 5 位作者1991-01-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRedox-switched molecular aggregates: the first example of vesicle formation from hydrophobic ferrocene derivativesJulio C. Medina, Isabelle Gay, Zhihong Chen, Luis Echegoyen, and George W. GokelCite this: J. Am. Chem. Soc. 1991, 113, 1, 365–366Publication Date (Print):Januar…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine Chemistry

CERAMIC COATINGS BY ANODIC SPARK DEPOSITION

G. P. WIRTZ、S. D. Brown、Waltraud M. Kriven1991-01-01Materials and Manufacturing Processes

A wide range of ceramic coatings has been deposited on metal substrates by a reaction occurring during dielectric breakdown at the anode surface in an electrochemical cell, which is accompanied by visible sparking at the anode/electrolyte interface. While the majority of work reported has been on oxide coatings deposi…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Developments in EELS instrumentation for spectroscopy and imaging

Ondrej L. Krivanek、A.J. Gubbens、Niklas Dellby1991-01-01Microscopy Microanalysis Microstructures

Recent developments in instrumentation for electron energy loss spectroscopy (EELS) at Gatan R&#x26;D are reviewed. A 10-channel intrinsic Si detector with single-electron detection capa- bility is being developed for fast energy-filtered imaging and elemental mapping in the STEM mode. A new type of an imaging filter…

Analytical Chemistry and SensorsLaser-induced spectroscopy and plasmaElectron and X-Ray Spectroscopy Techniques

Saturation of the nonlinear index of refraction in semiconductor-doped glass

Jean‐Louis Coutaz、M. Kull1991-01-01Journal of the Optical Society of America B

Interferometric measurements of saturation of the nonlinear index of refraction in a semiconductor-doped glass (Schott OG 550) are reported. The index change, measured at a wavelength of 532 nm, reaches a maximum value of ~1.5 × 10−4 at high intensity. It is shown that the magnitude of the corresponding third-order su…

Glass properties and applicationsLaser Material Processing TechniquesPhotorefractive and Nonlinear Optics

High‐Toughness Ce‐TZP/Al 2 O 3 Ceramics with Improved Hardness and Strength

Raymond A. Cutler、Robert J. Mayhew、Kevin Prettyman 等 4 位作者1991-01-01Journal of the American Ceramic Society

Simulataneous additions of SrO and Al 2 O 3 to ZrO 2 (12 mol% CeO 2 ) lead to the in situ formation of strontium aluminate (SrO · 6Al 2 O 3 ) platelets (∼0.5 μm in width and 5 to 10 μm in length) within the Ce‐TZP matrix. These platelet‐containing Ce‐TZP ceramics have the strength (500 to 700 MPa) and hardness (13 to…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

Wood Flour/Polypropylene Composites: Influence of Maleated Polypropylene and Process and Composition Variables on Mechanical Properties

George E. Myers、I. S. Chahyadi、Camden A. Coberly 等 4 位作者1991-01-01International Journal of Polymeric Materials

The mechanical properties of wood flour/polypropylene composites may be improved by using coupling agents to enhance the bonding between filler and matrix. We used a two-level, full-factorial experiment to examine the effectiveness of a commercially available additive, Epolene E-43, on strength (tensile, flexural, and…

Mechanical Behavior of CompositesPolymer crystallization and propertiesNatural Fiber Reinforced Composites

Overview of liposomes

Gregory Gregoriadis1991-01-01Journal of Antimicrobial Chemotherapy

Many of the problems associated with conventional drug therapy may be circumvented by the use of delivery systems which, in a variety of ways, will optimize drug action. Among the systems being investigated, liposomes hold considerable promise. Versatility in both the structural characteristics of liposomes and their…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesRNA Interference and Gene Delivery

Hydrogen Permeation Characteristics of Vanadium-Nickel Alloys

Chikashi Nishimura、M. Komaki、Muneyuki Amano1991-01-01Materials Transactions JIM

Hydrogen permeation characteristics of palladium-plated vanadium and vanadium-nickel alloy membranes have been investigated using gas permeation technique in the temperature range 423–673 K and in the hydrogen pressure range 1×104−3×105 Pa. Hydrogen solubilities of vanadium-nickel alloys have been determined using a v…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Crystallization Kinetics of a Lithia–Silica Glass: Effect of Sample Characteristics and Thermal Analysis Measurement Techniques

Chandra S. Ray、Wenhai Huang、Delbert E. Day1991-01-01Journal of the American Ceramic Society

The crystallization kinetics of a 40Li 2 O · 60SiO 2 (mol%) glass were studied using DTA and both isothermal and nonisothermal DSC techniques as a function of (1) particle size of the glass powder, (2) crucible material, e.g., alumina or platinum, (3) furnace atmosphere, e.g., nitrogen, oxygen, or argon, and (4) surfa…

Glass properties and applicationsRecycling and utilization of industrial and municipal waste in materials productionThermal and Kinetic Analysis

Cell geometry for cluster-based quasicrystal models

Christopher L. Henley1991-01-01Physical review. B, Condensed matter

A new model of the geometrical structure of icosahedral quasicrystals is discussed that is based on icosahedral clusters connected by linkages (consistent with currently accepted motifs of the atomic structure), yet that is also a tiling by four kinds of ``canonical cells.'' Such a geometry is convenient for complete…

Quasicrystal Structures and PropertiesMineralogy and Gemology Studies

Surface-enhanced Raman spectroscopy of peptides: preferential N-terminal adsorption on colloidal silver

Tonya M. Herne、Angela M. Ahern、Robin L. Garrell1991-01-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSurface-enhanced Raman spectroscopy of peptides: preferential N-terminal adsorption on colloidal silverTonya M. Herne, Angela Ahern, and Robin L. GarrellCite this: J. Am. Chem. Soc. 1991, 113, 3, 846–854Publication Date (Print):January 1, 1991Publication History Published on…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesElectrochemical Analysis and Applications

5-Formyltetrahydrofolate polyglutamates are slow tight binding inhibitors of serine hydroxymethyltransferase

Patrick J. Stover、Verne Schirch1991-01-01Journal of Biological Chemistry

The interaction of the mono- and triglutamate forms of 5-methyltetrahydrofolate and 5-formyltetrahydrofolate with serine hydroxymethyltransferase were determined by several methods. These methods included: determining dissociation constants by observing the absorbance at 502 nm of a ternary complex of the enzyme, glyc…

Folate and B Vitamins ResearchEnzyme Structure and FunctionBiochemical and Molecular Research