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Effect of particle size ratio on the conducting percolation threshold of granular conductive–insulating composites

Da He、N.N. Ekere2004-06-17Journal of Physics D Applied Physics

In this paper, we apply Monte Carlo simulation to investigate the conductive percolation threshold of granular composite of conductive and insulating powders with amorphous structure. We focus on the effect of insulating to conductive particle size ratio λ = d i / d c on the conducting percolation threshold p c (the v…

High voltage insulation and dielectric phenomenaDielectric materials and actuatorsAerosol Filtration and Electrostatic Precipitation

The contribution of discharge area variation to partial discharge patterns in disc-voids

Kai Wu、Yasuo Suzuoki、L. A. Dissado2004-06-17Journal of Physics D Applied Physics

Experimental ac partial discharge (PD) patterns are presented for a disc-void (area greater than length) with metal surfaces, one metal and one insulating surface, and with both surfaces insulating. These patterns indicate that the portion of the surface over which the charge is deposited (discharge area) plays an imp…

Power Transformer Diagnostics and InsulationHigh voltage insulation and dielectric phenomenaLightning and Electromagnetic Phenomena

Dendrimer-Activated Surfaces for High Density and High Activity Protein Chip Applications

Srikant Pathak、Anup K. Singh、James R. McElhanon 等 4 位作者2004-06-17Langmuir

Highly functional Si and glass surfaces for protein immobilization have been prepared by a facile activation of native surface silanol groups. Poly(propyleneimine) dendrimers of generations 1-5 were immobilized onto the surface using a facile room-temperature coupling procedure that involved activation of native silan…

Dendrimers and Hyperbranched PolymersPolymer Surface Interaction StudiesAdvanced Biosensing Techniques and Applications

Biological Bottom-Up Assembly of Antibody Nanotubes on Patterned Antigen Arrays

Nurxat Nuraje、Ipsita A. Banerjee、Robert I. MacCuspie 等 5 位作者2004-06-17Journal of the American Chemical Society

Application of biotechnology in nanofabrication has an advantage to produce functional building-block materials that may not have synthetic counterparts. Here we introduced a new type of building block, antibody nanotubes, and demonstrated anchoring them on complementary antigen arrays via antibody-antigen recognition…

Force Microscopy Techniques and ApplicationsAdvanced biosensing and bioanalysis techniquesDiatoms and Algae Research

The influence of shape-holding conditions on shape recovery of polyurethane-shape memory polymer foams

Hisaaki TOBUSHI、Ryosuke Matsui、S. Hayashi 等 4 位作者2004-06-17Smart Materials and Structures

The thermomechanical properties of polyurethane-shape memory polymer (SMP) foams and the influence of shape-holding conditions on shape recovery were investigated experimentally. The results obtained can be summarized as follows. (1) By cooling the foam down to below the glass transition temperature T g after compress…

Polymer composites and self-healing

Electrochromic Performance of Viologen-Modified Periodic Mesoporous Nanocrystalline Anatase Electrodes

Sung Yeun Choi、Marc Mamak、Neil Coombs 等 5 位作者2004-06-17Nano Letters

We report for the first time on the electrochromic performance of viologen-modified periodic mesoporous nanocrystalline anatase, denoted meso-nc-TiO 2 -V(2+). Electrodes fashioned from meso-nc-TiO 2 -V(2+) were found to display enhanced color contrast yet have similar conduction band edge energy level and electron per…

Polyoxometalates: Synthesis and ApplicationsMesoporous Materials and CatalysisTransition Metal Oxide Nanomaterials

Engineering Nanospaces: Iterative Synthesis of Melamine‐Based Dendrimers on Amine‐Functionalized SBA‐15 Leading to Complex Hybrids with Controllable Chemistry and Porosity

Edgar Acosta、C. Shane Carr、Eric E. Simanek 等 4 位作者2004-06-17Advanced Materials

A series of melamine‐based dendrimers of various generations are grown directly off the surface of amine‐functionalized SBA‐15 (see Figure), demonstrating the feasibility of using functionalized mesoporous silica as a solid‐phase support for organic–inorganic hybrid materials.

Dendrimers and Hyperbranched PolymersSynthesis and properties of polymersMembrane Separation and Gas Transport

Reorientation in Antiferromagnetic Multilayers: Spin-Flop Transition and Surface Effects

U. K. Roessler、A. N. Bogdanov2004-06-17arXiv

Nanoscale superlattices with uniaxial ferromagnetic layers antiferromagnetically coupled through non-magnetic spacers are recently used as components of magnetoresistive and recording devices. In the last years intensive experimental investigations of these artificial antiferromagnets have revealed a large variety of…

Materials Science

Controllable Synthesis of Highly Luminescent and Monodisperse CdS Nanocrystals by a Two‐Phase Approach under Mild Conditions

Daocheng Pan、Shichun Jiang、Liqiong An 等 4 位作者2004-06-17Advanced Materials

Highly luminescent and monodisperse CdS nanocrystals (see Figure) have been synthesized using a two‐phase approach. The synthesis of CdS nanocrystals at the liquid–liquid interface was easy, safe, and highly reproducible, and the reaction conditions were mild and controllable.

Chalcogenide Semiconductor Thin FilmsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Phosphorus Nanorods—Two Allotropic Modifications of a Long‐Known Element

Arno Pfitzner、Michael F. Bräu、J. Zweck 等 5 位作者2004-06-17Angewandte Chemie International Edition

Extracting the P: Two novel amorphous allotropes of elemental phosphorus that consist of polymeric chains (see example depicted) were obtained in a pure form by extraction from their copper iodide adducts with an aqueous solution of potassium cyanide. 31P NMR spectra and high-resolution TEM images suggest that the str…

Organometallic Complex Synthesis and CatalysisSynthesis and characterization of novel inorganic/organometallic compoundsMagnetism in coordination complexes

Effects of inter-site Coulomb interactions on ferromagnetism: Application to Fe, Co and Ni

Cyrille Barreteau、Daniel Spanjaard、Marie-Catherine Desjonqueres 等 4 位作者2004-06-17arXiv

We reanalyze the condition for metallic ferromagnetism in the framework of the tight-binding approximation and investigate the consequences of the inter-site Coulomb interactions using the Hartree-Fock approximation. We first consider a non-degenerate $s$ band and we show that the inter-site interactions modify the oc…

Materials Science

Spin Dynamics of a Canted Antiferromagnet in a Magnetic Field

R. S. Fishman2004-06-17arXiv

The spin dynamics of a canted antiferromagnet with a quadratic spin-wave dispersion near $\vq =0$ is shown to possess a unique signature. When the anisotropy gap is negligible, the spin-wave stiffness $\dsw (\vq, B) = (ω_{\vq}-B)/q^2$ depends on whether the limit of zero field or zero wavevector is taken first. Conseq…

Materials Science

Roughening of Fracture Surfaces: The Role of Plastic Deformation

Eran Bouchbinder、Joachim Mathiesen、Itamar Procaccia2004-06-17Physical Review Letters

Post mortem analysis of fracture surfaces of ductile and brittle materials on the microm-mm and the nm scales, respectively, reveal self-affine cracks with anomalous scaling exponent zeta approximately 0.8 in three dimensions and zeta approximately 0.65 in two dimensions. Attempts to use elasticity theory to explain t…

High-Velocity Impact and Material BehaviorMetal Forming Simulation TechniquesMicrostructure and mechanical properties

Critical hysteresis from random anisotropy

Rava Azeredo da Silveira、Stefano Zapperi2004-06-17Physical Review B

Critical hysteresis in ferromagnets is investigated through a N-component spin model with random anisotropies, more prevalent experimentally than the random fields used in most theoretical studies. Metastability, and the tensorial nature of anisotropy, dictate its physics. Generically, random-field Ising criticality o…

Theoretical and Computational PhysicsMagnetic Properties and ApplicationsMagnetic properties of thin films

Optical Investigation of Electrical Spin Injection into Semiconductors

Vasyl F. Motsnyi2004-06-17arXiv

In this paper one can find a detailed description of the research performed by author during his stay at IMEC (Belgium). It deals with the experimental verification of the highly coherent electron spin transport across ferromagnetic metal / semiconductor interface at low and room temperatures.

Strongly Correlated ElectronsMaterials Science

Correlation between Crystal Structure and Mobility in Organic Field-Effect Transistors Based on Single Crystals of Tetrathiafulvalene Derivatives

Marta Mas‐Torrent、P. Hadley、Stefan T. Bromley 等 9 位作者2004-06-17Journal of the American Chemical Society

Recently, it was reported that crystals of the organic material dithiophene-tetrathiafulvalene (DT-TTF) have a high field-effect charge carrier mobility of 1.4 cm(2)/(V x s). These crystals were formed by a simple drop-casting method, making this material interesting to investigate for possible applications in low-cos…

Perovskite Materials and ApplicationsOrganic Electronics and PhotovoltaicsOrganic and Molecular Conductors Research

Amorphous Calcium Carbonate: Synthesis and Potential Intermediate in Biomineralization

Michael Faatz、Franziska Gröhn、Gerhard Wegner2004-06-17OpenAlex

Amorphous calcium carbonate is produced as spherical particles (see Figure) via in‐situ generation of CO 2 by hydrolysis of dialkyl carbonates in aqueous solution of CaCl 2 at room temperature. This method of synthesis (precipitation) allows detailed studies of the particle formation process. Temperature‐dependent res…

Calcium Carbonate Crystallization and Inhibition

Enhanced Sensitivity of a Gas Sensor Incorporating Single‐Walled Carbon Nanotube–Polypyrrole Nanocomposites

Kay-Hyeok An、Seung Yol Jeong、Hosung Hwang 等 4 位作者2004-06-17OpenAlex

A nanocomposite of polypyrrole/carbon nanotubes prepared by in situ chemical polymerization shows improved conductivity of the polypyrrole as compared with its pure form. Its application as a chemical sensor, made using a simple spin‐casting technique, shows a drastically increased sensitivity. The Figure shows a fiel…

Advanced Chemical Sensor TechnologiesConducting polymers and applicationsAnalytical Chemistry and Sensors

Efficient Hybrid Solar Cells from Zinc Oxide Nanoparticles and a Conjugated Polymer

W.J. Beek、Martijn M. Wienk、René A. J. Janssen2004-06-17OpenAlex

ZnO nanoparticles dispersed in a semiconducting polymer form the active layer of a solar cell (see Figure) that is able to convert up to 40 % of the incident photons at 500 nm into electrical current and has a power conversion efficiency of about 1.5 % in sunlight. Manufactured at low temperature using environmentally…

TiO2 Photocatalysis and Solar CellsChalcogenide Semiconductor Thin FilmsQuantum Dots Synthesis And Properties

Selective Growth of Metal Tips onto Semiconductor Quantum Rods and Tetrapods

Taleb Mokari、Eli Rothenberg、Inna Popov 等 5 位作者2004-06-17OpenAlex

We show the anisotropic selective growth of gold tips onto semiconductor (cadmium selenide) nanorods and tetrapods by a simple reaction. The size of the gold tips can be controlled by the concentration of the starting materials. The new nanostructures display modified optical properties caused by the strong coupling b…

Quantum Dots Synthesis And PropertiesGold and Silver Nanoparticles Synthesis and ApplicationsMolecular Junctions and Nanostructures