Materials Literature
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We herein report two different methods to deposit metallic and semiconducting nanoparticles inside a conducting polymer (CP) by controlling the diffusion of an active ion within the film. The first method is a pulsed electrodeposition where the ‘off’ intervals allow the ions to flow into the CPs as they re-oxidize. Th…
This paper describes a previously unreported class of sterically crowded tetracene derivatives that have both phenyl and ethynyl substituents. The steric crowding above and below the tetracene core prevents overlap between the extended π-systems of the acenes. Substituent effects cause these tetra-substituted tetracen…
Through-silicon vias (TSV) will speed up interconnections between chips. Manufacturable and cost-effective TSVs will allow faster computer systems. In this paper, we report the successful formation of seed layers for plating copper TSVs with aspect ratios greater than 25:1. Following the rapid atomic layer deposition…
A white powder of oxonitridosilicate Ca3Si2O4N2 was synthesized at 1450 °C from CaCO3, Si3N4 and SiO2. The crystal structure was refined using X-ray and neutron powder diffraction data with subsequent Rietveld refinements (Rwp = 7.35 for XRD and Rwp = 5.53 for NPD). The phase has a cubic unit cell with space group Pa…
TiO2 (anatase) nanocrystals were prepared and their surface was modified by sol–gel deposition of vanadium oxide species. The resulting surface-modified TiO2 combines the good properties of both materials and new, synergistic properties arise, resulting in an increased electrical conductivity, voltage window, specific…
Studies on the self-assembly of metal nanoparticles (NPs) in the presence of ions are motivated by the biosensing applications of NP clusters and the capability to control the morphology of clusters of oppositely charged NPs. The effect of ions has been explored for the self-assembly of metal NPs capped solely with io…
Plasma polymerization was used to produce novel nanometric coatings able to direct fibronectin adsorption and cell response. Using ethyl acrylate as a monomer, we obtain coatings whose chemical composition maintains some of the characteristic functionalities of the photo-initiated polymer, while the water contact angl…
This work reports the direct growth of hollow one-dimensional nanostructure arrays on conducting substrates for use as efficient electrodes in Li-ion batteries. The C-coated hollow SnO2 pillar array structures can be prepared by template-directed synthesis, selective wet etching, and a carbonization route. The well-or…
In this paper we investigate the physical and electrochemical properties of micropatterned poly(3,4-ethylenedioxythiophene):tosylate (PEDOT:tosylate) microelectrodes for neurochemical detection. PEDOT:tosylate is a promising conductive polymer electrode material for chip-based bioanalytical applications such as capill…
New derivations of Young–Laplace's and Young's equations for a liquid drop deposited on a smooth solid substrate are presented, based on an integral form of equilibrium conditions applied to appropriately selected finite portions of the drop. A simple proof for the gravity independence of the contact angle is construc…
Crystal structures of polymorphs and solvatomorphs of the potential anxiolytic drug fenobam exhibit an exclusive preference for one of the two possible tautomeric structures. A novel methodology based on nonlinear optical response has been successfully employed to detect the presence of a polymorphic impurity in a mix…
This paper reports a combined experimental and modeling study to explain the influences of detailed surface chemistry within solidoxide fuel cell (SOFC) composite anode structures on electrochemical impedance spectra (EIS).Typically, SOFC models either neglect surface chemistry or include global reforming and water-ga…
The dispersion-corrected density functional theory (DFT-D) is applied for investigation of structure and electronic properties of a sulfur-terminated graphene nanoribbon (S-GNR) encapsulated in a carbon nanotube. Two mechanisms of accommodation of the GNR in the carbon nanotube, distortion of the nanotube cross-sectio…
The use of methyl 2-pyridyl ketone oxime (mpkoH) for the synthesis of Ni(II)/Ln(III) (Ln = lanthanide) complexes, using "one-pot" reactions in the absence of an external base, is described. Depending on the reaction and crystallization conditions employed, two families of complexes have been obtained. The first family…
The transition of barium titanate crystals from the tetragonal to the orthorhombic phase has been investigated by XRD measurements during slow cooling. Additional diffuse scattering intensity between the 002 and 200 peaks develops with decreasing temperature and with time. This can be understood by assuming that this…
The driving mechanism of the metal-insulator transition (MIT) in VO(2) has always attracted attention, in particular with regards to understanding if and how the doping mechanism may tune the MIT transition temperature. However, due to the lack of detailed local structural information, in this oxide the underlying MIT…
Three supramolecular materials based on different poly(oxomolybdophosphate) clusters, (H(2)imi)(6)(Himi)(4)[{Sr(H(2)O)(4)}(2){Sr ⊂ P(6)Mo(4)(V)Mo(14)(VI)O(73)}(2)]·17H(2)O (1), (H(2)(4,4'-bpy))(2)[Cu(2)Sr(2)Mo(12)O(24)·(OH)(6)(H(2)O)(6)(H(2)PO(4))(2)(HPO(4))(2)(PO(4))(4)]·5H(2)O (2), and (H(2)bim)(H(2)bim)[SrP(2)Mo(5)…
Acoustic waves produced by partial discharges inside in dielectric materials can be detected using acoustic emission (AE) sensors. This detection can be analyzed in the time domain. AE sensors are immune to electromagnetic interference and provide a nonintrusive and nondestructive detection and a galvanic decoupling w…
A systematic study of the preparation of lanthanide (Eu3+, Tb3+, Sm3+ and Dy3+) phosphors was carried out and luminescent materials (red, green, orange-red and blue-yellow) were successfully achieved at low temperature (70 °C) in 45 min, using simultaneous supersonic and microwave irradiation. Scanning and transmissio…
The properties of silicon nanocrystals (Si NCs) that are usually a few nanometers in size can be exquisitely tuned by boron (B) and phosphorus (P) doping. Recent progress in the simulation of B‐ and P‐doped Si NCs has led to improved explanation for B‐ and P‐doping‐induced changes in the optical properties of Si NCs.…