Materials Literature
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We measured the pump-probe spectrum of the Sm2+ ion in three materials: CaF2, SrP2, and SrCl2. The onset of the observed prominent excited-state absorption band is consistent with an electrostatic model for impurity levels in a solid-state material.
In order to expand and clear the applicable range of the coulostatic method to measure the metal corrosion rate in solution, the method was tested by measuring the corrosion rate of iron in water containing three types of inhibitor, i.e., potassium chromate, polyphosphate with calcium ion and sodium nitrate, in stagna…
Quasi-static and dynamic penetration tests were conducted using thin metal sheets of extra-super duralumin, corrosion-resistant aluminum alloy and cold-rolled carbon steel. The phenomenon before crack initiation differed from that after the initiation. Therefore, formulae for estimating the energy-absorbing capacity w…
In this paper the relationship of ageing time to tensile strength and ultimate elongation of rubber vulcanizates was derived from the combination of ageing kinetics with the molecular theory of ultimate tensile strength of elastic networks, based on the micro-structure model of rubber vulcanizates. According to this r…
The monolithic solid‐oxide fuel cell (MSOFC) is a promising electrochemical power generation device that is currently under development at Argonne National Laboratory. The extremely high power density of the MSOFC leads to MSOFC systems that have sufficiently high energy densities that they are excellent candidates fo…
The influence of Mo content variation approved in the standard in Type 316 stainless steel was investigated electrochemically to the localized corrosion characteristics in chloride solution. The shift in pitting potential Vc′ 10, which corresponds to film breakdown, was changed a little by decreasing content of Mo in…
Abstract The nitration capabilities of a range of chemical celluloses, including some containing the cellulose‐II polymorph, were examined. The cellulose samples, derived from Pinus radiata wood by bisulphite, prehydrolysis‐kraft or kraft pulping, were compared with a commercial nitration‐grade cellulose and two bleac…
A Landau theory is used to determine the order-parameter vibrational modes in the high-temperature incommensurate charge-density-wave phase of ${\mathrm{NbTe}}_{4}$. The dispersion relation is found to exhibit a soft mode consistent with the occurrence of a continuous incommensurate- to incommensurate-phase transition…
It is well known that reduced sulfur species lead to intergranular attack (IGA) of sensitized Alloy 600 at low temperature, however the effect of these species on Alloy 600 at high temperature is not clear. Static autoclave tests were performed to investigate the effect of reduced sulfur (CaS2O3) on the high temperatu…
Effects of organosulfur compounds (thioethers, thiophosphites, and thiophosphates) and organotin compounds as additives on the thermal decomposition of polypropylene were studied. Organosulfur compounds which have electron-donating substituents to sulfur atoms accelerated the thermal decomposition of polypropylene. Ap…
The results of thermal conductivity measurements κ ‘ Turbostratic Boron Nitride in the temperature range 80–380 K are cited. Measurements were carried out on two pressed Boron Nitride samples, for which the degree of three‐dimensional ordering of the given powder is equal to 0.298 and 0.345. For theoretical descriptio…
Abstract At temperatures above the monoclinic‐orthorhombic P 2 1 / c‐Pcmn phase transition at 180°C in terbium pentaphosphate, the presence of a third phase was observed spectroscopically, identified as a C 2/ c monoclinic structure. Two lines at 12 and 17 cm −1 were observed to grow in intensity as the temperature wa…
An NAD dimer analogue, 10,10′-dimethyl-9,9′-biacridine [(AcrH)2] reduces dioxygen much more efficiently than the corresponding monomer, 10-methyl-9,10-dihydroacridine (AcrH2) in the presence of HClO4 and a catalytic amount of CoTPP+(TPP = tetraphenylporphyrin) in acetonitrile to yield 10-methylacridinium ion and hydro…
Methyl fluorochlorobromoacetate was reduced either with lithium aluminium hydride or, better, with diisobutyl aluminium hydride. Work-up in the presence of water gave a mixture of the hydrate and methyl hemiacetal of fluorochlorobromoacetaldehyde. The mixture was dehydrated with phosphorus pentoxide/sulphuric acid to…
Resin concrete has been widely used in machine tool structures in order to improve the dynamic properties, to reduce the lead time of production and to reduce thermal deformation. It has been pointed out, however, that Yung's modulus of the concrete is about one-seventh that of cast iron and is inferior to conventiona…
In direct contact melting, one of the factors that affect the heat transfer is the size of the heat transfer surface. This means that the shorter the path through which the melted liquid between the heat transfer surface and the solid of PCM (Phase Change Material) is rejected outside, the thinner the melted film, whi…
Some of the important static and dynamic properties of elastomers will be examined and some examples will be given to show how they were prioritized in the development of specific applications
A model based on single-ion theory has been presented and is shown to be applicable for quasiternary compounds. The model allows one to obtain from the experimental data information about the contributions to the magnetic properties originating from rare-earth ions at different crystallographic sites as well as on the…
Abstract The light beating technique (intensity correlation algorithm) was employed to analyze the Rayleigh scattering from the roughened Ag electrode in very dilute (10 −4 M) pyrazine, pyridine and piperidine aqueous solutions containing KC1 (0.1 M). The relaxation time is longer when the applied voltages are between…
According to Waser and Pauling the Badger rule on the relation between force constant and interatomic distance in diatomic molecules holds in solids, too. On this basis the stretching mode and the bending mode of the central atom in the unit cells were calculated for boron carbide with good and for β‐rhombohedral boro…